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Authors = Irina A. Lobanova

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13 pages, 452 KiB  
Article
New Fulvalenium Salts of Cobalt Bis(dicarbollide): Crystal Structures and Electrical Conductivities
by Olga N. Kazheva, Grigory G. Aleksandrov, Andrey V. Kravchenko, Vladimir A. Starodub, Irina A. Lobanova, Irina D. Kosenko, Igor B. Sivaev, Vladimir I. Bregadze, Lev I. Buravov and Oleg A. Dyachenko
Crystals 2012, 2(1), 43-55; https://doi.org/10.3390/cryst2010043 - 6 Jan 2012
Cited by 14 | Viewed by 6917
Abstract
New radical cation salts (BEDT-TTF)[8,8',(7)-Cl2(Cl0.09)-3,3'-Co(1,2-C2B9H9.91)(1',2'-C2B9H10)] (1), (BEDT-TTF)[8,8'-Br0.75Cl1.25-3,3'-Co(1,2-C2B9H10)2] (2), and (BMDT-TTF)4 [...] Read more.
New radical cation salts (BEDT-TTF)[8,8',(7)-Cl2(Cl0.09)-3,3'-Co(1,2-C2B9H9.91)(1',2'-C2B9H10)] (1), (BEDT-TTF)[8,8'-Br0.75Cl1.25-3,3'-Co(1,2-C2B9H10)2] (2), and (BMDT-TTF)4[8,8'-Br1.16(OH)0.72-3,3'-Co(1,2-C2B9H10.06)2] (3) were synthesized, and their crystal structures and electrical conductivities were determined. All the radical cation salts are semiconductors. Compounds 1 and 2 were found to be isostructural, however their electrical conductivities strongly differ (s293 = 2 Ω1cm−1 and 10−5 Ω−1cm−1, respectively). Full article
(This article belongs to the Special Issue Molecular Conductors)
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