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Formation of an Isomeric Mixture of Dienynes Instead of a Diallene
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4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine

Institut UTINAM UMR CNRS 6213, UFR Sciences et Techniques, Université de Bourgogne-Franche-Comté, 16 Route de Gray, 25030 Besançon CEDEX, France
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Molbank 2020, 2020(2), M1142; https://doi.org/10.3390/M1142
Received: 5 March 2020 / Revised: 9 June 2020 / Accepted: 10 June 2020 / Published: 10 June 2020
(This article belongs to the Special Issue Molecules from Side Reactions)
A new pyrrole-substituted terpyridine derivative that possesses an allene moiety was obtained as an “unexpected” sole product during an attempt to alkylate the N-atom of pyrrole with propargyl bromide in order to obtain an alkyne-functionalized terpyridine. View Full-Text
Keywords: ligand; pyridine derivatives; allenic compounds; N-alkylation ligand; pyridine derivatives; allenic compounds; N-alkylation
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MDPI and ACS Style

Husson, J.; Guyard, L. 4′-(N-(Propan-1,2-dienyl)pyrrol-2-yl)-2,2′:6′,2″-terpyridine. Molbank 2020, 2020, M1142.

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