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Keywords = precious opal

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43 pages, 19705 KiB  
Article
Timing of Opalization at Lightning Ridge, Australia: New Evidence from Opalized Fossils
by George E. Mustoe and Elizabeth T. Smith
Minerals 2023, 13(12), 1471; https://doi.org/10.3390/min13121471 - 23 Nov 2023
Cited by 3 | Viewed by 6696
Abstract
Microscopic analysis of fossils from the Lightning Ridge district of northwestern New South Wales, Australia, shows that opal has been typically deposited in variable cavities left by the degradation of the original organic material. Fine-grained, clay-rich sediments have preserved the external morphology, and [...] Read more.
Microscopic analysis of fossils from the Lightning Ridge district of northwestern New South Wales, Australia, shows that opal has been typically deposited in variable cavities left by the degradation of the original organic material. Fine-grained, clay-rich sediments have preserved the external morphology, and opalization has produced detailed casts with different modes of preservation of internal details. Plant remains include cones, cone scales, fruiting bodies, and seeds, but the most common specimens are twigs, stems, and wood fragments. These specimens commonly contain angular inclusions that represent small tissue fragments produced by the degradation of the original wood. Inclusions commonly have a “hollow box” structure where the organic material has decomposed after the initial opal filling of the mold. These spaces commonly contain traces of the cellular architecture, in the form of wood fiber textures imprinted on the cavity wall, degraded cellular material, and silicified tracheids. Opal casts of mollusk shells and crustacean bioliths preserve the shape but no calcium carbonate residue. Likewise, opal casts of vertebrate remains (bones, teeth, osteoderms) lack preservation of the original bioapatite. These compositions are evidence that burial in fine clays and silts, isolated from the effects of water and oxygen, caused protracted delays between the timing of burial, decomposition, and the development of vacuities in the claystones that became sites for opal precipitation. The length of time required for the dissolution of cellulosic/ligninitic plant remains, calcium carbonate items, and calcium phosphates in bones and teeth cannot be quantified, but evidence from opal-bearing formations worldwide reveals that these processes can be very slow. The timing of opalization can be inferred from previous studies that concluded that Cenozoic tectonism produced faults and fissures that allowed horizontal and lateral movement of silica-bearing groundwater. Comparisons of Australian opal-AG with opal from international localities suggest that opalization was a Neogene phenomenon. The transformation of Opal-AG → Opal-CT is well-documented for the diagenesis of siliceous biogenic sediments and siliceous sinter from geothermal areas. Likewise, precious and common opal from the late Miocene Virgin Valley Formation in northern Nevada, USA, shows the rapidity of the Opal-AG → Opal-CT transformation. Taken together, we consider this evidence to indicate a Neogene age for Lightning Ridge opalization and by inference for the opalization of the extensive opal deposits of the Great Artesian Basin in Australia. New paleontology discoveries include a surprising level of cellular detail in plant fossils, the preservation of individual tracheids as opal casts, evidence of opalized plant pith or vascular tissue (non-gymnosperm), and the first report of Early Cretaceous coprolites from New South Wales, Australia. Full article
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21 pages, 8029 KiB  
Article
Geoheritage of the Precious Opal Bearing Zone in Libanka Mining District (Slovakia) and Its Geotourism and Geoeducation Potential
by Silvia Palgutová and Ľubomír Štrba
Land 2022, 11(12), 2293; https://doi.org/10.3390/land11122293 - 14 Dec 2022
Cited by 8 | Viewed by 3209
Abstract
The northern part of the Slanské Vrchy Mountains, in Slovakia, within the territory of Dubnik Opal Mines, is considered to be the historical source of opal, including the opal known to the Romans. Dubnik precious opal mineralization originating from post-magmatic hydrothermal fluids based [...] Read more.
The northern part of the Slanské Vrchy Mountains, in Slovakia, within the territory of Dubnik Opal Mines, is considered to be the historical source of opal, including the opal known to the Romans. Dubnik precious opal mineralization originating from post-magmatic hydrothermal fluids based on its values should be recognized as an area of global importance. Geological processes that are connected to Neogene volcanic activity took place in the territory of the Dubnik Opal Mines and resulted in the formation of various geological products and processes represented by polymetallic mineral formation, opal formation, antimonite formation, and mineralization of the supergene stage, as well as the stratovolcano rock environment, which are of geoheritage significance. Remnants of intensive mining activity that took place during the past 2000 years provide opportunities for visitors to explore, study, and appreciate this unique geological heritage of international importance. However, geo-interpretation aimed at the general public (the largest group of potential visitors from sustainable geotourism development) and research on (geo)tourism and/or geoheritage for tourism purposes, as discussed in this paper, are lacking. Full article
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21 pages, 8165 KiB  
Article
Synthesis and Spatial Order Characterization of Controlled Silica Particle Sizes Organized as Photonic Crystals Arrays
by Silvia Adriana Estrada Alvarez, Isabella Guger, Jana Febbraro, Ayse Turak, Hong-Ru Lin, Yolanda Salinas and Oliver Brüggemann
Materials 2022, 15(17), 5864; https://doi.org/10.3390/ma15175864 - 25 Aug 2022
Cited by 4 | Viewed by 2703
Abstract
The natural occurrence of precious opals, consisting of highly organized silica particles, has prompted interest in the synthesis and formation of these structures. Previous research has shown that a highly organized photonic crystal (PhC) array is only possible when it is based on [...] Read more.
The natural occurrence of precious opals, consisting of highly organized silica particles, has prompted interest in the synthesis and formation of these structures. Previous research has shown that a highly organized photonic crystal (PhC) array is only possible when it is based on a low polydispersity index (PDI) sample of particles. In this study, a solvent-only variation method is used to synthesize different sizes of silica particles (SiPs) by following the traditional sol-gel Stöber approach. The controlled rate of the addition of the reagents promoted the homogeneity of the nucleation and growth of the spherical silica particles, which in turn yielded a low PDI. The opalescent PhC were obtained via self-assembly of these particles using a solvent evaporation method. Analysis of the spatial statistics, using Voronoi tessellations, pair correlation functions, and bond order analysis showed that the successfully formed arrays showed a high degree of quasi-hexagonal (hexatic) organization, with both global and local order. Highly organized PhC show potential for developing future materials with tunable structural reflective properties, such as solar cells, sensing materials, and coatings, among others. Full article
(This article belongs to the Special Issue Soft Photonic Crystals and Metamaterials)
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18 pages, 11005 KiB  
Article
Textural Characteristics of Noncrystalline Silica in Sinters and Quartz Veins: Implications for the Formation of Bonanza Veins in Low-Sulfidation Epithermal Deposits
by Tadsuda Taksavasu, Thomas Monecke and T. James Reynolds
Minerals 2018, 8(8), 331; https://doi.org/10.3390/min8080331 - 2 Aug 2018
Cited by 22 | Viewed by 11292
Abstract
Silica sinters forming at the Wairakei geothermal power plant in New Zealand are composed of noncrystalline opal-A that deposited rapidly from cooling geothermal liquids flashed to atmosphere. The sinter is laminated with alternating layers of variably compacted silicified filamentous microbes encased by chains [...] Read more.
Silica sinters forming at the Wairakei geothermal power plant in New Zealand are composed of noncrystalline opal-A that deposited rapidly from cooling geothermal liquids flashed to atmosphere. The sinter is laminated with alternating layers of variably compacted silicified filamentous microbes encased by chains of fused silica microspheres. Microscopic inspection of bonanza quartz vein samples from the Buckskin National low-sulfidation epithermal precious metal deposit in Nevada showed that colloform bands in these veins exhibit relic microsphere textures similar to those observed in the silica sinters from the Wairakei power plant. The textural similarity suggests that the colloform bands were originally composed of noncrystalline opal-A that subsequently recrystallized to quartz. The colloform bands contain dendrites of electrum and naumannite that must have grown in a yielding matrix of silica microspheres deposited at the same time as the ore minerals, implying that the noncrystalline silica exhibited a gel-like behavior. Quartz bands having other textural characteristics in the crustiform veins lack ore minerals. This suggests that ore deposition and the formation of the colloform bands originally composed of compacted microspheres of noncrystalline silica are genetically linked and that ore deposition within the bonanza veins was only episodic. Supersaturation of silica and precious metals leading to the formation of the colloform bands may have occurred in response to transient flashing of the hydrothermal liquids. Flashing of geothermal liquids may thus represent a key mechanism in the formation of bonanza precious metal grades in low-sulfidation epithermal deposits. Full article
(This article belongs to the Special Issue Mineralogy of Quartz and Silica Minerals)
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13 pages, 15667 KiB  
Article
Silica Colloid Ordering in a Dynamic Sedimentary Environment
by Moritz Liesegang and Ralf Milke
Minerals 2018, 8(1), 12; https://doi.org/10.3390/min8010012 - 7 Jan 2018
Cited by 7 | Viewed by 6936
Abstract
The formation of ordered particle arrays plays an essential role in nanotechnology, biological systems, and inorganic photonic structures in the geosphere. Here, we show how ordered arrays of amorphous silica spheres form in deeply weathered lithologies of the Great Artesian Basin (central Australia). [...] Read more.
The formation of ordered particle arrays plays an essential role in nanotechnology, biological systems, and inorganic photonic structures in the geosphere. Here, we show how ordered arrays of amorphous silica spheres form in deeply weathered lithologies of the Great Artesian Basin (central Australia). Our multi-method approach, using optical and scanning electron microscopy, X-ray microdiffraction, Raman spectroscopy, and electron probe microanalysis, reveals that particle morphologies trace the flow of opal-forming colloidal suspensions and document syn- and post-depositional deformation. The micromorphology of amorphous silica pseudomorphs suggests that the volume-preserving replacement of non-silicate minerals proceeds via an interface-coupled dissolution precipitation process. We conclude that colloid flow and post-depositional shearing create but also destroy natural photonic crystals. Contrary to previous studies, our results indicate that purely gravitational settling/ordering is the exception rather than the rule during the formation of three-dimensional periodic sphere arrays in the highly dynamic colloidal suspensions of chemically weathered clastic sediments. Full article
(This article belongs to the Special Issue Mineralogy of Quartz and Silica Minerals)
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