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In this paper, an improved 100 CMM regenerative thermal oxidizer (RTO) is implemented for low-emission combustion. The existing RTO system is a cylindrical drum structure that cyclically introduces and discharges VOC gas into and from the rotating disk, and which achieves excellent energy efficiency with a heat recovery rate of more than 95%. However, the drive shaft designed under the RTO combustion chamber increases wear around the rotating shaft due to the load of the combustion chamber and there is a problem that the untreated gas is simultaneously released through the outlet due to the channeling phenomenon of the combustion chamber and the drive shaft. In addition, the combustion chamber, used at a high temperature of 800 °C, may cause serious problems such as rotation stop or explosion due to pollutants, dust accumulation, and thermal expansion in the chamber. Particularly when treating VOCs harmful gasses, RTO performance may be degraded due to the burner’s non-uniform temperature control and unstable combustion function. To solve this problem, first, the design of the combustion chamber rotating plate driving device is improved. Second, when treating high concentration VOC gas, the design of combustion chamber considers a temperature increase of up to 920 °C or more. For this, the diameter of the gas burner is 125 mm and the outlet dimension is set to 650 mm × 650 mm to effectively discharge high-temperature waste heat. Third, the heat storage material in the combustion chamber is composed of a ceramic block with a thickness of 250 mm, and the outer diameter and height of the combustion chamber are set to, 2530 mm and 1875 mm, respectively, to optimize gas residence time and heat insulation thickness. Fourth, we supplement safe operation by applying the trip control algorithm of the programmable logic controller (PLC) panel for failure prediction of RTO and the Edge-IoT-based intelligent algorithm for this. Finally, we evaluate the economic performance of 100 CMM RTO by conducting empirical experiments to analyze changes in VOCs removal efficiency, nitrogen oxide emission concentration, and total hydrocarbon (THC) concentration through 10 CMM design and implementation. Full article