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Keywords = bromoylides

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5 pages, 205 KiB  
Article
A Facile One-Pot Synthesis of α-Bromo-α,β-unsaturated Esters from Alcohols
by Usama Karama, Zeid Al-Othman, Abdullah Al-Majid and Abdulrahman Almansour
Molecules 2010, 15(5), 3276-3280; https://doi.org/10.3390/molecules15053276 - 4 May 2010
Cited by 12 | Viewed by 8267
Abstract
Treatment ofN-bromosuccinimide (NBS) with (carboethoxymethylene) triphenylphosphorane (1) in CH2Cl2 followed by the addition of an alcohol in the presence of manganese dioxide under ultrasonic irradiation constitutes a stereoselective one-pot procedure for the preparation of Z-configured α–bromo-α,β-unsaturated esters in good to excellent yield. Full article
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