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Authors = Jeremy H. Yune

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18 pages, 720 KiB  
Article
Enantioselectivity Induced by Oxazaborolidine Supported on Mesoporous Silica or by Its Analog in Homogeneous Phase
by Jeremy H. Yune, Françoise Quignard and Karine Molvinger
Molecules 2010, 15(5), 3643-3660; https://doi.org/10.3390/molecules15053643 - 18 May 2010
Cited by 3 | Viewed by 9163
Abstract
The impact of immobilization of oxazaborolidines supported on silica via different substituents on the boron and nitrogen atoms is evaluated in the enantioselective reduction of acetophenone. The performances of the homogeneous analog oxazaborolidines and silica supported-ones are compared by varying different parameters. This [...] Read more.
The impact of immobilization of oxazaborolidines supported on silica via different substituents on the boron and nitrogen atoms is evaluated in the enantioselective reduction of acetophenone. The performances of the homogeneous analog oxazaborolidines and silica supported-ones are compared by varying different parameters. This article deals with the synthesis, characterization and catalytic evaluation of silica-supported oxazaborolidines, their recycling capabilities and regeneration limitations. Full article
(This article belongs to the Special Issue Heterogeneous Catalysis)
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