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Authors = Günter Kreiselmeier

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4 pages, 196 KiB  
Short Note
(2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol
by Günter Kreiselmeier, Stefan Menner and Baldur Föhlisch
Molbank 2005, 2005(2), M406; https://doi.org/10.3390/M406 - 3 Oct 2005
Cited by 1 | Viewed by 3599
Abstract
We report the synthesis of (2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol. Compound 3 was described in the Molbank paper M405.[...] Full article
2 pages, 54 KiB  
Short Note
1-Benzyloxymethyl-2,2,4,4-tetrachloro-8-oxabicyclo[3.2.1]oct-6-en-3-one
by Günter Kreiselmeier and Baldur Föhlisch
Molbank 2004, 2004(1), M390; https://doi.org/10.3390/M390 - 29 Mar 2004
Cited by 1 | Viewed by 3125
Abstract
A mixture of 2-benzyloxymethylfuran[1] (1.88 g, 10 mmol) and pentachloroacetone[2] (2.30 g, 10 mmol) was cooled in an ice bath.[...] Full article
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