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Keywords = isomeric praealtaesters

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15 pages, 1342 KiB  
Article
Essential Oil Composition of Bupleurum praealtum and Bupleurum affine: New Natural Constituents
by Milica D. Nešić, Milan S. Nešić, Milan Ž. Dimitrijević and Niko S. Radulović
Plants 2024, 13(15), 2076; https://doi.org/10.3390/plants13152076 - 26 Jul 2024
Cited by 1 | Viewed by 1329
Abstract
This study explores the chemical composition of essential oils from two Serbian Bupleurum species (Apiaceae), Bupleurum praealtum L. and Bupleurum affine L., traditionally recognized in Chinese medicine for their therapeutic potential but less studied for their essential oils. Through GC-MS analysis, we identified 230 [...] Read more.
This study explores the chemical composition of essential oils from two Serbian Bupleurum species (Apiaceae), Bupleurum praealtum L. and Bupleurum affine L., traditionally recognized in Chinese medicine for their therapeutic potential but less studied for their essential oils. Through GC-MS analysis, we identified 230 constituents, revealing distinct profiles between the species. Perillyl 2-methylbutanoate was identified in B. affine oil for the first time, confirmed using synthetic approaches and characterized by advanced spectroscopic techniques, including two-dimensional NMR and spin-simulation of 1H NMR spectra. Additionally, new natural compounds, including tentatively identified 4-decyl acetate and 4-undecyl acetate, were discovered. The study also reports five stereoisomeric esters of tetradeca-5,7,9,11-tetraen-1-ol. These findings significantly contribute to the understanding of the phytochemical diversity within the genus Bupleurum and underscore potential differences in ecological adaptations or biosynthetic pathways among species. Full article
(This article belongs to the Special Issue Essential Oils: Chemistry and Biology, and Their Interplay)
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