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Keywords = Exclusion host-guest assembly

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9 pages, 716 KiB  
Article
Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
by Li-Mei Zheng, Yun-Qian Zhang, Jin-Ping Zeng, Yan Qiu, Da-Hai Yu, Sai-Feng Xue, Qian-Jiang Zhu and Zhu Tao
Molecules 2008, 13(11), 2814-2822; https://doi.org/10.3390/molecules13112814 - 12 Nov 2008
Cited by 7 | Viewed by 11515
Abstract
A host-guest assembly, [(C40H44N24O12)·(C6H5NO3)8·13(H2O)] (1), based on a partial substituted cucurbituril, α,δ-tetramethylcucurbit[6]uril (TMeQ[6]), and 4-nitrophenol was synthesized and structurally characterized by single-crystal X-ray diffraction. A [...] Read more.
A host-guest assembly, [(C40H44N24O12)·(C6H5NO3)8·13(H2O)] (1), based on a partial substituted cucurbituril, α,δ-tetramethylcucurbit[6]uril (TMeQ[6]), and 4-nitrophenol was synthesized and structurally characterized by single-crystal X-ray diffraction. A combination of hydrogen-bonding between the latticed water molecule and the hydroxyl group of 4-nitrophenol, the hydroxyl group of 4-nitrophenol and the carbonyl groups lining the portals in additon, the C-H···π interactions between the 4-nitrophenol molecules could be the driving forces of formation such an exclusion host-guest assembly. Full article
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