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Keywords = unsymmetrical salamo-like ligand

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16 pages, 3970 KB  
Article
Fluorescence Properties and Density Functional Theory Calculation of a Structurally Characterized Heterotetranuclear [ZnII2–SmIII2] 4,4′-Bipy-Salamo-Constructed Complex
by Xiao-Xin An, Chang Liu, Zhuang-Zhuang Chen, Ke-Feng Xie and Yang Zhang
Crystals 2019, 9(11), 602; https://doi.org/10.3390/cryst9110602 - 17 Nov 2019
Cited by 57 | Viewed by 4294
Abstract
A new heterotetranuclear complex, [{Zn(L)Sm(NO3)3}2(4,4′-bipy)]·2CH3OH, was synthesized via an unsymmetrical single salamo-like ligand H2L: 6-methoxy-6′-ethoxy-2,2′-[ethylenedioxybis(azinomethyl)]diphenol, with Zn(OAc)2·2H2O, Sm(NO3)3·6H2O, and [...] Read more.
A new heterotetranuclear complex, [{Zn(L)Sm(NO3)3}2(4,4′-bipy)]·2CH3OH, was synthesized via an unsymmetrical single salamo-like ligand H2L: 6-methoxy-6′-ethoxy-2,2′-[ethylenedioxybis(azinomethyl)]diphenol, with Zn(OAc)2·2H2O, Sm(NO3)3·6H2O, and 4,4′-bipyridine by the one-pot method. The [ZnII2–SmIII2] complex was validated via elemental analysis, powder X-ray diffraction (PXRD) analysis, infrared spectroscopy, and ultraviolet–visible (UV–Vis) absorption spectroscopy. The X-ray single crystal diffraction analysis of the [ZnII2–SmIII2] complex was carried out via X-ray single-crystal crystallography. The crystal structure and supramolecular features were discussed. In addition, while studying the fluorescence properties of the [ZnII2–SmIII2] complex, the density functional theory (DFT) calculation of its structure was also performed. Full article
(This article belongs to the Special Issue Fluorescent Complexes)
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19 pages, 18258 KB  
Article
Solvent-Induced Unsymmetric Salamo-Like Trinuclear NiII Complexes: Syntheses, Crystal Structures, Fluorescent and Magnetic Properties
by Jing Li, Hong-Jia Zhang, Jian Chang, Hao-Ran Jia, Yin-Xia Sun and Yong-Qing Huang
Crystals 2018, 8(4), 176; https://doi.org/10.3390/cryst8040176 - 18 Apr 2018
Cited by 59 | Viewed by 4143
Abstract
Solvent-induced trinuclear NiII complexes, [{Ni(L)(MeOH)}2(OAc)2Ni]·2MeOH (1), [{Ni(L)(EtOH)}2(OAc)2Ni]·2H2O (2), [{Ni(L)(n-PrOH)}2(OAc)2Ni]·2H2O (3) and [{Ni(L)(i-PrOH)}2(OAc)2Ni] [...] Read more.
Solvent-induced trinuclear NiII complexes, [{Ni(L)(MeOH)}2(OAc)2Ni]·2MeOH (1), [{Ni(L)(EtOH)}2(OAc)2Ni]·2H2O (2), [{Ni(L)(n-PrOH)}2(OAc)2Ni]·2H2O (3) and [{Ni(L)(i-PrOH)}2(OAc)2Ni] (4), have been prepared with an unsymmetric Salamo-like ligand H2L, and characterized via X-ray crystallography, FT-IR, UV-Vis and fluorescence spectra. In complexes 1, 2, 3 and 4, there are two ligand (L)2− moieties, two acetato ligands, two coordinated methanol, ethanol, n-propanol or i-propanol molecules, respectively, as well as other crystallizing solvent molecules. Two acetato ligands coordinated to the three NiII ions via usual Ni-O-C-O-Ni bridges, and four µ-phenoxo oxygen atoms coming from two [NiL(solvent)] units coordinate to the central NiII ions. Although different solvents are induced in the complexes, all the NiII ions are six-coordinated and adopt geometries of distorted octahedron. Magnetic measurements were performed on complex 2, an intramolecular antiferromagnetic interaction was observed between NiII ions and a simulation of the experimental data gives J = −2.96 cm−1 and g = 2.30. Full article
(This article belongs to the Section Crystal Engineering)
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