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Nanostructural Modification of PEDOT:PSS for High Charge Carrier Collection in Hybrid Frontal Interface of Solar Cells

National Institute of Astrophysics, Optics and Electronics (INAOE), Luis Enrique Erro # 1, Tonantzintla, Puebla, C.P. 72840, Mexico
Consejo Nacional de Ciencia y tecnología—INAOE, Luis Enrique Erro # 1, Tonantzintla, Puebla C.P. 72840, Mexico
Facultad de Ingeniería, Universidad Anáhuac México, Av. Universidad Anáhuac 46, Col. Lomas Anáhuac, Huixquilucan C.P. 52786, Mexico
UAM Reynosa—Rodhe, Universidad Autónoma de Tamaulipas, Carr. Reynosa-San Fernando S/N, Reynosa, Tamaulipas 88779, Mexico
Author to whom correspondence should be addressed.
Polymers 2019, 11(6), 1034;
Received: 4 May 2019 / Revised: 1 June 2019 / Accepted: 5 June 2019 / Published: 11 June 2019
(This article belongs to the Special Issue Conductive Polymers III)
PDF [5167 KB, uploaded 13 June 2019]


In this work, we propose poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) material to form a hybrid heterojunction with amorphous silicon-based materials for high charge carrier collection at the frontal interface of solar cells. The nanostructural characteristics of PEDOT:PSS layers were modified using post-treatment techniques via isopropyl alcohol (IPA). Atomic force microscopy (AFM), Fourier-transform infrared (FTIR), and Raman spectroscopy demonstrated conformational changes and nanostructural reorganization in the surface of the polymer in order to tailor hybrid interface to be used in the heterojunctions of inorganic solar cells. To prove this concept, hybrid polymer/amorphous silicon solar cells were fabricated. The hybrid PEDOT:PSS/buffer/a-Si:H heterojunction demonstrated high transmittance, reduction of electron diffusion, and enhancement of the internal electric field. Although the structure was a planar superstrate-type configuration and the PEDOT:PSS layer was exposed to glow discharge, the hybrid solar cell reached high efficiency compared to that in similar hybrid solar cells with substrate-type configuration and that in textured well-optimized amorphous silicon solar cells fabricated at low temperature. Thus, we demonstrate that PEDOT:PSS is fully tailored and compatible material with plasma processes and can be a substitute for inorganic p-type layers in inorganic solar cells and related devices with improvement of performance and simplification of fabrication process. View Full-Text
Keywords: PEDOT:PSS; conductive polymer; hybrid interface; silicon PEDOT:PSS; conductive polymer; hybrid interface; silicon

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Olivares, A.J.; Cosme, I.; Sanchez-Vergara, M.E.; Mansurova, S.; Carrillo, J.C.; Martinez, H.E.; Itzmoyotl, A. Nanostructural Modification of PEDOT:PSS for High Charge Carrier Collection in Hybrid Frontal Interface of Solar Cells. Polymers 2019, 11, 1034.

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