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Polymers 2018, 10(11), 1186; https://doi.org/10.3390/polym10111186

Synthesis of Poly(methyl methacrylate-co-butyl acrylate)/Perfluorosilyl Methacrylate Core-Shell Nanoparticles: Novel Approach for Optimization of Coating Process

1
Korea Institute of Industrial Technology, 89 Yangdaegiro-gil, Ipjang-myeon, Seobuk-gu, Cheonan, Chungcheongnam-do 31056, Korea
2
Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodamoon-gu, Seoul 03722, Korea
*
Author to whom correspondence should be addressed.
Received: 13 July 2018 / Revised: 2 October 2018 / Accepted: 20 October 2018 / Published: 24 October 2018
(This article belongs to the Special Issue Core-Shell Structured Polymers)
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Abstract

In this study, the coating order of two monomers in the shell polymerization process of core-shell nanoparticles was altered to facilitate easy coating and optimize the properties of the coated surface to simplify the additional coating formulation process. To obtain a glass transition temperature suitable for coating, a core was synthesized by the copolymerization of an acryl monomer. A perfluoro monomer and silane monomer were additionally added to synthesize nanoparticles exhibiting both water–oil repellency and anchoring properties. In order to realize various surface properties, the nanoparticles underwent surface modification and cellulose fiber was introduced. Through the various data described in this text, the surface properties improved with the order of the introduction of the two monomers. View Full-Text
Keywords: core-shell nanoparticles; optimization; surface properties; perfluorosilyl methacrylate core-shell nanoparticles; optimization; surface properties; perfluorosilyl methacrylate
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Kook, J.-W.; Kim, Y.; Hwang, K.; Kim, J.H.; Lee, J.-Y. Synthesis of Poly(methyl methacrylate-co-butyl acrylate)/Perfluorosilyl Methacrylate Core-Shell Nanoparticles: Novel Approach for Optimization of Coating Process. Polymers 2018, 10, 1186.

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