Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents and Instruments
2.2. Single-Crystal X-ray Diffraction
2.3. Preparation of Compounds 1–3
2.3.1. Synthesis of {[ Zn(L1)2(H2O)2]·4H2O}n (1)
2.3.2. Synthesis of {[Zn(L2)(H2O)2]·0.5H2O}n (2)
2.3.3. Synthesis of {[Zn1.5(L1)(o-bdc)(H2O)]·0.5H2O}n (3)
3. Results and Discussion
3.1. Structural Description
3.1.1. Crystal Structure of 1
3.1.2. Crystal Structure of 2
3.1.3. Crystal Structure of 3
3.2. Effects of Ligand Charge on the Structures of the Title Compounds
3.3. Powder X-ray Diffraction (PXRD) and Luminescent Properties
4. Conclusions
Supplementary Materials
Author Contributions
Acknowledgments
Conflicts of Interest
References
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1 | 2 | 3 | |
---|---|---|---|
Formula | C22H26N12O10Zn | C10H10N3O6.50Zn | C38H26N12O14Zn3 |
Formula weight | 683.92 | 341.58 | 1070.82 |
Crystal system | orthorhombic | monoclinic | monoclinic |
Space group | Pccn | I2/a | C2/c |
a (Å) | 13.3477(4) | 13.5074(5) | 20.5014(12) |
b (Å) | 15.2594(6) | 10.7712(4) | 7.0380(7) |
c (Å) | 13.5167(6) | 16.3959(5) | 26.7095(15) |
α (°) | 90 | 90 | 90 |
β (°) | 90 | 98.788(3) | 99.232(6) |
γ (°) | 90 | 90 | 90 |
V (Å3) | 2753.05(19) | 2357.45(14) | 3804.0(5) |
Z | 4 | 8 | 4 |
Dcalc (g·cm−3) | 1.650 | 1.925 | 1.870 |
μ (mm−1) | 0.972 | 2.121 | 1.969 |
F(000) | 1408 | 1384 | 2160 |
R1, wR2 (I > 2σ(I)) | 0.0368, 0.0863 | 0.0501, 0.1123 | 0.0556, 0.1334 |
R1, wR2 (all data) | 0.0480, 0.0905 | 0.0535, 0.1135 | 0.0617, 0.1366 |
Goodness-of-fit (GOF) on F2 | 1.074 | 1.184 | 1.186 |
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Miao, S.; Sun, X.; Wang, K.; Xu, C.; Li, Z.; Wang, Z. Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties. Crystals 2018, 8, 312. https://doi.org/10.3390/cryst8080312
Miao S, Sun X, Wang K, Xu C, Li Z, Wang Z. Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties. Crystals. 2018; 8(8):312. https://doi.org/10.3390/cryst8080312
Chicago/Turabian StyleMiao, Shaobin, Xiaojuan Sun, Kexin Wang, Chunying Xu, Zhaohao Li, and Zhiqiang Wang. 2018. "Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties" Crystals 8, no. 8: 312. https://doi.org/10.3390/cryst8080312
APA StyleMiao, S., Sun, X., Wang, K., Xu, C., Li, Z., & Wang, Z. (2018). Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties. Crystals, 8(8), 312. https://doi.org/10.3390/cryst8080312