Synthesis of MOF525/PEDOT Composites as Microelectrodes for Electrochemical Sensing of Dopamine
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis of MOF525
2.2. Electropolymerization of 3,4-Ethylenedioxythiophene (EDOT)-Based Monomers
2.3. Preparation of MOF525/PEDOT Composites Modified Microelectrode
2.4. Material Characterizations
2.5. Electrochemical Determination of Dopamine
3. Results and Discussion
3.1. NMR Analysis of EDOT Monomers
3.2. Characterization of MOF525
3.3. MOF525/PEM Composites Modified Microelectrode
3.4. MOF525/PEpC Composites Modified Microelectrode
3.5. Detection of Dopamine by Differential Pulse Voltammetry
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Conditions | S/B Ratio | |
---|---|---|
EDOT-MeOH:EDOT a | 3:1 | 1.32 |
2:1 | 1.22 | |
1:1 | 1.21 | |
0.33:1 | 1.17 | |
0.2:1 | 1.11 | |
TBAP concentration (M) | 0.01 | 1.19 |
0.1 | 1.17 | |
0.2 | 1.15 | |
TBAP concentration (M) b | 0.005 | 1.70 |
0.01 | 1.26 | |
0.02 | 1.26 |
Polymerization Time (s) | S/B Ratio |
---|---|
60 | 1.68 |
80 | 1.74 |
100 | 2.02 |
120 | 1.39 |
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Chen, S.S.; Han, P.-C.; Kuok, W.-K.; Lu, J.-Y.; Gu, Y.; Ahamad, T.; Alshehri, S.M.; Ayalew, H.; Yu, H.-h.; Wu, K.C.-W. Synthesis of MOF525/PEDOT Composites as Microelectrodes for Electrochemical Sensing of Dopamine. Polymers 2020, 12, 1976. https://doi.org/10.3390/polym12091976
Chen SS, Han P-C, Kuok W-K, Lu J-Y, Gu Y, Ahamad T, Alshehri SM, Ayalew H, Yu H-h, Wu KC-W. Synthesis of MOF525/PEDOT Composites as Microelectrodes for Electrochemical Sensing of Dopamine. Polymers. 2020; 12(9):1976. https://doi.org/10.3390/polym12091976
Chicago/Turabian StyleChen, Season S., Po-Chun Han, Wai-Kei Kuok, Jian-Yu Lu, Yesong Gu, Tansir Ahamad, Saad M. Alshehri, Hailemichael Ayalew, Hsiao-hua Yu, and Kevin C.-W. Wu. 2020. "Synthesis of MOF525/PEDOT Composites as Microelectrodes for Electrochemical Sensing of Dopamine" Polymers 12, no. 9: 1976. https://doi.org/10.3390/polym12091976