Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (1)

Search Parameters:
Keywords = retro-Buchner reaction

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
10 pages, 1672 KiB  
Article
On-Surface Thermal Stability of a Graphenic Structure Incorporating a Tropone Moiety
by Irene R. Márquez, Nerea Ruíz del Árbol, José I. Urgel, Federico Villalobos, Roman Fasel, María F. López, Juan M. Cuerva, José A. Martín-Gago, Araceli G. Campaña and Carlos Sánchez-Sánchez
Nanomaterials 2022, 12(3), 488; https://doi.org/10.3390/nano12030488 - 29 Jan 2022
Cited by 6 | Viewed by 4671
Abstract
On-surface synthesis, complementary to wet chemistry, has been demonstrated to be a valid approach for the synthesis of tailored graphenic nanostructures with atomic precision. Among the different existing strategies used to tune the optoelectronic and magnetic properties of these nanostructures, the introduction of [...] Read more.
On-surface synthesis, complementary to wet chemistry, has been demonstrated to be a valid approach for the synthesis of tailored graphenic nanostructures with atomic precision. Among the different existing strategies used to tune the optoelectronic and magnetic properties of these nanostructures, the introduction of non-hexagonal rings inducing out-of-plane distortions is a promising pathway that has been scarcely explored on surfaces. Here, we demonstrate that non-hexagonal rings, in the form of tropone (cycloheptatrienone) moieties, are thermally transformed into phenyl or cyclopentadienone moieties upon an unprecedented surface-mediated retro–Buchner-type reaction involving a decarbonylation or an intramolecular rearrangement of the CO unit, respectively. Full article
(This article belongs to the Special Issue On-Surface Synthesis of Low-Dimensional Organic Nanostructures)
Show Figures

Graphical abstract

Back to TopTop