Table of Contents
Molecules, Volume 21, Issue 11 (November 2016)
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Cover Story (view full-size image) Hypervalent pentacoordinated phosphoranes are an interesting class of organophosphorus compounds [...] Read more. Hypervalent pentacoordinated phosphoranes are an interesting class of organophosphorus compounds due to their unusual trigonal bipyramid structure, the center of which comprises a phosphorus atom with a valence shell expanded from 8 to 10 electrons. Such a structure can induce chirality provided that the substituents are properly located. This is particularly discernible in the case of mono- and bi-cyclic derivatives of this kind. This review summarizes recent achievements in this field. View the paper