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Authors = Akpeko Gasonoo

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8 pages, 3307 KiB  
Communication
Polymer Dispersed Liquid Crystal Imprinted by Microlens Array for Enhanced Outcoupling Efficiency of Organic Light Emitting Diode
by Seongmin Lim, Hyeon-Sik Ahn, Eun-Jeong Jang, So-Young Boo, Akpeko Gasonoo, Jin-Seog Gwag, Jae-Hyun Lee and Yoonseuk Choi
Molecules 2024, 29(1), 73; https://doi.org/10.3390/molecules29010073 - 22 Dec 2023
Cited by 1 | Viewed by 1891
Abstract
In this paper, we demonstrate the use of polymer dispersed liquid crystal (PDLC) imprinted with a microlens array (MLA) via solution process to improve the outcoupling efficiency of organic light emitting diodes (OLEDs). The PDLC, well known for its scattering effect, is an [...] Read more.
In this paper, we demonstrate the use of polymer dispersed liquid crystal (PDLC) imprinted with a microlens array (MLA) via solution process to improve the outcoupling efficiency of organic light emitting diodes (OLEDs). The PDLC, well known for its scattering effect, is an excellent technology for improving the outcoupling efficiency of OLEDs. Additionally, we introduce a simple spin-coating process to fabricate PDLC which is adaptable for future solution-processed OLEDs. The MLA-imprinted PDLC applied OLED shows an enhancement factor of 1.22 in outcoupling efficiency which is a 37.5% increase compared to the existing PDLC techniques without changing the electrical properties of the OLED. Through this approach, we can expect the roll-to-roll based extremely flexible OLED, and with further research on pattering PDLC by various templates, higher outcoupling efficiency is achievable through a simple UV irradiation process. Full article
(This article belongs to the Special Issue Polymeric Liquid Crystals and Applications)
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11 pages, 3084 KiB  
Article
Optical and Electrical Characterization of Visible Parylene Films
by Ye-Seul Lee, Ji-Hyeon Yoon, Akeem Raji, Seung-Yo Baek, Yoonseuk Choi, Jonghee Lee, Akpeko Gasonoo and Jae-Hyun Lee
Materials 2022, 15(19), 6717; https://doi.org/10.3390/ma15196717 - 27 Sep 2022
Cited by 7 | Viewed by 10662
Abstract
Poly-dichloro-para-xylylene (parylene-C) film is formed through a chemical vapor deposition process, where monomeric gases are polymerized on the target surface at room temperature and are used as transparent insulating coating films. The thin parylene-C films exhibit uniform conformal layers even when deposited on [...] Read more.
Poly-dichloro-para-xylylene (parylene-C) film is formed through a chemical vapor deposition process, where monomeric gases are polymerized on the target surface at room temperature and are used as transparent insulating coating films. The thin parylene-C films exhibit uniform conformal layers even when deposited on substrates or surfaces with fine cracks, structures, and bumps. However, the film is highly transparent in the visible range (transmittance > 90%); thus, it is difficult to visually identify, inspect the coating process and check for any defects when used as an insulation film. Some reports have demonstrated the deposition of visible (hazy) parylene films through the control of the vaporization or pyrolysis of the parylene-C powder and sublimed dimers, respectively. Even though these films have been applied as device substrates and light extraction layers in organic light-emitting diodes (OLEDs), their optical and electrical characteristics have not been extensively explored, especially for their applications as insulation coatings. In this study, the characteristics of visible parylene films produced by tuning the ratio of dimer to monomer gases via the adjustments of the pyrolysis temperature are analyzed with electrical and optical methods. Parylene-C films deposited within the pyrolysis temperature of 400–700 °C exhibited a haze range of 10–90%. A relative reflectance of 18.8% at 550 nm of the visible light region was achieved in the visible parylene film deposited with a pyrolysis temperature of 400 °C. Resistivity in the order of 1010 Ω cm was achieved for the visible parylene films measured with the transmission line measurement (TLM) method. The films can be applied in advanced insulation coatings for various optical systems and electronic devices. Full article
(This article belongs to the Special Issue Wear and Corrosion Resistance Technology of Thin Film Materials)
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11 pages, 2799 KiB  
Article
Fabrication of Color Glass by Pearlescent Pigments and Dissolved EVA Film
by Seongmin Lim, Hyeon-Sik Ahn, Akpeko Gasonoo, Jae-Hyun Lee and Yoonseuk Choi
Materials 2022, 15(16), 5570; https://doi.org/10.3390/ma15165570 - 13 Aug 2022
Cited by 9 | Viewed by 2756
Abstract
In this paper, we propose a single-layer thin-film color glass manufacturing process for building-integrated photovoltaics (BIPV) with excellent aesthetics and high transmittance, through a solution process using pearlescent pigments. As a matrix for the color solution, ethylene vinyl acetate (EVA), which serves as [...] Read more.
In this paper, we propose a single-layer thin-film color glass manufacturing process for building-integrated photovoltaics (BIPV) with excellent aesthetics and high transmittance, through a solution process using pearlescent pigments. As a matrix for the color solution, ethylene vinyl acetate (EVA), which serves as an encapsulant and adhesive for the photovoltaic module (PV), was dissolved and used as a matrix for the color solution. The color glass produced is excellent in securing the aesthetics of buildings, has a high transmittance of 90% or more, outputs a maximum solar power generation efficiency of 91% from a solar cell, and can minimize the deterioration of power generation efficiency. In addition, the characteristics do not change over time, so it is suitable as color glass for BIPV. Through this study, the solution-based color glass manufacturing process for BIPV using dissolved EVA as a matrix forms a single-layer thin film with good color extensions. The choice of EVA as a matrix makes it possible for color glass to be easily attached to a solar panel using a heat press method. This proposed technique makes it easier and simpler to manufacture color glass as compared to the physical vapor deposition process. The adoption of this solution process technique to fabricate pearlescent pigment-based color glass can effectively reduce the time and cost of the process, so it is expected to be applied to the low-cost BIPV market with excellent aesthetics and high transmittance. Full article
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12 pages, 23732 KiB  
Article
The Effect of Reactive Sputtering on the Microstructure of Parylene-C
by Akeem Raji, Ye-Seul Lee, Seung-Yo Baek, Ji-Hyeon Yoon, Akpeko Gasonoo, Jonghee Lee and Jae-Hyun Lee
Materials 2022, 15(15), 5203; https://doi.org/10.3390/ma15155203 - 27 Jul 2022
Cited by 6 | Viewed by 1954
Abstract
Sputtering technique involves the use of plasma that locally heats surfaces of substrates during the deposition of atoms or molecules. This modifies the microstructure by increasing crystallinity and the adhesive properties of the substrate. In this study, the effect of sputtering on the [...] Read more.
Sputtering technique involves the use of plasma that locally heats surfaces of substrates during the deposition of atoms or molecules. This modifies the microstructure by increasing crystallinity and the adhesive properties of the substrate. In this study, the effect of sputtering on the microstructure of parylene-C was investigated in an aluminum nitride (AlN)-rich plasma environment. The sputtering process was carried out for 30, 45, 90 and 120 min on a 5 μm thick parylene-C film. Topography and morphology analyses were conducted on the parylene-C/AlN bilayers. Based on the experimental data, the results showed that the crystallinity of parylene-C/AlN bilayers was increased after 30 min of sputtering and remained saturated for 120 min. A scratch-resistance test conducted on the bilayers depicted that a higher force is required to delaminate the bilayers on top of the substrate. Thus, the adhesion properties of parylene-C/AlN bilayers were improved on glass substrate by about 17% during the variation of sputtering time. Full article
(This article belongs to the Special Issue Organic Materials for Electronic and Optoelectronic Applications)
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11 pages, 3320 KiB  
Article
Fabrication of Color Glass with High Light Transmittance by Pearlescent Pigments and Optical Adhesive
by Hyeon-Sik Ahn, Akpeko Gasonoo, Seong-Min Lim, Jae-Hyun Lee and Yoonseuk Choi
Materials 2022, 15(7), 2627; https://doi.org/10.3390/ma15072627 - 2 Apr 2022
Cited by 9 | Viewed by 3193
Abstract
In this study, we propose a solution process for realizing colored glass for building integrated photovoltaic (BIPV) systems by spin coating a color solution composed of pearlescent pigments mixed in a Norland Optical Adhesive (NOA) matrix. Color solutions are made from mixing pearlescent [...] Read more.
In this study, we propose a solution process for realizing colored glass for building integrated photovoltaic (BIPV) systems by spin coating a color solution composed of pearlescent pigments mixed in a Norland Optical Adhesive (NOA) matrix. Color solutions are made from mixing pearlescent pigments in NOA63. Compared to a physical vapor deposition process, color coatings are achieved by spin coating in a relatively simple and inexpensive process at room temperature. The optical properties can be easily controlled by adjusting the spin coating speed and the concentration of the pearlescent pigments. The produced colored glass achieved a high transmittance of 85% or more in the visible wavelength range, except for the wavelength spectrum exhibiting the maximum reflectance. In addition, we propose a one-step lamination process of colored glass on a solar cell by leveraging on the adhesive property of the NOA matrix. This eliminates the cost and process of additional ethylene vinyl acetate (EVA) layer or other materials used in the conventional lamination process. The colored glass produced through this study has stability that does not change its properties over time. Therefore, it is expected to be applied to the BIPV solar module market where aesthetics and energy efficiency are required. Full article
(This article belongs to the Special Issue Soft Materials and Optical Devices)
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11 pages, 2637 KiB  
Article
Fabrication of Multi-Layer Metal Oxides Structure for Colored Glass
by Akpeko Gasonoo, Hyeon-Sik Ahn, Eun-Jeong Jang, Min-Hoi Kim, Jin Seog Gwag, Jae-Hyun Lee and Yoonseuk Choi
Materials 2021, 14(9), 2437; https://doi.org/10.3390/ma14092437 - 7 May 2021
Cited by 15 | Viewed by 2827
Abstract
This study proposes front colored glass for building integrated photovoltaic (BIPV) systems based on multi-layered derivatives of glass/MoO3/Al2O3 with a process technology developed to realize it. Molybdenum oxide (MoO3) and aluminum oxide (Al2O3 [...] Read more.
This study proposes front colored glass for building integrated photovoltaic (BIPV) systems based on multi-layered derivatives of glass/MoO3/Al2O3 with a process technology developed to realize it. Molybdenum oxide (MoO3) and aluminum oxide (Al2O3) layers are selected as suitable candidates to achieve thin multi-layer color films, owing to the large difference in their refractive indices. We first investigated from a simulation based on wave optics that the glass/MoO3/Al2O3 multi-layer type offers more color design freedom and a cheaper fabrication process when compared to the glass/Al2O3/MoO3 multi-layer type. Based on the simulation, bright blue and green were primarily fabricated on glass. It is further demonstrated that brighter colors, such as yellow and pink, can be achieved secondarily with glass/MoO3/Al2O3/MoO3 due to enhanced multi-interfacial reflections. The fabricated color glasses showed the desired optical properties with a maximum transmittance exceeding 80%. This technology exhibits promising potential in commercial BIPV system applications. Full article
(This article belongs to the Special Issue Soft Materials and Optical Devices)
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8 pages, 2241 KiB  
Article
Color Glass by Layered Nitride Films for Building Integrated Photovoltaic (BIPV) System
by Akpeko Gasonoo, Hyeon-Sik Ahn, Seongmin Lim, Jae-Hyun Lee and Yoonseuk Choi
Crystals 2021, 11(3), 281; https://doi.org/10.3390/cryst11030281 - 12 Mar 2021
Cited by 15 | Viewed by 3529
Abstract
We investigated layered titanium nitride (TiN) and aluminum nitride (AlN) for color glasses in building integrated photovoltaic (BIPV) systems. AlN and TiN are among suitable and cost-effective optical materials to be used as thin multilayer films, owing to the significant difference in their [...] Read more.
We investigated layered titanium nitride (TiN) and aluminum nitride (AlN) for color glasses in building integrated photovoltaic (BIPV) systems. AlN and TiN are among suitable and cost-effective optical materials to be used as thin multilayer films, owing to the significant difference in their refractive index. To fabricate the structure, we used radio frequency magnetron deposition method to achieve the target thickness uniformly. A simple, fast, and cheap fabrication method is achieved by depositing the multilayer films in a single sputtering chamber. It is demonstrated that a multilayer stack that allows light to be transmitted from a low refractive index layer to a high refractive index layer or vice-versa can effectively create various distinct color reflections for different film thicknesses and multilayer structures. It is investigated from simulation based on wave optics that TiN/AlN multilayer offers better color design freedom and a cheaper fabrication process as compared to AlN/TiN multilayer films. Blue, green, and yellow color glasses with optical transmittance of more than 80% was achieved by indium tin oxide (ITO)-coated glass/TiN/AlN multilayer films. This technology exhibits good potential in commercial BIPV system applications. Full article
(This article belongs to the Special Issue Organic Optoelectronic Materials (Volume II))
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