Special Issue "Crystal Structure Analysis of Supramolecular and Porous Solids"
Deadline for manuscript submissions: closed (31 December 2017)
Supramolecular chemistry emerged as a powerful tool for chemists to create new materials from already known molecules. In a supramolecular solid, dissimilar molecules complement each other to build a new, highly organized structure, as seen in host–guest complexes, inclusion compounds, pharmaceutical co-crystals, supramolecular polymers, biomimetic materials, or mechanically interlocked molecular assemblies.
Supramolecular solids are a new target in materials science, where desired properties in a material can be predicted and generated through a specific arrangement of the molecules in the 3D structure. A range of physical (e.g., optical, electrical, magnetic), chemical (thermal stability, reactivity, catalysis) and biomedical (toxicity, bioavailability) properties have been created or tuned in various solids using this approach known as crystal engineering.
Porous solids, with uniform pores on molecular or nano scale, are produced from supramolecular solids. In the first step of this production, a guest template is used to shape a desired topology of pores with specific sorption, catalytic or ion-exchange capabilities. At a later stage, the guest template is removed to yield a zeolite, mesoporous silica, porous metal organic framework material, or porous material based on weaker interactions.
Crystal structure analysis is a primary characterization method in the design and study of supramolecular and porous solids. It provides the most critical information about the spatial arrangement of molecules in the crystal, topology and geometry of the cavity space, intermolecular interactions, as well as any changes in the structure induced by temperature, pressure or guest inclusion/removal. This Special Issue deals with all aspects of such research. The topics include, but are not limited to:
Design of new host molecules and host materials
Preparation and characterization of inclusion compounds
Design and characterization of co-crystals
Design of porous frameworks
Studies on weak intermolecular interactions in supramolecular solids
Studies on molecular disorder and dynamics in molecular crystals
Structural studies of phase transitions in supramolecular and porous solids
Database studies on supramolecular and porous solids
Prof. Dr. Dmitriy V Soldatov
Manuscript Submission Information
Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All papers will be peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.
Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Crystals is an international peer-reviewed open access monthly journal published by MDPI.
Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 1200 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.
metal organic frameworks
covalent organic frameworks
hydrogen-bonded organic frameworks
phase transitions in crystals