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Keywords = Morpholine Tetrafluoroborate

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13 pages, 3286 KiB  
Article
Enhancing the Performance and Stability of Perovskite Solar Cells via Morpholinium Tetrafluoroborate Additive Engineering: Insights and Implications
by Jianxiao Bian, Yingtang Sun, Jinchang Guo, Xin Liu and Yang Liu
Coatings 2023, 13(9), 1528; https://doi.org/10.3390/coatings13091528 - 31 Aug 2023
Cited by 3 | Viewed by 2105
Abstract
Perovskite solar cells (PSCs), since their inception in 2009, have experienced a meteoric rise in power conversion efficiencies (PCEs), challenging established photovoltaic technologies. However, their commercial deployment is hindered by stability and performance issues related to the presence of defects at the perovskite [...] Read more.
Perovskite solar cells (PSCs), since their inception in 2009, have experienced a meteoric rise in power conversion efficiencies (PCEs), challenging established photovoltaic technologies. However, their commercial deployment is hindered by stability and performance issues related to the presence of defects at the perovskite surface and grain boundaries. This study focused on the exploration of Morpholinium tetrafluoroborate (MOT) as a post-treatment additive to mitigate these challenges. Comprehensive characterization techniques revealed that the synergistic action of Morpholine and BF4 ions in MOT substantially improved the quality of the perovskite films and passivates surface and bulk defects, yielding notable enhancements in device PCE and stability. MOT-doped PSCs exhibited a PCE of 23.83% and retain 92% of the initial PCE after 2000 h of continuous illumination under one sun condition. The findings underscore the significance of additive engineering in advancing perovskite solar cell technology, opening up prospects for high-performing and durable perovskite photovoltaic devices. Full article
(This article belongs to the Special Issue Recent Advances in the Development of Thin Films)
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