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Inorganics 2014, 2(1), 115-131; doi:10.3390/inorganics2010115

Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands

Departament de Química Inorgànica, Facultat de Química, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain
Received: 14 February 2014 / Revised: 13 March 2014 / Accepted: 13 March 2014 / Published: 21 March 2014
(This article belongs to the Special Issue Organoplatinum Complexes)
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Abstract

This review deals with the reactions of diarylplatinum(II) complexes with N-donor ligands to produce a variety of cycloplatinated compounds including endo-five-, endo-seven-, endo-six- or exo-five-membered platinacycles. The observed reactions result from a series of oxidative addition/reductive elimination processes taking place at platinum(II)/platinum(IV) species and involving C–X (X = H, Cl, Br) bond activation, arene elimination, and, in some cases, Caryl–Caryl bond formation.
Keywords: platinum; cyclometallation; N-donor ligands; diarylplatinum(II) precursors; synthesis platinum; cyclometallation; N-donor ligands; diarylplatinum(II) precursors; synthesis
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This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Crespo, M. Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands. Inorganics 2014, 2, 115-131.

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