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Keywords = Bi2Sn2O7/g-C3N4

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34 pages, 6224 KB  
Review
Anions of α-Amino Acids as (O,N)-Donor Ligands in Si-, Ge- and Sn-Coordination Chemistry
by Anne Seidel and Jörg Wagler
Molecules 2025, 30(4), 834; https://doi.org/10.3390/molecules30040834 - 11 Feb 2025
Cited by 1 | Viewed by 1666
Abstract
This review gives an overview of Si-, Ge- and Sn-compounds with (O,N)-bi- and -oligodentate ligands, which have the α-amino carboxylic acid motif N–C(R,R′)–C(=O)O in common (R,R′ = H or hydrocarbyl). While the amino acids themselves [...] Read more.
This review gives an overview of Si-, Ge- and Sn-compounds with (O,N)-bi- and -oligodentate ligands, which have the α-amino carboxylic acid motif N–C(R,R′)–C(=O)O in common (R,R′ = H or hydrocarbyl). While the amino acids themselves are encountered as mono- and di-anionic ligands, modifications at the N-terminus (e.g., extension of the ligand backbone by, e.g., additional alkane carboxylic acid groups) give rise to a wealth of ligands, which bear the α-amino carboxylic acid motif. With particular interest in the coordination features of these ligands, crystallographically characterized complexes are the focus of this review. Full article
(This article belongs to the Special Issue Exclusive Feature Papers in Inorganic Chemistry, 2nd Edition)
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13 pages, 3196 KB  
Article
Facile Construction of Bi2Sn2O7/g-C3N4 Heterojunction with Enhanced Photocatalytic Degradation of Norfloxacin
by Zhengru Zhu, Haiwen Xia, Hong Li and Songlin Han
Inorganics 2022, 10(9), 131; https://doi.org/10.3390/inorganics10090131 - 1 Sep 2022
Cited by 23 | Viewed by 2933
Abstract
To mitigate antibiotic residues in the water environment, Bi2Sn2O7/g-C3N4 (BSCN) heterojunction was fabricated by a facile ultrasound-assisted hydrothermal method. The microstructure, morphology, and optical properties of Bi2Sn2O7/g-C3 [...] Read more.
To mitigate antibiotic residues in the water environment, Bi2Sn2O7/g-C3N4 (BSCN) heterojunction was fabricated by a facile ultrasound-assisted hydrothermal method. The microstructure, morphology, and optical properties of Bi2Sn2O7/g-C3N4 heterojunction was studied by XRD, FTIR, XPS, SEM, TEM, UV–Vis DRS, and PL. The degradation rate of 20 mg/L norfloxacin (NOR) under visible light for 3 h was adopted as one of the indexes to evaluate the photocatalytic performance of Bi2Sn2O7/g-C3N4 heterojunction. Embellished with 20% Bi2Sn2O7 (BSO), the Bi2Sn2O7/g-C3N4 heterojunction decomposed 94% NOR in the experimental solution, which was 2.35 and 3.03 times as much as pristine g-C3N4 and bare Bi2Sn2O7, respectively. In addition, the Bi2Sn2O7/g-C3N4 heterojunction still eliminated 89% of NOR after five cycles, portending outstanding stability and cyclability of photocatalytic activity. A possible photocatalytic mechanism of Bi2Sn2O7/g-C3N4 heterojunction for NOR degradation is proposed. Full article
(This article belongs to the Special Issue Inorganics: 10th Anniversary)
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