Special Issue "Polyelectrolytes 2014"
A special issue of Polymers (ISSN 2073-4360).
Deadline for manuscript submissions: closed (31 March 2014)
Dr. Christian Seidel
Max Planck Institute of Colloids and Interfaces, Department of Theory & Bio-Systems, Science Park Golm, D-14424 Potsdam, Germany
Phone: +49 331 567 9608
Fax: +49 331 567 9612
Interests: polymers and polyelectrolytes in solution and at interfaces; polyelectrolyte brushes; organization of nanoparticles at copolymer brushes; numerical simulations and theory
Synthetic and natural polyelectrolytes have been the subject of fundamental and applied studies for nearly a century. Due to substantial advances both in experimental methods and theoretical approaches, since the 1990’s polyelectrolyte research has undergone a considerable speed-up. On the one hand, interest in polyelectrolytes is spurred by their fascinating properties, such as water solubility, intra- and interchain interactions, the strength of which can be tuned simply by varying salt concentration, and ionic conductivity. These properties make polyelectrolytes attractive from the application-oriented point of view, such as stabilizer of colloidal suspensions, additives to modify flocculation and viscosity, and superabsorbers. Functional polyelectrolytes combine the useful properties intrinsic to polyelectrolytes with added functionality provided by specific features of the polymer backbone, such as delocalized electrons in conjugated chains. Combined functionality can be used to create materials with highly interesting optical, electro-optical, and electronic properties.
On the other hand, the understanding of polyelectrolytes still belongs to the most challenging and most exciting problems in polymer physics and physical chemistry. Despite much effort and substantial progress during the last two decades, much more work is ahead to achieve a quantitative agreement between theory and experiments for a lot of problems, such as counterion condensation, chain stiffness, and formation of complexes. It is still a major open problem to have a satisfactory model explaining the coupling between small ions in solutions and polyelectrolyte charges, which is necessary to understand how electrostatics affects the behavior of polyelectrolytes.
Many biologically relevant macromolecules, such as nucleic acids, polypeptides, and polysaccharides, are polyelectrolytes. Electrophoresis is a well-established method for the fractionation of polyelectrolytes and more specifically, DNA. Hydration-mediated interactions play an important role in the field of biological polyelectrolytes, but are not well understood on nano-scales.
Dr. Christian Seidel
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. Papers will be published continuously (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are refereed through a peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed Open Access monthly journal published by MDPI.
- synthesis and biopolyelectrolytes
- stimuli-responsive polyelectrolytes
- hydration effects and ion-specific interactions
- polyelectrolyte multilayers, complexes and gels
- polyelectrolyte brushes
- conjugated polyelectrolytes
- theory and modeling
Polymers 2014, 6(8), 2100-2115; doi:10.3390/polym6082100
Received: 22 May 2014; in revised form: 15 July 2014 / Accepted: 22 July 2014 / Published: 31 July 2014| PDF Full-text (1351 KB) | HTML Full-text | XML Full-text
Article: Lipid Monolayers with Adsorbed Oppositely Charged Polyelectrolytes: Influence of Reduced Charge Densities
Polymers 2014, 6(7), 1999-2017; doi:10.3390/polym6071999
Received: 30 April 2014; in revised form: 26 June 2014 / Accepted: 27 June 2014 / Published: 10 July 2014| PDF Full-text (801 KB) | HTML Full-text | XML Full-text
Polymers 2014, 6(7), 1897-1913; doi:10.3390/polym6071897
Received: 21 March 2014; in revised form: 24 June 2014 / Accepted: 26 June 2014 / Published: 4 July 2014| PDF Full-text (1079 KB) | HTML Full-text | XML Full-text | Supplementary Files
Article: Stimuli-Responsive Polyelectrolyte Brushes As a Matrix for the Attachment of Gold Nanoparticles: The Effect of Brush Thickness on Particle Distribution
Polymers 2014, 6(7), 1877-1896; doi:10.3390/polym6071877
Received: 16 April 2014; in revised form: 23 June 2014 / Accepted: 24 June 2014 / Published: 27 June 2014| PDF Full-text (1259 KB) | HTML Full-text | XML Full-text | Supplementary Files
Polymers 2014, 6(6), 1756-1772; doi:10.3390/polym6061756
Received: 5 May 2014; in revised form: 3 June 2014 / Accepted: 4 June 2014 / Published: 16 June 2014| PDF Full-text (1785 KB) | HTML Full-text | XML Full-text
Polymers 2014, 6(6), 1655-1675; doi:10.3390/polym6061655
Received: 15 April 2014; in revised form: 15 May 2014 / Accepted: 18 May 2014 / Published: 30 May 2014| PDF Full-text (815 KB) | HTML Full-text | XML Full-text | Supplementary Files
Polymers 2014, 6(5), 1544-1601; doi:10.3390/polym6051544
Received: 16 April 2014; in revised form: 3 May 2014 / Accepted: 8 May 2014 / Published: 23 May 2014| Cited by 1 | PDF Full-text (463 KB) | HTML Full-text | XML Full-text
Polymers 2014, 6(5), 1602-1617; doi:10.3390/polym6051602
Received: 31 March 2014; in revised form: 13 May 2014 / Accepted: 19 May 2014 / Published: 23 May 2014| PDF Full-text (1089 KB) | HTML Full-text | XML Full-text
Article: Development of a Biocompatible Layer-by-Layer Film System Using Aptamer Technology for Smart Material Applications
Polymers 2014, 6(5), 1631-1654; doi:10.3390/polym6051631
Received: 17 March 2014; in revised form: 4 May 2014 / Accepted: 8 May 2014 / Published: 23 May 2014| PDF Full-text (2854 KB) | HTML Full-text | XML Full-text | Supplementary Files
Article: pH and Salt Effects on the Associative Phase Separation of Oppositely Charged Polyelectrolytes
Polymers 2014, 6(5), 1414-1436; doi:10.3390/polym6051414
Received: 27 March 2014; in revised form: 9 May 2014 / Accepted: 9 May 2014 / Published: 16 May 2014| PDF Full-text (3356 KB) | HTML Full-text | XML Full-text
Review: Does Electrical Conductivity of Linear Polyelectrolytes in Aqueous Solutions Follow the Dynamic Scaling Laws? A Critical Review and a Summary of the Key Relations
Polymers 2014, 6(4), 1207-1231; doi:10.3390/polym6041207
Received: 14 February 2014; in revised form: 4 April 2014 / Accepted: 11 April 2014 / Published: 22 April 2014| PDF Full-text (660 KB) | HTML Full-text | XML Full-text
The below list represents only planned manuscripts. Some of these manuscripts have not been received by the Editorial Office yet. Papers submitted to MDPI journals are subject to peer-review.
Type of Paper: Article
Title: Electrophoresis of Polyelectrolytes in Confinement: The Influence of Counterion Properties
Authors: Sorin Nedelcu and Jens-Uwe Sommer
Affiliation: Institute of Physical Chemistry and Polymer Physics, Leibniz-Institut für Polymerforschung Dresden e. V., Werkstofflaborgebäude, Budapester Straße 29, 01069 Dresden, Germany; E-Mail: firstname.lastname@example.org
Type of Paper: Article
Title: Bone Therapeutic Drug Delivery and cell Interaction of Adhesive Polyelectrolyte Complex Particle Films
Authors: Martin Müller *, Bernhard Torger, David Vehlow, Birgit Urban, Beatrice Woltmann and Ute Hempel
Affiliation: Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Str. 6, 01069 Dresden, Germany; E-mail: email@example.com
Abstract: Herein we report on novel zoledronate (ZOL) and simvastatin (SIM) loaded polyelectrolyte complex (PEC) nanoparticles, which can be solution casted on Ge substrates serving as analytically accessible model substrate regarding bone substituting materials (BSM). Four important requirements for drug loaded PEC particles and their films are addressed herein, which are the colloidal stability of PEC dispersions (i), interfacial stability (ii), biocompatibility (iii) and release kinetics in contact to release medium (iv). Dynamic light scattering measurements (DLS) showed, that both poly(ethyleneimine)/cellulose sulphate (PEI/CS) and PEI/dextran sulphate (PEI/DS) particles could be prepared with hydrodynamic radii in the range 35-170 nm and time stability up to several months. Transmission FTIR spectroscopy evidenced that films of both systems were stable in contact to the release medium (PBS) for several days. Immunofluorescence imaging suggested cytocompatibility of cast PEC particle films. Finally, in-situ-ATR-FTIR spectroscopy at cast PEC/drug films at Ge substrates revealed retarded drug releases in comparison to the pure drug film.
Last update: 24 July 2014