Search Results (6)

This paper proposes a Swiss-roll-type mini-reformer employing a copper–zinc catalyst for high-efficient SRM process. Although the commercially available copper–zinc catalysts commonly used in cylindrical-type reformers provide decent conversion rates in the short term, their long-term durability still requires improvement, mainly due to temperature variations in the reformer, catalyst loading, and thermal sintering issues. This Swiss-roll-shaped mini-reformer is designed to improve thermal energy preservation/temperature uniformity by using dual spiral channels to improve the long-term durability while maintaining methanol-reforming efficiency. It was fabricated on a copper plate that was 80 mm wide, 80 mm long, and 4 mm high with spiral channels that were 2 mm deep, 4 mm wide, and 350 mm long. To optimize the design and reformer operation, the catalyst porosity, gas hourly speed velocity (GHSV), operation temperature, and fuel feeding rate are investigated. Swiss-roll-type reformers may require higher driving pressures but can provide better thermal energy preservation and temperature uniformity, posing a higher conversion rate for the same amount of catalyst when compared with other geometries. By carefully adjusting the catalyst bed porosity, locations, and catalyst loading amount as well as other conditions, an optimized gas hourly space velocity (GHSV) can be obtained (14,580 mL/g·h) and lead to not only a high conversion rate (96%) and low carbon monoxide generation rate (0.98%) but also a better long-term durability (decay from 96% to 88.12% after 60 h operation time) for SRM processes. The decay rate, 0.13%/h, after 60 h of operation, is five-folds lower than that (0.67%/h, 0.134%/h) of a commercial cylindrical-type fixed-bed reactor with a commercial catalyst. Full article

The oxidative dehydrogenation of alkanes is a prospective method for olefins production. CO₂-assisted propane dehydrogenation over metal oxide catalysts provides an opportunity to increase propylene production with collateral CO₂ utilization. We prepared the chromia catalysts on various mesoporous aluminosilicate supports, such as halloysite nanotubes, nanostructured core/shell composites of MCM-41/halloysite (halloysite nanotubes for the core; silica of MCM-41-type for the shell), and MCM-41@halloysite (silica of MCM-41-type for the core; halloysite nanotubes for the shell). The catalysts have been characterized by X-ray fluorescence analysis, low-temperature nitrogen adsorption, X-ray diffraction, temperature-programmed reduction, temperature-programmed desorption of ammonia, transmission electron microscopy with energy-dispersive X-ray spectroscopy, and thermogravimetric analysis. The catalysts’ performance in carbon-dioxide-assisted propane dehydrogenation has been estimated in a fixed-bed reactor at atmospheric pressure. The most stable catalyst is Cr/halloysite, having the lowest activity and the largest pore diameter. The catalyst, Cr/MCM-41/HNT, shows the best catalytic performance: having the highest conversion (19–88%), selectivity (83–30%), and space–time yield (4.3–7.1 mol C₃H₆/kg catalyst/h) at the temperature range of 550–700 °C. The highest space–time yield could be related to the uniform distribution of the chromia particles over the large surface area and narrow pore size distribution of 2–4 nm provided by the MCM-41-type silica and transport channels of 12–15 nm from the halloysite nanotubes. Full article

A new type of Water Lead Lithium Cooled (WLLC) blanket that adopts the modular design scheme, water cooling the structure components, liquid PbLi as breeder and coolant, and SiC as the thermal insulator between PbLi and structures is under development as a candidate blanket concept for the Chinese Fusion Engineering Test Reactor (CFETR). Based on a poloidal-radial slice model, thermal hydraulic analysis is performed for this blanket to validate the feasibility of design goals. Results show that the present design can achieve the outlet temperature in the range of 600–700 °C, with all the material temperatures safely below the upper limits. A series of sensitivity analyses are also carried out. It indicates that the thermal conductivity (TC) of SiC would have a significant influence on the temperature field, streamlines and pressure drop; that is, lower TC of SiC can maintain the temperature of PbLi at a high level, and induce an increased number of vortices in the liquid PbLi flow as well as a larger pressure drop. On this basis, the joint effects of the TC of SiC and inlet velocity on the performance of blanket thermal hydraulics are analyzed, then the so-called “attainable region” is proposed. Finally, optimization design studies are carried out by decreasing the width of the front channel. Comparison results show that the present design is the most reasonable. Full article

The steam generator in a nuclear power plant is a type of heat exchanger in which heat transfer occurs from the hot fluid in multiple channels to the cold fluid. Therefore, a uniform flow over multiple channels is necessary to improve heat exchanger efficiency. The study aims at experimentally investigating the improvement of flow uniformity by the perforated plate in the heat exchanger used for a sodium-cooled fast reactor stream generator. A 1/4-scale experimental model for one heat exchanger unit with 33 × 66 channels was manufactured. The working fluid was water. A perforated plate was systematically designed using numerical simulations to improve the flow uniformity over the 33 × 66 channels. As a result, the flow uniformity greatly improved at a slight cost of pressure drop. To validate the numerical results, planar particle image velocimetry measurements were performed on the selected planes in the inlet and outlet headers. The experimental velocity profiles near the exits of the channels were compared with numerical simulation data. The experimental profiles agreed with the numerical data well. Both the numerical simulation and the experimental results showed a slight increase in pressure drop, despite significant improvement in the flow uniformity. Full article

In this paper, the conceptual design and a preliminary study of the LUT Heating Experimental Reactor (LUTHER) for 2 MWth power are presented. Additionally, commercially sized designs for 24 MWth and 120 MWth powers are briefly discussed. LUTHER is a scalable light-water pressure-channel reactor designed to operate at low temperature, low pressure, and low core power density. The LUTHER core utilizes low enriched uranium (LEU) to produce low-temperature output, targeting the district heating demand in Finland. Nuclear power needs to contribute to the decarbonizing of the heating and cooling sector, which is a much more significant greenhouse gas emitter than electricity production in the Nordic countries. The main principle in the development of LUTHER is to simplify the core design and safety systems, which, along with using commercially available reactor components, would lead to lower fabrication costs and enhanced safety. LUTHER also features a unique design with movable individual fuel assembly for reactivity control and burnup compensation. Two-dimensional (2D) and three-dimensional (3D) fuel assemblies and reactor cores are modeled with the Serpent Monte Carlo reactor physics code. Different reactor design parameters and safety configurations are explored and assessed. The preliminary results show an optimal basic core design, a good neutronic performance, and the feasibility of controlling reactivity by moving fuel assemblies. Full article

The monolithic catalyst, namely the structured catalyst, is one of the important categories of catalysts used in various fields, especially in catalytic exhaust after-treatment. Despite its successful application in conventional wash-coated catalysts in both mobile and stationary catalytic converters, washcoat-based technologies are facing multi-fold challenges, including: (1) high Pt-group metals (PGM) material loading being required, driving the market prices; (2) less-than ideal distribution of washcoats in typically square-shaped channels associated with pressure drop sacrifice; and (3) far from clear correlations between macroscopic washcoat structures and their catalytic performance. To tackle these challenges, the well-defined nanostructure array (nano-array)-integrated structured catalysts which we invented and developed recently have been proven to be a promising class of cost-effective and efficient devices that may complement or substitute wash-coated catalysts. This new type of structured catalysts is composed of honeycomb-structured monoliths, whose channel surfaces are grown in situ with a nano-array forest made of traditional binary transition metal oxide support such as Al₂O₃, CeO₂, Co₃O₄, MnO₂, TiO₂, and ZnO, or newer support materials including perovskite-type ABO₃ structures, for example LaMnO₃, LaCoO₃, LaNiO, and LaFeO₃. The integration strategy parts from the traditional washcoat technique. Instead, an in situ nanomaterial assembly method is utilized, such as a hydro (solva-) thermal synthesis approach, in order to create sound structure robustness, and increase ease and complex-shaped substrate adaptability. Specifically, the critical fabrication procedures for nano-array structured catalysts include deposition of seeding layer, in situ growth of nano-array, and loading of catalytic materials. The generic methodology utilization in both the magnetic stirring batch process and continuous flow reactor synthesis offers the nano-array catalysts with great potential to be scaled up readily and cost-effectively. The tunability of the structure and catalytic performance could be achieved through morphology and geometry adjustment and guest atoms and defect manipulation, as well as composite nano-array catalyst manufacture. Excellent stabilities under various conditions were also present compared to conventional wash-coated catalysts. Full article