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Keywords = hydrogen isotope separation (HIS)

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23 pages, 5981 KB  
Review
A Mini Review of Advances in Porous Materials Designing for Hydrogen Isotope Separation
by Huafeng Zhu, Liangbo Xu, Jia Li, Duanwei He and Jingchuan Wang
Materials 2024, 17(23), 5708; https://doi.org/10.3390/ma17235708 - 22 Nov 2024
Viewed by 1519
Abstract
The separation of mixtures of hydrogen isotopes is one of the greatest challenges of modern separation technology. A newly proposed separation mechanism, the quantum sieving (QS) effect, is expected to achieve high separation factors, the main desired properties for hydrogen isotope separation (HIS). [...] Read more.
The separation of mixtures of hydrogen isotopes is one of the greatest challenges of modern separation technology. A newly proposed separation mechanism, the quantum sieving (QS) effect, is expected to achieve high separation factors, the main desired properties for hydrogen isotope separation (HIS). Metal–organic frameworks (MOFs) and zeolites are excellent candidates to study these quantum effects because of their well-defined and tunable pore structure and the potential to introduce strong adsorption sites directly into the framework structure. This paper briefly discusses the fundamentals of QS of hydrogen isotopes in nanoporous materials, mainly including kinetic quantum sieving (KQS) and chemical affinity quantum sieving (CAQS). Recent experimental advances in the separation of hydrogen isotopes from MOFs and zeolites are highlighted. Full article
(This article belongs to the Collection Porous Materials and Nanozeolites)
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