Special Issue "Organoplatinum Complexes"

Quicklinks

A special issue of Inorganics (ISSN 2304-6740).

Deadline for manuscript submissions: closed (30 September 2014)

Special Issue Editors

Guest Editor
Prof. Dr. Axel Klein
University of Cologne, Department of Chemistry, Institute of Inorganic Chemistry, Cologne, Germany.
Website: http://www.klein.uni-koeln.de/
Interests: transition metal complexes (including organometallic); platinum, palladium, nickel; synthesis; electrochemistry; photophysics; spectroscopy; modelling of catalytic processes
Co-Guest Editor
Prof. Dr. Elena Lalinde
University of La Rioja, Logrono, La Rioja, Spain
Website: https://cisq.unirioja.es/en/gmmo.php
Interests: synthesis of platinum group metal complexes, design of clusters and supramolecular networks stabilized by metal-metal and metal alkynyl bonds, study of their reactivity and photophysical behavior

Special Issue Information

Dear Colleagues,

The history of organoplatinum chemistry spans a long time period, from the early reports of Zeise or Pope and Peachey in the 19th century to today’s manifold applications of organoplatinum complexes or building blocks. On first view, the reason is simple: platinum, especially in the oxidation state +II provides very inert and thermodynamically stable Pt-C bonds and Pt2+ is (apart from Pd2+) the best ion to coordinate to olefin ligands.

Many applications of organoplatinum compounds utilize this robustness, which is even further elevated in cyclometalated compounds or units. In turn, the ease-of-use of the metalation reaction in activating H-C or X-C functions opens a vast field of synthetic organometallic chemistry. Organometallic platinum complexes or building blocks are highly amenable for use in the construction of supramolecular aggregates or hybrid materials. Such materials are often employed because of their easily tuneable (electro)luminescence. Here, the heavy and relativistic character of platinum, and thus the availability of triplet excited states, adds to the stable binding in such compounds. Pt-C bonds of organoplatinum complexes have also proved to be inert under physiological conditions; and the increased cytotoxicity compared to the established (non-organometallic) drug cisplatin and different toxicity mechanism, makes them interesting candidates for future anti-cancer drugs. On the other hand, chemists would not be chemists if they could not tune the bond strength and reactivity of Pt-C bonds, and thus render them more reactive. Therefore, in addition to the currently established use of organoplatinum complexes as slowed down models of platinum metal catalysed processes (note that palladium and rhodium are far less inert), organoplatinum complexes themselves have emerged on the scene as reactive, chemo- or stereo-selective reagents or catalysts.

Prof. Dr. Axel Klein
Guest Editor

Submission

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. Papers will be published continuously (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are refereed through a peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Inorganics is an international peer-reviewed Open Access quarterly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. For the first couple of issues the Article Processing Charge (APC) will be waived for well-prepared manuscripts. English correction and/or formatting fees of 250 CHF (Swiss Francs) will be charged in certain cases for those articles accepted for publication that require extensive additional formatting and/or English corrections.

Keywords

  • luminescent complexes and materials
  • supramolecular chemistry; cytotoxicity
  • CVD
  • cyclometalation
  • structural and mechanistic studies
  • reactive species in organometallic catalysis

Published Papers (8 papers)

Download All Papers
Sort by:
Display options:
Select articles Export citation of selected articles as:
Select/unselect all
Displaying article 1-8
p. 155-159
by
Inorganics 2015, 3(2), 155-159; doi:10.3390/inorganics3020155
Received: 23 April 2015 / Revised: 11 May 2015 / Accepted: 12 May 2015 / Published: 19 May 2015
Show/Hide Abstract | PDF Full-text (430 KB) | HTML Full-text | XML Full-text
(This article belongs to the Special Issue Organoplatinum Complexes)
p. 118-138
by , , , , ,  and
Inorganics 2015, 3(2), 118-138; doi:10.3390/inorganics3020118
Received: 7 April 2015 / Revised: 22 April 2015 / Accepted: 5 May 2015 / Published: 13 May 2015
Show/Hide Abstract | PDF Full-text (4740 KB) | HTML Full-text | XML Full-text | Supplementary Files
(This article belongs to the Special Issue Organoplatinum Complexes)
p. 55-81
by , ,  and
Inorganics 2015, 3(2), 55-81; doi:10.3390/inorganics3020055
Received: 16 January 2015 / Revised: 9 April 2015 / Accepted: 10 April 2015 / Published: 17 April 2015
Show/Hide Abstract | PDF Full-text (2232 KB) | HTML Full-text | XML Full-text | Supplementary Files
(This article belongs to the Special Issue Organoplatinum Complexes)
p. 620-648
by , , , , , ,  and
Inorganics 2014, 2(4), 620-648; doi:10.3390/inorganics2040620
Received: 31 July 2014 / Revised: 8 October 2014 / Accepted: 10 October 2014 / Published: 6 November 2014
Show/Hide Abstract | PDF Full-text (1506 KB) | HTML Full-text | XML Full-text | Supplementary Files
(This article belongs to the Special Issue Organoplatinum Complexes)
abstract graphic
p. 565-590
by , ,  and
Inorganics 2014, 2(4), 565-590; doi:10.3390/inorganics2040565
Received: 16 September 2014 / Revised: 9 October 2014 / Accepted: 9 October 2014 / Published: 31 October 2014
Show/Hide Abstract | PDF Full-text (1849 KB) | HTML Full-text | XML Full-text | Supplementary Files
(This article belongs to the Special Issue Organoplatinum Complexes)
p. 591-605
by , , , ,  and
Inorganics 2014, 2(4), 591-605; doi:10.3390/inorganics2040591
Received: 11 September 2014 / Revised: 13 October 2014 / Accepted: 14 October 2014 / Published: 31 October 2014
Show/Hide Abstract | Cited by 1 | PDF Full-text (2103 KB) | HTML Full-text | XML Full-text
(This article belongs to the Special Issue Organoplatinum Complexes)
p. 508-523
by ,  and
Inorganics 2014, 2(3), 508-523; doi:10.3390/inorganics2030508
Received: 7 July 2014 / Revised: 4 August 2014 / Accepted: 5 August 2014 / Published: 26 August 2014
Show/Hide Abstract | PDF Full-text (1096 KB) | HTML Full-text | XML Full-text | Supplementary Files
(This article belongs to the Special Issue Organoplatinum Complexes)
p. 115-131
by
Inorganics 2014, 2(1), 115-131; doi:10.3390/inorganics2010115
Received: 14 February 2014 / Revised: 13 March 2014 / Accepted: 13 March 2014 / Published: 21 March 2014
Show/Hide Abstract | Cited by 2 | PDF Full-text (631 KB) | HTML Full-text | XML Full-text
(This article belongs to the Special Issue Organoplatinum Complexes)
abstract graphic
Select/unselect all
Displaying article 1-8
Select articles Export citation of selected articles as:

Last update: 9 June 2015

Inorganics EISSN 2304-6740 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert