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Authors = N. Akaberi

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8 pages, 71 KiB  
Article
Electrochemical Study of Bromide in the Presence of 1,3-Indandione. Application to the Electrochemical Synthesis of Bromo Derivatives of 1,3-Indandione
by D. Nematollahi and N. Akaberi
Molecules 2001, 6(7), 639-646; https://doi.org/10.3390/60700639 - 30 Jun 2001
Cited by 17 | Viewed by 11032
Abstract
The electrochemical oxidation of bromide in the presence of 1,3-indandione (1) in water/acetic acid and methanol/acetic acid mixtures has been studied by cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of 1,3-indandione in the bromination reaction. On the basis of the [...] Read more.
The electrochemical oxidation of bromide in the presence of 1,3-indandione (1) in water/acetic acid and methanol/acetic acid mixtures has been studied by cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of 1,3-indandione in the bromination reaction. On the basis of the electroanalytical and preparative results a reaction mechanism including electron transfer, chemical reaction and regeneration of bromide was discussed. The electrochemical synthesis of bromo derivatives of 1,3-indandione (2-3) has been successfully performed at constant current, in an undivided cell, in good yield and purity. Full article
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