Chemical Variability of the Essential Oils from Two Portuguese Apiaceae: Coriandrum sativum L. and Foeniculum vulgare Mill.
Abstract
:1. Introduction
2. Results
2.1. Coriandrum sativum Fruits and Vegetative Aerial Parts—EO Profile and Cluster Analysis
2.2. Foeniculum vulgare Mill. Fruits—EO Profile and Cluster Analysis
3. Discussion
3.1. Coriandrum sativum EOs Isolated from Fruits and Vegetative Aerial Parts
3.2. Foeniculum vulgare EOs Isolated from Fruits
4. Materials and Methods
4.1. Plant Material
4.2. Essential Oils Isolation
4.3. Analysis and Compound Quantification of the EOs
4.3.1. Gas Chromatography with Flame Ionization Detection (GC-FID)
4.3.2. Gas Chromatography–Mass Spectrometry (GC-MS)
4.4. Statistical Analysis
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Experimental Field | BPGV Accession | Accession Origin Municipality/District | Plant Material | Plantation Date (Month/Year) | Harvest Date (Month/Year) | EO Yield (%, v/w) | Accession Code |
---|---|---|---|---|---|---|---|
Coriandrum sativum | |||||||
ESAE/IPP | BPGV08514 | Elvas, Portalegre | Fruits | 03/21 | 06/21 | <0.05 | Cs21_fr1 |
ESAE/IPP | BPGV19290 | Alcácer do Sal, Setúbal | Fruits | 03/21 | 06/21 | <0.05 | Cs21_fr2 |
ESAE/IPP | BPGV28150 | Campo Maior, Portalegre | Fruits | 03/21 | 06/21 | <0.05 | Cs21_fr3 |
ESAE/IPP | BPGV08514 | Elvas, Portalegre | VAPs | 02/22 | 05/22 | 0.11 | Cs22_lv1 |
ESAE/IPP | BPGV19290 | Alcácer do Sal, Setúbal | VAPs | 02/22 | 05/22 | 0.09 | Cs22_lv2 |
ESAE/IPP | BPGV28150 | Campo Maior, Portalegre | VAPs | 02/22 | 05/22 | 0.06 | Cs22_lv3 |
ESAE/IPP | - | CV | VAPs | 02/22 | 05/22 | 0.07 | ROMA |
ESAE/IPP | - | CV | VAPs | 02/22 | 05/22 | 0.07 | SANTO |
ESAE/IPP | BPGV19280 | Amareleja, Beja | VAPs | 02/22 | 05/22 | <0.05 | Cs22_lv4 |
ESAE/IPP | BPGV19282 | Castro Verde, Beja | VAPs | 02/22 | 05/22 | <0.05 | Cs22_lv5 |
ESAE/IPP | BPGV19284 | Vidigueira, Beja | VAPs | 02/22 | 05/22 | 0.10 | Cs22_lv6 |
Foeniculum vulgare | |||||||
BPGV | BPGV10429 | Avis, Portalegre | Fruits | 04/20 | 10/20 | 3.00 | Fv20_P1 |
BPGV | BPGV10439 | Sousel, Portalegre | Fruits | 04/20 | 10/20 | 4.00 | Fv20_P2 |
BPGV | BPGV11263 | Bragança, Bragança | Fruits | 04/20 | 10/20 | 4.50 | Fv20_B |
BPGV | BPGV12149 | Vila Real, Vila Real | Fruits | 04/20 | 10/20 | 4.00 | Fv20_VR1 |
BPGV | BPGV12172 | Vila Real, Vila Real | Fruits | 04/20 | 10/20 | 4.50 | Fv20_VR2 |
BPGV | BPGV12179 | Mesão Frio, Vila Real | Fruits | 04/20 | 10/20 | 4.00 | Fv20_VR3 |
BPGV | BPGV16265 | Monção, Viana do Castelo | Fruits | 04/20 | 10/20 | 4.00 | Fv20_VC1 |
BPGV | BPGV16268 | Valença, Viana do Castelo | Fruits | 04/20 | 10/20 | 3.00 | Fv20_VC2 |
BPGV | BPGV16271 | Viana do Castelo, Viana do Castelo | Fruits | 04/20 | 10/20 | 4.50 | Fv20_VC3 |
BPGV | BPGV16428 | Fundão, Castelo Branco | Fruits | 04/20 | 10/20 | 4.00 | Fv20_CB |
BPGV | BPGV12198 | Montalegre, Vila Real | Fruits | 05/21 | 11/21 | 2.79 | Fv21_VR1 |
BPGV | BPGV12221 | Vila Real, Vila Real | Fruits | 05/21 | 11/21 | 3.67 | Fv21_VR2 |
BPGV | BPGV12225 | Valpaços, Vila Real | Fruits | 05/21 | 11/21 | 4.69 | Fv21_VR3 |
BPGV | BPGV12231 | Chaves, Vila Real | Fruits | 05/21 | 11/21 | 3.25 | Fv21_VR4 |
BPGV | BPGV12233 | Chaves, Vila Real | Fruits | 05/21 | 11/21 | 4.42 | Fv21_VR5 |
BPGV | BPGV16276 | Ponte da Barca, Viana do Castelo | Fruits | 05/21 | 11/21 | 3.49 | Fv21_VC1 |
BPGV | BPGV16279 | Paredes de Coura, Viana do Castelo | Fruits | 05/21 | 11/21 | 4.80 | Fv21_VC2 |
BPGV | BPGV16285 | Ponte da Barca, Viana do Castelo | Fruits | 05/21 | 11/21 | 2.58 | Fv21_VC3 |
BPGV | BPGV16294 | Ponte de Lima, Viana do Castelo | Fruits | 05/21 | 11/21 | 2.88 | Fv21_VC4 |
Components | RI | Cluster I | Cluster II | ||
---|---|---|---|---|---|
Min | Max | Min | Max | ||
n-Nonane | 900 | t | t | 0.3 | 3.1 |
α-Pinene | 930 | 1.7 | 4.3 | t | 0.3 |
γ-Terpinene | 1035 | 8.1 | 12.0 | t | 0.3 |
Linalool | 1074 | 59.6 | 72.6 | t | 0.4 |
n-Decanal | 1180 | 0.7 | 1.9 | 13.2 | 30.2 |
2-trans-Decenal | 1236 | 1.4 | 3.3 | 36.7 | 63.3 |
2-trans-Undecenal | 1334 | t | 0.1 | 2.6 | 6.2 |
Geranyl acetate | 1370 | 1.4 | 4.5 | ||
2-trans-Dodecenal | 1446 | 0.3 | 1.0 | 6.0 | 11.8 |
2-trans-Tetradecenal * | 1643 | 0.1 | 0.2 | 2.5 | 4.1 |
% Identification | 98.9 | 99.7 | 96.9 | 98.3 | |
Grouped components | |||||
Monoterpene hydrocarbons | 16.9 | 22.0 | 0.6 | 1.3 | |
Oxygen-containing monoterpenes | 66.3 | 76.7 | 0.1 | 0.5 | |
Sesquiterpene hydrocarbons | t | 0.1 | t | t | |
Oxygen-containing sesquiterpenes | t | 0.3 | t | 0.1 | |
Oxygen-containing diterpenes | 0.2 | 0.4 | |||
Fatty acids | 0.4 | 4.8 | |||
Fatty acid derivatives | 4.0 | 9.2 | 91.8 | 96.6 | |
Others | t | t | 0.4 | 3.5 |
Components | RI | Cluster I | Cluster II | ||
---|---|---|---|---|---|
Min | Max | Min | Max | ||
α-Pinene | 930 | 0.4 | 2.7 | 0.5 | 1.2 |
β-Myrcene | 975 | 0.4 | 1.5 | 0.7 | 1.5 |
1,8-Cineole | 1005 | 0.3 | 1.6 | 0.3 | 2.0 |
Limonene | 1009 | 1.3 | 3.5 | 2.2 | 7.1 |
γ-Terpinene | 1035 | 0.3 | 2.4 | 0.3 | 2.2 |
Fenchone | 1050 | 15.8 | 29.6 | 13.6 | 34.1 |
Estragole (=Methyl chavicol) | 1163 | 34.0 | 75.5 | 3.2 | 35.1 |
trans-Anethole | 1254 | 1.0 | 32.0 | 37.0 | 56.3 |
% Identification | 99.8 | 99.9 | 99.8 | 99.9 | |
Grouped components | |||||
Monoterpene hydrocarbons | 3.5 | 9.4 | 6.6 | 13.2 | |
Oxygen-containing monoterpenes | 16.7 | 31.3 | 15.1 | 35.3 | |
Phenylpropanoids | 62.2 | 77.9 | 56.3 | 75.2 | |
Others | t | t | t | t |
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Machado, A.M.; Lopes, V.; Barata, A.M.; Póvoa, O.; Farinha, N.; Figueiredo, A.C. Chemical Variability of the Essential Oils from Two Portuguese Apiaceae: Coriandrum sativum L. and Foeniculum vulgare Mill. Plants 2023, 12, 2749. https://doi.org/10.3390/plants12142749
Machado AM, Lopes V, Barata AM, Póvoa O, Farinha N, Figueiredo AC. Chemical Variability of the Essential Oils from Two Portuguese Apiaceae: Coriandrum sativum L. and Foeniculum vulgare Mill. Plants. 2023; 12(14):2749. https://doi.org/10.3390/plants12142749
Chicago/Turabian StyleMachado, Alexandra M., Violeta Lopes, Ana Maria Barata, Orlanda Póvoa, Noémia Farinha, and Ana Cristina Figueiredo. 2023. "Chemical Variability of the Essential Oils from Two Portuguese Apiaceae: Coriandrum sativum L. and Foeniculum vulgare Mill." Plants 12, no. 14: 2749. https://doi.org/10.3390/plants12142749