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Keywords = cycloboration

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5 pages, 1370 KiB  
Proceeding Paper
Ti-Catalyzed Reaction of β-Pinene with BF3·THF
by Liliya I. Tulyabaeva, Rustam R. Salakhutdinov, Tatiyana V. Tyumkina and Arthur R. Tulyabaev
Chem. Proc. 2022, 12(1), 42; https://doi.org/10.3390/ecsoc-26-13529 - 14 Nov 2022
Cited by 1 | Viewed by 1407
Abstract
The reaction between β-pinene and BF3·THF in the presence of the catalytic system Cp2TiCl2/Mg was carried out for the first time to obtain a 1-fluoro-substituted boraspirane, undescribed previously. The reaction proceeds stereoselectively, but is complicated by the [...] Read more.
The reaction between β-pinene and BF3·THF in the presence of the catalytic system Cp2TiCl2/Mg was carried out for the first time to obtain a 1-fluoro-substituted boraspirane, undescribed previously. The reaction proceeds stereoselectively, but is complicated by the rearrangement of the β-pinene under the Ti-catalyzed reaction conditions. Full article
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