Special Issue "Biodegradability and Environmental Sciences"
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A special issue of International Journal of Environmental Research and Public Health (ISSN 1660-4601).
Deadline for manuscript submissions: closed (31 July 2009)
Special Issue Editors
Managing Editor
Dr. Shu-Kun Lin
MDPI AG, Kandererstrasse 25, CH-4057 Basel, Switzerland
Website: http://www.mdpi.org/lin/
E-Mail: lin@mdpi.com
Phone: +41 79 322 33 79
Interests: Gibbs paradox; entropy; symmetry; similarity; diversity; information theory; thermodynamics; process irreversibility or spontaneity; stability; nature of the chemical processes; molecular recognition; open access journals
Editorial Advisor
Dr. Naozumi Teramoto
Department of Life and Environmental Sciences, Faculty of Engineering, Chiba Institute of Technology 2-17-1, Tsudanuma, Narashino, Chiba 275-0016, Japan
E-Mail: teramoto-n@sea.it-chiba.ac.jp
Phone: +81 47 478 0406
Fax: +81 47 478 0439
Interests: biomaterial; bio-based polymer; bioplastics; biodegradable polymer; biopolymer; composite material comprising a polymer matrix
Special Issue Information
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Summary
To protect environment, the biodegradable materials have great advantage. However, sometimes, for material stability, biodegradation is a problem, for example, the biomedical materials.
- free for readers, with low publishing fees paid by authors or their institutions- Free publication for manuscripts submitted by end of 2008.
- Rapid publication: accepted papers are immediately published online (we started to publish papers quickly since September 2008). The printed edition will only be continued for the Proceedings of the yearly International Symposiums on Recent Advances in Environmental Health Research starting 2009.
Submission
The Int. J. Environ. Res. Public Health (ISSN 1660-4601) was launched in 2004 and is an Open Access journal, with the main Editorial Office located in Basel, Switzerland. It has been accepted for coverage in Science Citation Index Expanded, available as the Web of Science and in Current Contents/Agriculture, Biology, and Environmental Sciences. Coverage will begin with the 2009 issues. This journal is also abstracted and indexed very rapidly by Chemical Abstracts, MedLine/PubMed and EMBASE. The IJERPH maintains a rapid editorial procedure and a rigorous peer-review system. Well written papers have been peer-reviewed and published in less than 4 weeks from manuscript submission. All papers published in IJERPH have DOI numbers.
All papers should be submitted to ijerph@mdpi.com with copy to the guest editor. To be published continuously until the deadline and papers will be listed together at this special issue website.
Please visit the Instructions for Authors page before submitting a paper. Open Access publication fees are 300 CHF per paper. English correction fees (250 CHF) will be added in certain cases (550 CHF per paper for those papers that require extensive additional formatting and/or English corrections.). Free publication in open access format for manuscripts submitted in 2008.
Keywords
- biodegradable polymers, organics or materials
Published Papers (10 papers)
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Received: 6 November 2008 / Accepted: 6 January 2009 / Published: 13 January 2009
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Abstract: Aromatic compounds are among the most prevalent and persistent pollutants in the environment. Petroleum-contaminated soil and sediment commonly contain a mixture of polycyclic aromatic hydrocarbons (PAHs) and heterocyclic aromatics. Aromatics derived from industrial activities often have functional groups such as alkyls, halogens and nitro groups. Biodegradation is a major mechanism of removal of organic pollutants from a contaminated site. This review focuses on bacterial degradation pathways of selected aromatic compounds. Catabolic pathways of naphthalene, fluorene, phenanthrene, fluoranthene, pyrene, and benzo[a]pyrene are described in detail. Bacterial catabolism of the heterocycles dibenzofuran, carbazole, dibenzothiophene, and dibenzodioxin is discussed. Bacterial catabolism of alkylated PAHs is summarized, followed by a brief discussion of proteomics and metabolomics as powerful tools for elucidation of biodegradation mechanisms.
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Received: 9 October 2008 / Accepted: 24 January 2009 / Published: 1 February 2009
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Abstract: Ectomycorrhiza (ECM) communities can be described on a species level or on a larger scale at an ecosystem level. Here we show that the species level approach of successional processes in ECM communities is not appropriate for understanding the diversity patterns of ECM communities at contaminated sites. An ecosystem based approach improves predictability since different biotic and abiotic factors are included. However, it still does not take into account the hierarchical structure of the ecosystem. We suggest that diversity patterns of ECMs communities in forests can best be investigated at three levels. This hypothetical approach for investigation can be tested at sites of secondary succession in areas contaminated with metals. Once the diversity patterns are appropriately described by a hierarchical ecosystem approach, to the species level is used to explain these patterns by populational and ecotoxicological mechanisms.
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Received: 22 January 2009 / Accepted: 3 February 2009 / Published: 5 February 2009
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Abstract: Flame-retardants (FR) are a group of anthropogenic environmental contaminants used at relatively high concentrations in many applications. Currently, the largest market group of FRs is the brominated flame retardants (BFRs). Many of the BFRs are considered toxic, persistent and bioaccumulative. Bioremediation of contaminated water, soil and sediments is a possible solution for the problem. However, the main problem with this approach is the lack of knowledge concerning appropriate microorganisms, biochemical pathways and operational conditions facilitating degradation of these chemicals at an acceptable rate. This paper reviews and discusses current knowledge and recent developments related to the environmental fate and impact of FRs in natural systems and in engineered treatment processes.
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Received: 18 February 2009 / Accepted: 10 March 2009 / Published: 17 March 2009
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Abstract: The treatment of paper mill effluent for COD, TOC, total phenols and color removal was investigated using combined activated sludge-ozonation processes and single processes. The combined activated sludge-O3/pH 10 treatment was able to remove around 80% of COD, TOC and color from Kraft E1 effluent. For the total phenols, the efficiency removal was around 70%. The ozonation post treatment carried out at pH 8.3 also showed better results than the single process. The COD, TOC, color and total phenols removal efficiency obtained were 75.5, 59.1, 77 and 52.3%, respectively. The difference in the concentrations of free radical produced by activated sludge-O3/pH 10 and activated sludge-O3/pH 8.3 affected mainly the TOC and total phenol removal values.
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Received: 1 February 2009 / Accepted: 17 March 2009 / Published: 9 April 2009
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Abstract: The effects on the environment of pollution, particularly that caused by various industrial activities, have been responsible for the accelerated fluxes of organic and inorganic matter in the ecosphere. Xenobiotics such as phenol, phenolic compounds, polycyclic aromatic hydrocarbons (PAHs), and heavy metals, even at low concentrations, can be toxic to humans and other forms of life. Many of the remediation technologies currently being used for contaminated soil and water involve not only physical and chemical treatment, but also biological processes, where microbial activity is the responsible for pollutant removal and/or recovery. Fungi are present in aquatic sediments, terrestrial habitats and water surfaces and play a significant part in natural remediation of metal and aromatic compounds. Fungi also have advantages over bacteria since fungal hyphae can penetrate contaminated soil, reaching not only heavy metals but also xenobiotic compounds. Despite of the abundance of such fungi in wastes, penicillia in particular have received little attention in bioremediation and biodegradation studies. Additionally, several studies conducted with different strains of imperfecti fungi, Penicillium spp. have demonstrated their ability to degrade different xenobiotic compounds with low co-substrate requirements, and could be potentially interesting for the development of economically feasible processes for pollutant transformation.
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Received: 3 February 2009 / Accepted: 23 March 2009 / Published: 9 April 2009
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Abstract: The aerobic biodegradability of the high explosive CL-20 by activated sludge and the white rot fungus Phanerochaete chrysosporium has been investigated. Although activated sludge is not effective in degrading CL-20 directly, it can mineralize the alkaline hydrolysis products. Phanerochaete chrysosporium degrades CL-20 in the presence of supplementary carbon and nitrogen sources. Biodegradation studies were conducted using various nutrient media under diverse conditions. Variables included the CL-20 concentration; levels of carbon (as glycerol) and ammonium sulfate and yeast extract as sources of nitrogen. Cultures that received CL-20 at the time of inoculation transformed CL-20 completely under all nutrient conditions studied. When CL-20 was added to pre-grown cultures, degradation was limited. The extent of mineralization was monitored by the 14CO2 time evolution; up to 51% mineralization was achieved when the fungus was incubated with [14C]-CL-20. The kinetics of CL-20 biodegradation by Phanerochaete chrysosporium follows the logistic kinetic growth model.
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Received: 7 January 2009 / Accepted: 9 April 2009 / Published: 17 April 2009
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Abstract: A group of compounds structurally similar to bis(4-hydroxyphenyl)propane (bisphenol A, BPA) are called bisphenols (BPs), and some of them can partially replace BPA in industrial applications. The production and consumption of BPs other than BPA, especially those of bis(4-hydroxyphenyl)methane (bisphenol F, BPF) and bis(4-hydroxy-phenyl)sulfone (bisphenol S, BPS), have increased recently, leading to their detection as contaminants in the aquatic environment. The three compounds tested 100% positive for estrus response in 1936 and concerns about their health risks have been increasing. Abundant data on degradation of bisphenols (BPs) has been published, but results for biodegradation of BPs in seawater are lacking. However, several research groups have focused on this topic recently. In this study, the biodegradation behaviors of three BPs, namely BPA, BPF and BPS, in seawater were investigated using TOC Handai (TOC, potential test) and river (sea) die-away (SDA, simulation test) methods, which are both a kind of river-die-away test. The main difference between the tests is that indigenous microcosms remain in the sampled raw seawater for the SDA experiments, but they are removed through filtration and dispersed into artificial seawater for the TOC experiments. The BPs, except for BPS, were degraded using both methods. The SDA method produced better biodegradation results than the TOC method in terms of degradation time (both lag and degradation periods). Biodegradation efficiencies were measured at 75-100% using the SDA method and 13-63% using the TOC method. BPF showed better degradation efficiency than BPA, BPF was > 92% and BPA 83% depleted according to the SDA tests. BPS degradation was not observed. As a conclusion, the biodegradability of the three BPs in seawater could be ranked as BPF > BPA >> BPS. BPF is more biodegradable than BPA in seawater and BPS is more likely to accumulate in the aquatic environment. BPS poses a lower risk to human health and to the environment than BPA or BPF but it is not amenable to biodegradation and might be persistent and become an ecological burden. Thus other degradation methods need to be found for the removal of BPS in the environment.
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Received: 28 July 2009 / Accepted: 7 August 2009 / Published: 12 August 2009
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Abstract: A number of toxic synthetic organic compounds can contaminate environmental soil through either local (e.g., industrial) or diffuse (e.g., agricultural) contamination. Increased levels of these toxic organic compounds in the environment have been associated with human health risks including cancer. Plant-associated bacteria, such as endophytic bacteria (non-pathogenic bacteria that occur naturally in plants) and rhizospheric bacteria (bacteria that live on and near the roots of plants), have been shown to contribute to biodegradation of toxic organic compounds in contaminated soil and could have potential for improving phytoremediation. Endophytic and rhizospheric bacterial degradation of toxic organic compounds (either naturally occurring or genetically enhanced) in contaminated soil in the environment could have positive implications for human health worldwide and is the subject of this review.
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Received: 30 July 2009 / Accepted: 15 August 2009 / Published: 19 August 2009
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Abstract: Abstract: The pattern of biodegradation and the chemical changes occurring in the macromolecular fraction of domestic sludge during autothermal thermophilic aerobic digestion (ATAD) was monitored and characterised via solid-state 13C-NMR CP-MAS. Major indexes such as aromaticity, hydrophobicity and alkyl/O-alkyl ratios calculated for the ATAD processed biosolids were compared by means of these values to corresponding indexes reported for sludges of different origin such as manures, soil organic matter and certain types of compost. Given that this is the first time that these techniques have been applied to ATAD sludge, the data indicates that long-chain aliphatics are easily utilized by the microbial populations as substrates for metabolic activities at all stages of aerobic digestion and serve as a key substrate for the temperature increase, which in turn results in sludge sterilization. The ATAD biosolids following treatment had a prevalence of O-alkyl domains, a low aromaticity index (10.4%) and an alkyl/O-alkyl ratio of 0.48 while the hydrophobicity index of the sludge decreased from 1.12 to 0.62 during the treatment. These results have important implications for the evolution of new ATAD modalities particularly in relation to dewatering and the future use of ATAD processed biosolids as a fertilizer, particularly with respect to hydrological impacts on the soil behaviour.
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Received: 26 August 2009 / Accepted: 15 September 2009 / Published: 16 September 2009
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Abstract: The strain Sphingomonas sp. GY2B is a high efficient phenanthrene-degrading strain isolated from crude oil contaminated soils that displays a broad-spectrum degradation ability towards PAHs and related aromatic compounds. This paper reports embedding immobilization of strain GY2B in calcium alginate gel beads and the rapid degradation of phenanthrene by the embedded strains. Results showed that embedded immobilized strains had high degradation percentages both in mineral salts medium (MSM) and 80% artificial seawater (AS) media, and had higher phenanthrene degradation efficiency than the free strains. More than 90% phenanthrene (100 mg·L-1) was degraded within 36 h, and the phenanthrene degradation percentages were >99.8% after 72 h for immobilized strains. 80% AS had significant negative effect on the phenanthrene degradation rate (PDR) of strain GY2B during the linear-decreasing stage of incubation and preadsorption of cells onto rice straw could improve the PDR of embedded strain GY2B. The immobilization of strain GY2B possesses a good potential for application in the treatment of industrial wastewater containing phenanthrene and other related aromatic compounds.
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Last update: 10 February 2011
