Search Results (6)

An important aspect of lithium-ion batteries related to lifetime and aging is the change in state within the cells, which results from the expansion of the electrode materials and causes internal stress during operation. In this work, fiber optical sensors by means of Bragg gratings are utilized to determine the internal strain in the anode material. The collected data were employed to approximate aging-related changes in anode strain using a combination of established methods, such as the differential voltage and incremental capacity analysis. Moreover, additional methodologies are proposed and explored, substituting electrical data with optical strain measurements to quantify degradation effects linked to changes in strain. During the cycling of the cell, changes in the strain behavior have been observed and can be partially attributed to changes in the cell’s electrochemical composition. The methods suggested have proven effective in providing additional insights into the current state of the cells and tracking changes over time due to detected degradation effects. Full article

Optical sensors, such as fiber Bragg gratings, offer advantages compared to other sensors in many technological fields due to their outstanding characteristics. This sensor technology is currently transferred to polymer waveguides that provide the potential for cost-effective, easy, and flexible manufacturing of planar structures. While sensor production itself, in the majority of cases, is performed by means of phase mask technique, which is limited in terms of its degrees of freedom, other inscription techniques enable the manufacture of more adaptable sensor elements for a wider range of applications. In this article, we demonstrate the point-by-point femtosecond laser direct inscription method for the processing of polymer Bragg gratings into waveguides of the epoxy-based negative photoresist material EpoCore for a wavelength range around 850 nm. By characterizing the obtained grating back-reflection of the produced sensing element, we determined the sensitivity for the state variables temperature, humidity, and strain to be 45 pm/K, 19 pm/%, and 0.26 pm/µε, respectively. Individual and more complex grating structures can be developed from this information, thus opening new fields of utilization. Full article

We present the manufacturing and utilization of an all-polymer arrayed waveguide grating (AWG) interacting with a fiber Bragg grating (FBG) for battery status monitoring on the example of a 40 Ah lithium-ion battery. The AWG is the main component of a novel low-cost approach for an optical interrogation unit to track the FBG peak wavelength by means of intensity changes monitored by a CMOS linear image sensor, read out by a Teensy 3.2 microcontroller. The AWG was manufactured using laser direct lithography as an all-polymer-system, whereas the FBG was produced by point-by-point femtosecond laser writing. Using this system, we continuously monitored the strain variation of a battery cell during low rate charge and discharge cycles over one month under constant climate conditions and compared the results to parallel readings of an optical spectrum analyzer with special attention to the influence of the relative air humidity. We found our low-cost interrogation unit is capable of precisely and reliably capturing the typical strain variation of a high energy pouch cell during cycling with a resolution of 1 pm and shows a humidity sensitivity of −12.8 pm per %RH. Full article

Developed societies with advanced economic performance are undoubtedly coupled with the availability of electrical energy. Whilst industrialized nations already started to decrease associated carbon emissions in many business sectors, e.g., by substituting combustion engines with battery-powered vehicles, less developed countries still lack broad coverage of reliable electricity supply, particularly in rural regions. Progressive electrification leads to a need for storage capacity and thus to increasing availability of advanced battery systems. To achieve a high degree of sustainability, re-used batteries from the electromobility sector are appropriate, as they do not consume further primary resources and still have sufficient residual capacity for stationary electrical storage applications. In this article, a blueprint for the electrification of a remote region by utilizing second-life lithium ion traction batteries for an integrated energy system in a stand-alone grid is presented and the implementation by the example case of a Tanzanian island in Lake Victoria is demonstrated. First, economic potentials and expected trends in the disposability of second-life lithium ion batteries and their foreseeable costs are outlined. Subsequently, key decision variables are identified to evaluate logistic aspects and the feasibility of the implementation of an off-grid electrical system in remote areas for economically and geographically unfavorable environments. The practical realization is pictured in detail with a focus on technical performance and safety specificities associated with second-life applications. Therefore, a new type of battery management system is introduced, which meets the special requirements of climate compatibility, low maintenance, enhanced cell balancing capability and cell configuration flexibility, and combined with a fiber-optical sensor system, provides reliable status monitoring of the battery. By carrying out on-site measurements, the overall system efficiency is evaluated along with a sustainability analysis. Finally, the socioeconomic and humanitarian impact for the people on the island is debated. Full article

In this scientific publication, a new sensor approach for status monitoring, such as state of charge and state of health, of lithium ion batteries by using special Bragg gratings inscribed into standard optical glass fibers is presented. In addition to well-known core gratings, embedded into the anode of 5 Ah lithium ion pouch cells as a strain monitoring unit, the manufacturing of a surface cladding waveguide Bragg grating sensor incorporated into the cell’s separator, that is sensitive to changes of the refractive index of the surrounding medium, is demonstrated. On the basis of the experiments carried out, characteristics of the cell behavior during standard cyclization and recognizable marks in subsequent post-mortem analyses of the cell components are shown. No negative influence on the cell performance due to the integrated sensors have been observed; however, the results show a clear correlation between fading cell capacity and changes of the interior optical signals. Additionally, with the novel photonic sensor, variations in the electrolyte characteristics are determinable as the refractive index of the solution changes at different molar compositions. Furthermore, with the manufactured battery cells, abuse tests by overcharging were conducted, and it was thereby demonstrated how internal battery sensors can derive additional information beyond conventional battery management systems to feasibly prevent catastrophic cell failures. The result of the research work is an early stage photonic sensor that combines chemical, mechanical and thermal information from inside the cell for an enhanced battery status analysis. Full article

Lithium ion batteries play an increasing role in everyday life, giving power to handheld devices or being used in stationary storage solutions. Especially for medium or large scale solutions, the latter application confines a huge amount of energy within a small volume; however, increasing the hazard potential far above the common level. Furthermore, as the safety hazards of lithium ion cells have been known for years, impressively shown by several burning cars or laptops, the need for a further enhancement of the safety of these systems is rising. This manuscript presents measurements of the gas emission from lithium ion batteries in case of a malfunction for different scenarios, showing a large variety of species with mostly toxic to highly toxic properties. The measurements were carried out using a combination of gas chromatography-mass spectrometry (GC-MS), quadrupole mass spectrometry (QMS), photoacoustic spectroscopy, and chemical analysis. It is shown that the inflammation of a cell can be overcome, also preventing a cascading effect to neighboring cells, but giving rise to worse toxic gas emission. Furthermore, a filtration concept is presented that decreases the concentration of the emitted components significantly and promises filtration below immediately dangerous to life or health (IDLH) equivalent levels. Full article