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Keywords = α,ω-alkenol

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27 pages, 4761 KiB  
Review
Copolymerization of Ethylene with Selected Vinyl Monomers Catalyzed by Group 4 Metal and Vanadium Complexes with Multidentate Ligands: A Short Review
by Marzena Białek and Julia Fryga
Polymers 2021, 13(24), 4456; https://doi.org/10.3390/polym13244456 - 19 Dec 2021
Cited by 12 | Viewed by 5584
Abstract
This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with α,ω-alkenols. The review [...] Read more.
This paper gives a short overview of homogeneous post-metallocene catalysts based on group 4 metal and vanadium complexes bearing multidentate ligands. It summarizes the catalytic behavior of those catalysts in copolymerization of ethylene with 1-olefins, with styrenic monomers and with α,ω-alkenols. The review is focused on finding correlations between the structure of a complex, its catalyst activity and comonomer incorporation ability, as well as the microstructure of the copolymer chains. Full article
(This article belongs to the Special Issue Polymers Synthesis and Characterization)
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