Table of Contents
Crystals, Volume 7, Issue 12 (December 2017)
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Cover Story (view full-size image) Our results demonstrate the important role of liquid in directing the mechanochemical synthesis [...] Read more. Our results demonstrate the important role of liquid in directing the mechanochemical synthesis toward the intended solid product. Grinding of the CoCl2(phenantroline)2 complex and 1,4-diiodotetrafluorobenzene with a small amount of water gives a cocrystal product in which the dominant supramolecular interactions are I···Cl halogen bonds. Grinding solid reactants with a small amount of methanol gives an ionic structure, the four-component solid, in which the dominant supramolecular interactions are I···Cl- charge-assisted halogen bonds as well as O-H···Cl- hydrogen bonds. View this paper