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Dichloro(η6-p-cymene)(P,P-diphenyl-N-propyl-phosphinous amide-κP)ruthenium(II)

Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Clavería 8, E-33006 Oviedo, Spain
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Academic Editors: Raffaella Mancuso and Nicholas E. Leadbeater
Molbank 2021, 2021(2), M1217; https://doi.org/10.3390/M1217
Received: 15 April 2021 / Revised: 14 May 2021 / Accepted: 17 May 2021 / Published: 28 May 2021
The title compound, i.e., [RuCl2(η6-p-cymene)(PPh2NHnPr)] (2), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine complex [RuCl2(η6-p-cymene)(PPh2Cl)] (1) with two equivalents of n-propylamine at room temperature. The aminophosphine complex 2 was characterized by elemental analysis, multinuclear NMR (31P{1H}, 1H and 13C{1H}) and IR spectroscopy. In addition, its catalytic behavior in the hydration of benzonitrile was briefly explored. View Full-Text
Keywords: aminophosphines; ruthenium; half-sandwich complexes; chlorophosphines; nitrile hydration aminophosphines; ruthenium; half-sandwich complexes; chlorophosphines; nitrile hydration
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MDPI and ACS Style

González-Fernández, R.; Crochet, P.; Cadierno, V. Dichloro(η6-p-cymene)(P,P-diphenyl-N-propyl-phosphinous amide-κP)ruthenium(II). Molbank 2021, 2021, M1217. https://doi.org/10.3390/M1217

AMA Style

González-Fernández R, Crochet P, Cadierno V. Dichloro(η6-p-cymene)(P,P-diphenyl-N-propyl-phosphinous amide-κP)ruthenium(II). Molbank. 2021; 2021(2):M1217. https://doi.org/10.3390/M1217

Chicago/Turabian Style

González-Fernández, Rebeca; Crochet, Pascale; Cadierno, Victorio. 2021. "Dichloro(η6-p-cymene)(P,P-diphenyl-N-propyl-phosphinous amide-κP)ruthenium(II)" Molbank 2021, no. 2: M1217. https://doi.org/10.3390/M1217

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