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Authors = Seiichi Toyoshima

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9 pages, 212 KiB  
Article
Preparation of SRN1-Type Coupling Adducts from Aliphatic gem-Dinitro Compounds in Ionic Liquids
by Akio Kamimura and Seiichi Toyoshima
Molecules 2012, 17(5), 4782-4790; https://doi.org/10.3390/molecules17054782 - 25 Apr 2012
Viewed by 5154
Abstract
SRN1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with [...] Read more.
SRN1-type coupling adducts are readily prepared by the reaction between a-sulfonylesters or a-cyanosulfones and gem-dinitro compounds in ionic liquids. The reactions progress smoothly and recovered ionic liquids can be used for several iterations, as long as they are washed with water to remove alkali metallic salts. The reaction rate is slower than the corresponding SRN1 reaction in DMSO, but no acceleration on irradiation or no inhibition in the presence of m-DNB are observed. Full article
(This article belongs to the Collection Ionic Liquids)
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