Inorganics 2014, 2(1), 115-131; doi:10.3390/inorganics2010115
Review

Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands

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Received: 14 February 2014; in revised form: 13 March 2014 / Accepted: 13 March 2014 / Published: 21 March 2014
(This article belongs to the Special Issue Organoplatinum Complexes)
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract: This review deals with the reactions of diarylplatinum(II) complexes with N-donor ligands to produce a variety of cycloplatinated compounds including endo-five-, endo-seven-, endo-six- or exo-five-membered platinacycles. The observed reactions result from a series of oxidative addition/reductive elimination processes taking place at platinum(II)/platinum(IV) species and involving C–X (X = H, Cl, Br) bond activation, arene elimination, and, in some cases, Caryl–Caryl bond formation.
Keywords: platinum; cyclometallation; N-donor ligands; diarylplatinum(II) precursors; synthesis
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MDPI and ACS Style

Crespo, M. Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands. Inorganics 2014, 2, 115-131.

AMA Style

Crespo M. Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands. Inorganics. 2014; 2(1):115-131.

Chicago/Turabian Style

Crespo, Margarita. 2014. "Diarylplatinum(II) Compounds as Versatile Metallating Agents in the Synthesis of Cyclometallated Platinum Compounds with N-Donor Ligands." Inorganics 2, no. 1: 115-131.

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