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Keywords = plant fiber-based degradable film

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22 pages, 5929 KiB  
Article
Development of Polylactic Acid Films with Alkali- and Acetylation-Treated Flax and Hemp Fillers via Solution Casting Technique
by Anamol Pokharel, Kehinde James Falua, Amin Babaei-Ghazvini, Mostafa Nikkhah Dafchahi, Lope G. Tabil, Venkatesh Meda and Bishnu Acharya
Polymers 2024, 16(7), 996; https://doi.org/10.3390/polym16070996 - 5 Apr 2024
Cited by 7 | Viewed by 2631
Abstract
This study aims to enhance value addition to agricultural byproducts to produce composites by the solution casting technique. It is well known that PLA is moisture-sensitive and deforms at high temperatures, which limits its use in some applications. When blending with plant-based fibers, [...] Read more.
This study aims to enhance value addition to agricultural byproducts to produce composites by the solution casting technique. It is well known that PLA is moisture-sensitive and deforms at high temperatures, which limits its use in some applications. When blending with plant-based fibers, the weak point is the poor filler–matrix interface. For this reason, surface modification was carried out on hemp and flax fibers via acetylation and alkaline treatments. The fibers were milled to obtain two particle sizes of <75 μm and 149–210 μm and were blended with poly (lactic) acid at different loadings (0, 2.5%, 5%, 10%, 20%, and 30%) to form a composite film The films were characterized for their spectroscopy, physical, and mechanical properties. All the film specimens showed C–O/O–H groups and the π–π interaction in untreated flax fillers showed lignin phenolic rings in the films. It was noticed that the maximum degradation temperature occurred at 362.5 °C. The highest WVPs for untreated, alkali-treated, and acetylation-treated composites were 20 × 10−7 g·m/m2 Pa·s (PLA/hemp30), 7.0 × 10−7 g·m/m2 Pa·s (PLA/hemp30), and 22 × 10−7 g·m/m2 Pa·s (PLA/hemp30), respectively. Increasing the filler content caused an increase in the color difference of the composite film compared with that of the neat PLA. Alkali-treated PLA/flax composites showed significant improvement in their tensile strength, elongation at break, and Young’s modulus at a 2.5 or 5% filler loading. An increase in the filler loadings caused a significant increase in the moisture absorbed, whereas the water contact angle decreased with an increasing filler concentration. Flax- and hemp-induced PLA-based composite films with 5 wt.% loadings showed a more stable compromise in all the examined properties and are expected to provide unique industrial applications with satisfactory performance. Full article
(This article belongs to the Special Issue Synthesis, Characterization and Applications of Natural Polymers)
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10 pages, 1947 KiB  
Article
Experiment on Cultivation Performance of Plant Fiber-Based Degradable Film in Paddy Field
by Xianglan Ming and Haitao Chen
Appl. Sci. 2020, 10(2), 495; https://doi.org/10.3390/app10020495 - 9 Jan 2020
Cited by 13 | Viewed by 3204
Abstract
To solve the problems of the damage of weed in paddy field on crop yield and quality, the impact of chemical herbicides on the ecological environment, and the soil pollution caused by plastic film mulching, the field-positioning test was carried out in 2015 [...] Read more.
To solve the problems of the damage of weed in paddy field on crop yield and quality, the impact of chemical herbicides on the ecological environment, and the soil pollution caused by plastic film mulching, the field-positioning test was carried out in 2015 to 2017. Taking Daohuaxiang 2 as the test material, three treatments (plant fiber-based degradable film, plastic film, and CK) were setup to investigate the effects of plant fiber-based degradable film on the weed inhibition, warming effect under mulching cultivation, rice yield, rice quality, and economic benefit. The results showed that compared with CK, the plant fiber-based degradable film and plastic film reduced the weed by 85.5% to 87.7% and 78.7% to 81.7%, respectively. Plant fiber-based degradable film mulching cultivation can increase the soil temperature of soil layer 0 to 0.1 m depth. In 2015 to 2017, rice yield with plant fiber-based degradable film increased by 8.71%, 7.53%, and 9.02%, respectively. Plant fiber-based degradable film can significantly reduce the hardness, increase its adhesion, and improve the eating quality of rice. Different films mulching had a certain impact on crop economic benefit. During the developmental stage of the panicle, the plant fiber-based degradable film began to crack, and by the blossom fruit period, the degradation rate reached the grade of 3 or 4. Therefore, the use of plant fiber-based degradable film instead of plastic film can reduce the amount of weed under the membrane and create a more suitable soil temperature, which was conducive to rice yield and quality. Full article
(This article belongs to the Section Applied Biosciences and Bioengineering)
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