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Keywords = protohistoric metallurgy

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10 pages, 3842 KiB  
Article
Evidence of Copper and Iron Deposits of the Protohistoric City of Temesa
by Virgilio Vecchio, Maurizio Cannatà, Edoardo Proverbio, Elpida Piperopoulos, Lorenzo Torrisi and Letteria Silipigni
Quaternary 2023, 6(1), 18; https://doi.org/10.3390/quat6010018 - 7 Mar 2023
Viewed by 2401
Abstract
With the name ‘Temesa’ (Latin Tempsa), the ancients identified a settlement located along the Tyrrhenian coast of Calabria, cited by sources as an international metal exchange emporium. The town is mentioned by Homer as being famous in the ancient world for the production [...] Read more.
With the name ‘Temesa’ (Latin Tempsa), the ancients identified a settlement located along the Tyrrhenian coast of Calabria, cited by sources as an international metal exchange emporium. The town is mentioned by Homer as being famous in the ancient world for the production of bronze, and in the I century A.D. Strabo wrote that there were rich copper mines near the city. Many years of study led to the recognition of Temesa as a complex urban system located between the Oliva and Savuto rivers, near Amantea. To confirm this hypothesis, we searched, in the surrounding rocky outcrops, for the presence of minerals useful for the extraction of iron and copper. Samples of 3 different rock stratifications were taken near the protohistoric settlement of Serra Aiello. The observation under an polarized reflected light microscope and the X-ray diffraction patterns revealed the presence of many minerals useful for the extraction of iron and copper in every sample. The heating of samples under both oxidizing and reducing conditions helped us to better quantify copper and iron minerals content causing, at the same time, the appearance of a marked paramagnetic behavior that could be associated with the presence of goethite. X ray fluorescence analysis showed a high concentration of iron and a low copper content. Full article
(This article belongs to the Special Issue Geological Materials and Cultural Heritage through the Millennia)
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14 pages, 2792 KiB  
Article
Characterisation of Alloy Composition of Protohistoric Small Boat Models from Sardinia (Italy)
by Roberta Iannaccone, Anna Depalmas, Claudio Bulla, Sergio Augusto Barcellos Lins and Antonio Brunetti
Materials 2022, 15(4), 1324; https://doi.org/10.3390/ma15041324 - 11 Feb 2022
Cited by 2 | Viewed by 2527
Abstract
The Sardinian protohistoric civilisation (Final Bronze Age and the Early Iron Age) has greatly contributed to the development of metallurgy in the Mediterranean area by producing a large number of bronze artefacts. Among them, small boat models (so-called “navicelle”) represent one of the [...] Read more.
The Sardinian protohistoric civilisation (Final Bronze Age and the Early Iron Age) has greatly contributed to the development of metallurgy in the Mediterranean area by producing a large number of bronze artefacts. Among them, small boat models (so-called “navicelle”) represent one of the most characteristic objects from the Sardinian Protohistoric civilisation. This work is an attempt to classify these boats on the basis of their alloy composition, provenience, and morphology. Due to the impossibility of removing the boats from the museum, alloys were characterised using energy-dispersive X-ray fluorescence spectrometry and Monte Carlo simulations. Fifteen boats were analyzed. Obtained results were compared to other performed analyses in the last few decades with different techniques and reported in the literature. Analyses allow for characterising both the bulk composition of ternary alloy Cu–Sn–Pb and patina thickness, offering useful information about their conservation status and the technological achievements of Sardinian craftsmen, while also providing information on smelting temperatures and casting techniques. Full article
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