Search Results (7)

At the research and production company “PlasmaScience” (Ust-Kamenogorsk, Kazakhstan), a linear plasma generator installation, KAZ-PSI (Kazakhstan Plasma Generator for Plasma Surface Interactions), has been developed and constructed for the study of the interaction of plasma and materials. This article outlines some features of the developed experimental installation designed for the investigation of surface–plasma interactions. The primary components of the linear plasma installation include an electron-beam gun with a LaB6 cathode, a plasma-beam discharge chamber, an interaction chamber, a target device, and an electromagnetic system comprising electromagnetic coils. The KAZ-PSI unit enables continuous plasma generation using hydrogen, deuterium, helium, argon, and nitrogen. The electron density of the plasma is in the range of about 10¹⁷–10¹⁸ m⁻³ and the electron temperature is in the range of 1 to 20 eV. The incident ion energy is regulated by applying a negative potential of up to 2 kV to the target. Experiments on the irradiation of tungsten with helium plasma were carried out using the KAZ-PSI installation for the first time. This article presents the research findings on the structure and properties of tungsten relative to the temperature of helium plasma irradiation. Alterations in roughness, microstructure, hardness, modulus of elasticity, and erosion of the tungsten’s surface following helium plasma irradiation at varying temperatures were examined. The study’s results indicate that helium plasma irradiation induces changes in the morphology of the tungsten’s surface, creating surface relief due to sputtering by helium ions, as well as the formation of blisters. Mechanical testing revealed that after irradiation at T = 500 °C, there was an increase in hardness of up to 10%, and a slight decrease in modulus of elasticity. And after irradiation at T = 900 °C and T = 1300 °C, both hardness and elastic modulus decreased with rising temperature. The tungsten surface erosion evaluation results showed that the degrees of surface erosion increase with increasing target temperature. Full article

Studies on the erosion products of tungsten plasma-facing components (films, surfaces, and dust) for thermonuclear fusion reactors by spectroscopic methods are considered and compared with those of carbon deposits. The latter includes: carbon–deuterium CD_x (x ~ 0.5) smooth films deposited at the vacuum chamber during the erosion of the graphite limiters in the T-10 tokamak and mixed CH_x-Me films (Me = W, Fe, etc.) formed by irradiating a tungsten target with an intense H-plasma flux in a QSPA-T plasma accelerator. It is shown that the formerly developed technique for studying CD_x films with 15 methods, including spectroscopic methods, such as XPS, TDS, EPR, Raman, and FT-IR, is universal and can be supplemented by a number of new methods for tungsten materials, including in situ analysis of the MAPP type using XPS, SEM, TEM, and probe methods, and nuclear reaction method. In addition, the analysis of the fractality of the CD_x films using SAXS + WAXS is compared with the analysis of the fractal structures formed on tungsten and carbon surfaces under the action of high-intensity plasma fluxes. A comparative analysis of spectroscopic studies on carbon and tungsten deposits makes it possible to identify the problems of the safe operation of thermonuclear fusion reactors. Full article

During the service life of plasma-facing components, they are exposed to cyclic stationary and transient thermal loads. The former causes thermal fatigue and potentially detachment between the plasma-facing material tungsten and the structural Cu-based materials (divertor) and steel (first wall). The latter causes surface roughening, cracking, or even melting, which could drastically increase the erosion rate. Employing thin flexible W wires (W_w) with a diameter of a few hundred µm can reduce mechanical stresses, and we demonstrated their crack resilience against transient loads within first proof of principle studies. Here, status and future paths towards the large-scale production of such W_w assemblies, including techniques for realizing feasible joints with Cu, steel, or W, are presented. Using wire-based laser metal deposition, we were able to create a homogeneous and shallow infiltration of about 200 µm of the W_w assembly with steel. A high-heat-flux test on such a µ-brush (10 × 10 × 5 mm³ W_w on a ~0.5 mm thick steel layer) using 5 MW/m² for 2000 cycles was performed without loss of any wire. Microstructural examination after and infrared analysis during the test showed no significant signs of degradation of the joint. Full article

(1) Mud pulser carbide rotors, as a core component of ground communication in crude oil exploration, are often subjected to mud erosion and acid corrosion, resulting in pitting pits on the surface, which affects the accuracy. The purpose of this study was to investigate the acid corrosion and erosion behavior of cemented carbide materials and provide a reference for the wider application of cemented carbide materials in the petrochemical industry. (2) Experimental samples of tungsten–cobalt carbide were sintered at a low pressure by powder metallurgy. The petrochemical application environment was simulated by accelerated salt spray corrosion and solid slurry erosion with the aid of acidic copper, and the experimental phenomena were analyzed by SEM (scanning electron microscope), EDS (Energy Dispersive Spectroscopy), and XRD (X-ray diffraction). (3) The experimental results show that the coercivity of the pitted cobalt-cemented tungsten carbide prepared in this study was 17.89 KA/m, and the magnetic saturation strength was 14.42 G·cm³/g. The corrosion rate was the fastest during the acidic copper acceleration experiments from 4 h to 16 h, and the corrosion products of WCo₃ and Co₃O₄ were generated on the corrosion surface. The maximum erosion rate of 0.00104 in the erosion experiment corresponds to a corrosion sample with a corrosion time of 36 h. (4) Therefore, the coercive magnetic force and magnetic saturation strength could be derived from the prepared carbide hard phase grains and carbon content in the appropriate range. The corrosion product in the corrosion process slowed the corrosion rate, and a large amount of cobalt and a small amount of tungsten was lost by oxidation during the corrosion process. The corrosion time had the greatest effect on the erosion performance of the carbide, and the long corrosion time led to surface sparseness, which reduced the erosion resistance. Full article

Feeding IC engines with hydrogen-rich syngas as an admixture to hydrocarbon fuels can decrease pollutant emissions, particularly NOx. It offers a potential technique for low-environmental impact hydrocarbon fuel use in automotive applications. However, hydrogen-rich reformate gas (syngas) production via fuel reforming still needs more research and optimization. In this paper, we describe the effect of a plasma torch assembly design on syngas yield and composition during plasma-assisted reforming of gasoline. Additionally, erosion resistance of the cathode-emitting material under the conditions of gasoline reforming was studied, using hafnium metal and lanthanated tungsten alloy. The gasoline reforming was performed with a noncatalytic, nonthermal, low-current plasma system in the conditions of partial oxidation in an air and steam mixture. To find the most efficient plasma torch assembly configuration in terms of hydrogen production yield, four types of anode design were tested, i.e., two types of the swirl ring, and two cathode materials while varying the inlet air and fuel flow rates. The experimental results showed that hydrogen was the highest proportion of the produced syngas. The smooth funnel shape anode design in Ring 1 at air/fuel flow rates of 24/4, 27/4.5, and 30/5 g/min, respectively, was more effective than the edged funnel shape. Lanthanated tungsten alloy displayed higher erosion resistance than hafnium metal. Full article

WC-Co (tungsten carbide-cobalt) composites are widely used in industry, wear-resistant parts, and cutting tools. As successful tool materials, WC-Co carbides are widely applied in metal cutting, wear applications, chipless forming, stoneworking, wood, and plastic working. These materials are exposed to severe solid particle erosion by sand particles, such as in the wood industry. During the production of furniture with HDF (High Density Fibreboard), MDF (Medium Density Fibreboard), or OSB (Oriented Strand Board), there are observed problems with tool erosion. Contamination, mainly of the HDF by sand, is quite often, which is why all tools used for the machining of such materials are exposed to erosion by sand particles. Although many studies have been performed on the erosion of various metals, and erosion models exist to predict their erosion behavior, the issue is still relevant. The aim of the study was to determine the effect of grain size (submicron, ultrafine) and the manufacturing technology (SPS—Spark Plasma Sintering, conventional) used on the erosive properties of WC-Co sintered carbides. Sinters produced by the SPS method with different sizes of WC grains and commercial samples were used for the tests. Ten two-hour cycles were carried out under medium conditions of quartz sand and quartz sand with 10% SiC added. Used samples were characterised using scanning electron microscopy (SEM) and roughness was determined. Furthermore, erosion studies allowed individuating a wear mechanism as well as the possibility to foresee cutting performance in prospective application. Full article

The nature and constituents of ballistic aerosol created by kinetic energy penetrator rods of tungsten heavy alloys (W-Fe-Ni and W-Fe-Co) perforating steel target plates was characterized by scanning and transmission electron microscopy. These aerosol regimes, which can occur in closed, armored military vehicle penetration, are of concern for potential health effects, especially as a consequence of being inhaled. In a controlled volume containing 10 equispaced steel target plates, particulates were systematically collected onto special filters. Filter collections were examined by scanning and transmission electron microscopy (SEM and TEM) which included energy-dispersive (X-ray) spectrometry (EDS). Dark-field TEM identified a significant nanoparticle concentration while EDS in the SEM identified the propensity of mass fraction particulates to consist of Fe and FeO, representing target erosion and formation of an accumulating debris field. Direct exposure of human epithelial cells (A549), a model for lung tissue, to particulates (especially nanoparticulates) collected on individual filters demonstrated induction of rapid and global cell death to the extent that production of inflammatory cytokines was entirely inhibited. These observations along with comparisons of a wide range of other nanoparticulate species exhibiting cell death in A549 culture may suggest severe human toxicity potential for inhaled ballistic aerosol, but the complexity of the aerosol (particulate) mix has not yet allowed any particular chemical composition to be identified. Full article