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The application techniques and composition of green and blue-green pigments in the Maijishan Grottoes were explored by utilizing microscopic observation, Raman spectroscopy, and SEM-EDX analysis. For the first time, lavendulan and high-purity botallackite were identified in these grottoes, in addition to the commonly found malachite and atacamite. These discoveries suggest that several caves in the Maijishan Grottoes were originally painted in blue-green tones, which have since altered to the current green or dark green hues. It was also revealed that the application of green mixed pigments involved layering malachite over basic copper chloride, rather than blending them together. Moreover, variations in the composition and placement of white ash layers indicate that the use of mixed pigments was likely due to repainting rather than initial decorative purposes. These findings significantly enhance our understanding of ancient painting techniques and provide crucial data for the conservation and restoration of cultural heritage in the Maijishan Grottoes. Full article

The island of Malta, despite its small size, boasts a great variety of landscapes and landforms, offering a wide range of geological and geomorphological features of great interest. The identification and assessment of geosites can contribute to the preservation, protection, and promotion of this rich geodiversity. In addition, geosites have a high potential of attracting geotourists, thus also contributing to the development of the local economy. Tourism plays a key role for the Maltese Islands, with Malta’s tourism direct contribution to GDP being among the highest in Europe. Thus, geotourism could represent a significant resource for Malta, though it has yet to receive the attention and recognition it deserves. Within this framework, this work aims to highlight the role of geoheritage and geotourism as potential resources for the enhancement of sustainable tourism and geoconservation in the southern sector of Malta. This region of Malta receives less visitors compared with the northern sector of the island, which is popular for its sandy beaches. To this end, potential geosites were inventoried and quantitatively assessed using a commonly applied methodology tailored to the local setting. The results of this evaluation let to identify 18 potential geosites that can be recognized as both parts of the Maltese natural heritage and tourist resources. Among these 18 sites, we identified four priority geosites which could be incorporated into a potential geotourism route to also highlight the valuable elements of the cultural heritage located in the vicinity. Moreover, the assessment methodology, applied for the first time in the investigated area, has proven to be a valuable support for geosite identification and can be extended to other Maltese regions. Full article

The Yungang Grottoes, excavated during the 5th to 6th centuries AD, stand as a pinnacle of Buddhist sculpture, representing a precious world cultural heritage. Since their excavation, the grottoes have undergone multiple phases of painting, with a significant amount of pigment still present on the surfaces of the stone carvings. Since the 1990s, two large-scale archaeological excavations have been conducted on both the front ground and the summit of Yungang Grottoes. During these excavations, various artifacts with accompanying pigments were unearthed, encompassing stone carvings, grinding tools, architectural components, fragments of murals, and remnants of clay sculptures, spanning the historical periods of the Northern Wei, Liao-Jin, and Ming-Qing dynasties. Using portable X-ray fluorescence spectrometry, portable microscopy, polarizing microscopy, scanning electron microscopy–energy dispersive X-ray spectroscopy, and confocal Raman microscopy, we conducted a comprehensive analysis of these painted elements. The investigation revealed the presence of hematite, vermilion, goethite, malachite, calcium carbonate, lead white, and ivory black pigments in the Northern Wei samples. The Liao-Jin samples exhibited hematite, while the Ming-Qing samples contained vermilion, minium, atacamite, lead white, and Prussian blue. Full article