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Keywords = isoprene polymerisation

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15 pages, 3389 KiB  
Communication
Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis
by Samantha Russell, Thierry Loiseau, Christophe Volkringer and Marc Visseaux
Inorganics 2015, 3(4), 467-481; https://doi.org/10.3390/inorganics3040467 - 9 Nov 2015
Cited by 12 | Viewed by 6140
Abstract
In this study, we are combining two areas of chemistry; solid-state coordination polymers (or Metal-Organic Framework—MOF) and polymerization catalysis. MOF compounds combining two sets of different lanthanide elements (Nd3+, Eu3+/Tb3+) were used for that purpose: the use [...] Read more.
In this study, we are combining two areas of chemistry; solid-state coordination polymers (or Metal-Organic Framework—MOF) and polymerization catalysis. MOF compounds combining two sets of different lanthanide elements (Nd3+, Eu3+/Tb3+) were used for that purpose: the use of neodymium was required due to its well-known catalytic properties in dienes polymerization. A second lanthanide, europium or terbium, was included in the MOF structure with the aim to provide luminescent properties. Several lanthanides-based MOF meeting these criteria were prepared according to different approaches, and they were further used as catalysts for the polymerization of isoprene. Stereoregular cis-polyisoprene was received, which in some cases exhibited luminescent properties in the UV-visible range. Full article
(This article belongs to the Special Issue Rare Earth and Actinide Complexes)
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