17 pages, 15655 KiB  
Article
A Statistical Analysis of Tropical Cyclone-Induced Low-Level Winds near Taiwan Island
by Lin Xue, Ying Li and Sen Yao
Atmosphere 2023, 14(4), 715; https://doi.org/10.3390/atmos14040715 - 14 Apr 2023
Cited by 2 | Viewed by 2173
Abstract
Using ERA5 reanalysis data and the tropical cyclone (TC) best track datasets from the China Meteorological Administration and Joint Typhoon Warning Center (from 1979 to 2021), TC-induced low-level winds near Taiwan Island are statistically analyzed. This study mainly concerns TC activity, low-level wind [...] Read more.
Using ERA5 reanalysis data and the tropical cyclone (TC) best track datasets from the China Meteorological Administration and Joint Typhoon Warning Center (from 1979 to 2021), TC-induced low-level winds near Taiwan Island are statistically analyzed. This study mainly concerns TC activity, low-level wind fields around Taiwan Island under TCs, and the detailed characteristics of TC wind structure. Results show that on average, 8.3 TCs enter the study region near Taiwan Island every year mainly from May to November, with more frequent and stronger TCs on the eastern and southern sides of Taiwan Island. For TC centers located at different positions around Taiwan Island, positive and negative vertical vorticity belts alternate between Taiwan Island and the TC center. Moreover, stronger and more frequent TC-induced winds mainly occur on the eastern side of Taiwan Island and the north of Taiwan Strait. TCs to the east of Taiwan Island have stronger maximum sustained wind than those on the western side of the island. Radii of the maximum wind (RMW) for TCs around Taiwan Island range from 5 to 90 nautical mile (nm, 9.3 to 116.7 km) with a mean value of 24.7 nm (44.4 km). Moreover, the RMWs of TCs are the largest (smallest) when the TC centers are located to the southwest (east) of the island. In addition, the outer sizes of TC winds vary from 52 to 360 nm (17.2 to 666.7 km) in the study region, with 187.4 nm (347.1 km) on average, and smaller values for TCs on the western side of the island. The average radii of severe winds, including R34, R50, and R64, are largest in the northeast quadrant and smallest in the southwest quadrant of the TC. The higher the specific wind speed is, the smaller the TC radius and the more symmetric its wind circle. These statistical results may provide references for TC gale forecasting and wind-resistant design for offshore engineering to mitigate TC-induced wind hazards. Full article
(This article belongs to the Special Issue Feature Papers in Meteorological Science)
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14 pages, 3484 KiB  
Article
Study on the Hemispheric Asymmetry of Thermospheric Density Based on In-Situ Measurements from APOD Satellite
by Jiangzhao Ai, Yongping Li, Xianguo Zhang, Chao Xiao, Guangming Chen, Xiaoliang Zheng and Zhiliang Zhang
Atmosphere 2023, 14(4), 714; https://doi.org/10.3390/atmos14040714 - 14 Apr 2023
Cited by 1 | Viewed by 1967
Abstract
In this article, high spatiotemporal resolution data obtained by the atmospheric density detector carried by China’s APOD satellite are used to study the hemispheric asymmetry of thermospheric density. A detailed analysis is first performed on the dual magnetic storm event that occurred near [...] Read more.
In this article, high spatiotemporal resolution data obtained by the atmospheric density detector carried by China’s APOD satellite are used to study the hemispheric asymmetry of thermospheric density. A detailed analysis is first performed on the dual magnetic storm event that occurred near the autumnal equinox on 8 September 2017. The results show that the enhancement ratio of atmospheric density in the southern polar region (SPR) on the duskside was approximately 1.33–1.65 times that of the northern polar region (NPR), demonstrating a strong hemispheric asymmetry of thermospheric atmospheric density response during the magnetic storm. However, the asymmetry response was smaller on the dawnside, suggesting that the hemispheric density response asymmetry is related to local time (LT). The energy injection in high-latitude regions increases local atmospheric density and forms traveling atmospheric disturbances (TADs). TADs can propagate to low-latitude regions over several hours and affect the global distribution of thermospheric atmospheric density. Similarly, the geomagnetic index fitting slope of SPR relative density difference is greater than that of NPR. The SuperDARN convection pattern indicates that the plasma convection velocity of SPR is significantly greater than that of NPR, indicating that joule heating caused by neutral friction of ions in the Southern Hemisphere may be stronger. Subsequently, an analysis of annual solar activity and seasons was carried out on the thermospheric NPR, SPR atmospheric density, and their differences from December 2015 to December 2020. The results show that thermospheric atmospheric density decreases overall as the number of sunspots decreases. The differences between the NPR and SPR atmospheric densities in the thermosphere exhibits a noticeable annual periodicity. The NPR and SPR atmospheric densities appear to have different distribution characteristics in different seasons. The NPR density peak is mainly in March or April. In particular, the “double-peak” phenomenon occurred in 2017, with peaks in March and September, while the most obvious feature of SPR atmospheric density is that its minimum value occurs in the summer months of June and July. This paper reveals the annual, seasonal, and magnetic storm response characteristics of the hemispheric asymmetry of thermospheric atmospheric density, which has significant implications for the study of multilayer energy coupling of the magnetosphere–ionosphere–thermosphere. Full article
(This article belongs to the Section Upper Atmosphere)
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11 pages, 1214 KiB  
Article
Determining the Geogenic Radon Potential in Different Layouts and Numbers of Points
by Alexandru Lupulescu, Călin Baciu, Tiberius Dicu, Bety-Denissa Burghele and Alexandra Laura Cucoș
Atmosphere 2023, 14(4), 713; https://doi.org/10.3390/atmos14040713 - 14 Apr 2023
Cited by 3 | Viewed by 1573
Abstract
The geogenic radon potential is primarily controlled by the geological characteristics of the site, such as the rock type and structural elements, as well as the permeability of the soil. Depending on the scope of the survey, the geogenic radon potential can be [...] Read more.
The geogenic radon potential is primarily controlled by the geological characteristics of the site, such as the rock type and structural elements, as well as the permeability of the soil. Depending on the scope of the survey, the geogenic radon potential can be mapped based on measurements conducted in the field at various resolutions. Detailed surveys are generally labour-intensive and time-consuming. Therefore, a balance should be reached between the desired level of precision and the required amount of effort, delivering the best results with the least number of resources. The international literature describes a variety of surveying techniques. This study was undertaken in a region of the central zone of the Poiana Rusca Mountains (Southern Carpathians, Romania) that contains several metamorphic, volcanic, and sedimentary rock types. The primary objective of the study is to compare alternative sampling point configurations, which vary in number and arrangement. The objective was to achieve the most accurate representation of the calculated geogenic radon potential while limiting the number of measurements and the time and effort associated with them. Radon activity concentration and soil permeability data were collected from 34 locations using seven alternative layouts of the sampling points. The proposed layouts were based on various configurations of fifteen, nine, five, and three sampling points. Locally, in some of the metamorphic units and in the regions containing sedimentary deposits with volcanic intercalations, the geogenic radon potential was found to be elevated. The results indicate that the three-measuring-point configuration is acceptable for general geogenic radon potential surveys. Full article
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31 pages, 6503 KiB  
Article
Comprehensive Analysis of Current Primary Measures to Mitigate Brake Wear Particle Emissions from Light-Duty Vehicles
by Lukas Storch, Christopher Hamatschek, David Hesse, Felix Feist, Thomas Bachmann, Philipp Eichler and Theodoros Grigoratos
Atmosphere 2023, 14(4), 712; https://doi.org/10.3390/atmos14040712 - 14 Apr 2023
Cited by 16 | Viewed by 5883
Abstract
Exhaust regulations and improved exhaust gas treatment systems have already initiated the trend that brings emissions from brakes and tires to the forefront of traffic-induced particulate matter. The health and environmental relevance of particulate matter has resulted in regulators, industry, and research institutions [...] Read more.
Exhaust regulations and improved exhaust gas treatment systems have already initiated the trend that brings emissions from brakes and tires to the forefront of traffic-induced particulate matter. The health and environmental relevance of particulate matter has resulted in regulators, industry, and research institutions prioritising the mitigation of non-exhaust particle emissions. To this end, under the umbrella of the United Nations Economic Commission for Europe World Forum for Harmonisation of Vehicle Regulations (UNECE WP.29), the Working Party on Pollution and Energy (GRPE) mandated the Particle Measurement Programme Informal Working Group (PMP-IWG) to develop a Global Technical Regulation (GTR) for measuring brake dust. The standards and procedures defined within the GTR should eventually form the basis for the introduction of a Euro 7 limit value for brake emissions. The purpose of this measurement campaign is to provide an exemplary overview of the emission behaviour of wheel brakes and friction pairings currently available on the market and to identify possible reduction potential with regard to particulate emissions. All measurements were carried out taking into account the draft GTR valid at the time of execution. For the investigations, brakes were selected using the example of different vehicle classes, brake concepts (disc and drum brake), vehicle axles (front and rear axle), and alternative friction materials (brake disc and pads/shoes). Thus, the use of wear-resistant discs and improved brake pad compositions are able to achieve significantly lower emissions. In addition, the measurement of brake dust emissions from vehicles with different levels of electrification was considered. Electrical braking was modelled and applied to the Worldwide Harmonised Light-Duty Vehicles Test Procedure (WLTP) Brake Cycle, which has demonstrated high emission reduction potentials depending on the electrification level. Full article
(This article belongs to the Special Issue Brake Wear Particulate Matter and Mitigation Strategies)
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16 pages, 2710 KiB  
Article
Runoff Response to Climate in Two River Basins Supplied by Small Glacier Meltwater in Southern and Northern Tibetan Plateau
by Ruzhen Yao, Shenghai Li and Deliang Chen
Atmosphere 2023, 14(4), 711; https://doi.org/10.3390/atmos14040711 - 13 Apr 2023
Cited by 4 | Viewed by 2041
Abstract
The Tibetan Plateau (TP) has experienced amplified warming in recent decades, causing glaciers to melt and affecting river runoff. It is well established that the southern and northern areas of the TP have responded to climate changes differently, with the north dominated by [...] Read more.
The Tibetan Plateau (TP) has experienced amplified warming in recent decades, causing glaciers to melt and affecting river runoff. It is well established that the southern and northern areas of the TP have responded to climate changes differently, with the north dominated by a westerly climate and the south by the Indian monsoon. While there are more glaciers in the TP than in any other region outside the polar areas, most of these glaciers are tiny, and only a limited number of them have been monitored to study mass balance and downward runoff. This study used the mass balance measured at two glaciers along with in situ and satellite data to drive a hydrological model called the Alpine Runoff Predictor that includes glacier melt to simulate glacial melting and the accompanying hydrological processes of the two glacierized basins, analyze their contributions to the river runoffs, and investigate their responses to local climate changes. The results show that the glacier meltwater in both river basins showed an increasing trend, with values of 0.001 × 108 m3 a−1 in the Kyanjing River basin and 0.0095 × 108 m3 a−1 in the Tuole River basin. However, their multi-year average contributions to the runoff were 12.5% and 5.6%, respectively. In contrast to the Tuole River basin, where runoff is increasing (0.0617 × 108 m3 a−1), the Kyanjing River basin has decreasing runoff (−0.0216 × 108 m3 a−1) as a result of decreasing precipitation. This result highlights the dominant role played by precipitation changes in the two basins under study, which are characterized by small glacier meltwater contributions. Full article
(This article belongs to the Special Issue Glaciers Mass Balance Sensitivity to Meteorological Variability)
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17 pages, 6659 KiB  
Article
Physicochemical Analysis of Particle Matter from a Gasoline Direct Injection Engine Based on the China Light-Duty Vehicle Test Cycle
by Hao Wang, Chao He, Haisheng Yu, Jiaqiang Li and Xueyuan Liu
Atmosphere 2023, 14(4), 710; https://doi.org/10.3390/atmos14040710 - 13 Apr 2023
Cited by 2 | Viewed by 2366
Abstract
This paper investigated the physical and chemical properties of gasoline direct injection (GDI) engine particulate matter (PM). The physical properties mainly included the particulate aggregate morphology, primary particle size, and internal nanostructure. High-resolution transmission electron microscopy (HRTEM) and scanning electron microscopy (SEM) were [...] Read more.
This paper investigated the physical and chemical properties of gasoline direct injection (GDI) engine particulate matter (PM). The physical properties mainly included the particulate aggregate morphology, primary particle size, and internal nanostructure. High-resolution transmission electron microscopy (HRTEM) and scanning electron microscopy (SEM) were used to obtain particle morphology information and to conduct image processing and analysis. The chemical characterization tests included X-ray photoelectron spectroscopy (XPS), energy dispersive scanning (EDS), Raman spectroscopy, Fourier-transform infrared spectroscopy (FTIR), and thermal gravimetric analysis (TGA). XPS can be used to observe the content of carbon and oxygen components and the surface carbon chemistry status, EDS can be used to obtain the elemental composition of particles, and TGA is used to analyze the oxidative kinetics of particles. Samples were collected from the exhaust emissions of a passenger vehicle compliant with China’s VI emission standards under China Light-Duty Vehicle Test Cycle (CLTC) test conditions. The study found that the particle morphology mainly comprised primary particles stacked on top of each other to form agglomerate structures, and the primary particles exhibited a core–shell structure. Analysis showed that carbon and oxygen were the predominant components of the particles, with other metallic elements also present. The XPS observations agreed with the FTIR results, indicating a small amount of oxygen was present on the particle surface and that the carbon components consisted mainly of sp2 hybridized graphite and sp3 hybridized organic carbon. The TGA results indicated high characteristic temperatures and low oxidation activity. Full article
(This article belongs to the Special Issue Traffic Related Emission)
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22 pages, 12504 KiB  
Article
Influences of the Mid-Level Vortex on the Formation of Tropical Cyclone Toraji (2013)
by Chen-Hao Chuang, Yi-Huan Hsieh, Pin-Yen Liu, Hsu-Feng Teng and Cheng-Shang Lee
Atmosphere 2023, 14(4), 709; https://doi.org/10.3390/atmos14040709 - 12 Apr 2023
Cited by 1 | Viewed by 2217
Abstract
This study analyzes the influences of the mid-level vortex on the formation of Tropical Cyclone Toraji (2013). A rare case of a tropical cyclone that formed near Taiwan involved a mid-level vortex that was a remnant of Tropical Cyclone Kong-Rey (2013). The piecewise [...] Read more.
This study analyzes the influences of the mid-level vortex on the formation of Tropical Cyclone Toraji (2013). A rare case of a tropical cyclone that formed near Taiwan involved a mid-level vortex that was a remnant of Tropical Cyclone Kong-Rey (2013). The piecewise potential vorticity inversion method is applied to examine the contribution of the mid-level vortex to the low-level wind field under quasi-balanced conditions. Numerical sensitivity experiments are conducted to quantify the importance of the mid-level vortex on Toraji formation, in which the mid-level vortex is removed with different removing factors (percentages) from the initial field. The results indicate that mid-level positive potential vorticity anomalies significantly contribute to the low-level positive vorticity before Toraji formation. Furthermore, when the removing factors increase in the sensitivity experiments, either the intensity of the simulated low-level vortex or the development trend of pre-Toraji decreases. However, there is no significant relationship between the convection’s magnitude and the intensity of the mid-level vortex. The main difference comes from the mid-level vortex’s intensity, which would result in a greater high-level warm core structure and cause stronger vertical mass flux. In summary, the mid-level vortex plays a critical role in the formation of Toraji. It provides a favorable environment for forming the pre-Toraji vortex by maintaining a high-level warm-core structure, leading to the formation of Toraji. Full article
(This article belongs to the Special Issue Typhoon/Hurricane Dynamics and Prediction)
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25 pages, 3279 KiB  
Article
A Comparison of the Statistical Downscaling and Long-Short-Term-Memory Artificial Neural Network Models for Long-Term Temperature and Precipitations Forecasting
by Noé Carème Fouotsa Manfouo, Linke Potgieter, Andrew Watson and Johanna H. Nel
Atmosphere 2023, 14(4), 708; https://doi.org/10.3390/atmos14040708 - 12 Apr 2023
Cited by 10 | Viewed by 3231
Abstract
General circulation models (GCMs) run at regional resolution or at a continental scale. Therefore, these results cannot be used directly for local temperatures and precipitation prediction. Downscaling techniques are required to calibrate GCMs. Statistical downscaling models (SDSM) are the most widely used for [...] Read more.
General circulation models (GCMs) run at regional resolution or at a continental scale. Therefore, these results cannot be used directly for local temperatures and precipitation prediction. Downscaling techniques are required to calibrate GCMs. Statistical downscaling models (SDSM) are the most widely used for bias correction of GCMs. However, few studies have compared SDSM with multi-layer perceptron artificial neural networks and in most of these studies, results indicate that SDSM outperform other approaches. This paper investigates an alternative architecture of neural networks, namely the long-short-term memory (LSTM), to forecast two critical climate variables, namely temperature and precipitation, with an application to five climate gauging stations in the Lake Chad Basin. Lake Chad is a data scarce area which has been impacted by severe drought, where water resources have been influenced by climate change and recent agricultural expansion. SDSM was used as the benchmark in this paper for temperature and precipitation downscaling for monthly time–scales weather prediction, using grid resolution GCM output at a 5 degrees latitude × 5 degrees longitude global grid. Three performance indicators were used in this study, namely the root mean square error (RMSE), to measure the sensitivity of the model to outliers, the mean absolute percentage error (MAPE), to estimate the overall performance of the predictions, as well as the Nash Sutcliffe Efficiency (NSE), which is a standard measure used in the field of climate forecasting. Results on the validation set for SDSM and test set for LSTM indicated that LSTM produced better accuracy on average compared to SDSM. For precipitation forecasting, the average RMSE and MAPE for LSTM were 33.21 mm and 24.82% respectively, while the average RMSE and MAPE for SDSM were 53.32 mm and 34.62% respectively. In terms of three year ahead minimum temperature forecasts, LSTM presents an average RMSE of 4.96 degree celsius and an average MAPE of 27.16%, while SDSM presents an average RMSE of 8.58 degree celsius and an average MAPE of 12.83%. For maximum temperatures forecast, LSTM presents an average RMSE of 4.27 degree celsius and an average MAPE of 11.09 percent, while SDSM presents an average RMSE of 9.93 degree celsius and an average RMSE of 12.07%. Given the results, LSTM may be a suitable alternative approach to downscale global climate simulation models’ output, to improve water management and long-term temperature and precipitations forecasting at local level. Full article
(This article belongs to the Special Issue Precipitation in Africa)
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13 pages, 21301 KiB  
Technical Note
On Saharan Air Layer Stability and Suppression of Convection over the Northern Tropical Atlantic: Case Study Analysis of a 2007 Dust Outflow Event
by Adrian Flores, Ricardo K. Sakai, Everette Joseph, Nicholas R. Nalli, Alexander Smirnov, Belay Demoz, Vernon R. Morris, Daniel Wolfe and Sen Chiao
Atmosphere 2023, 14(4), 707; https://doi.org/10.3390/atmos14040707 - 12 Apr 2023
Cited by 2 | Viewed by 2448
Abstract
A prominent Saharan Air Layer (SAL) was detected over the Northern Atlantic from the West African Coast to the Caribbean Sea in 2007. Data was collected from the Aerosols and Ocean Science Expedition (AEROSE), which encountered a major dust outflow on 13 and [...] Read more.
A prominent Saharan Air Layer (SAL) was detected over the Northern Atlantic from the West African Coast to the Caribbean Sea in 2007. Data was collected from the Aerosols and Ocean Science Expedition (AEROSE), which encountered a major dust outflow on 13 and 14 May 2007. These observational measurements came from onboard instrumentation and radiosondes that captured the dust-front event from 13 to 14 May 2007. Aerosol backscatter was confined within the Marine Boundary Layer (MBL), with layers detected up to 3 km. Aerosol Optical Depth (AOD) increased by one order of magnitude during the dust front, from 0.1 to 1. Downward solar radiation was also attenuated by 200 W/m2 and 100 W/m2 on the first and second days, respectively. A weaker gradient at and above 500 m from potential temperature profiles indicates a less-defined MBL, and an ambient air temperature of 26 °C on 14 May and 28 °C on 15 May were observed above 500 m, reinforcing the temperature inversion and static stability of the SAL. Subsequent days, clear and boundary-layer cloudy days were observed after the dust front. From 14 to 18 May, a Convective Inhibition (CIN) layer started to form at the top of the MBL, developing into a negative buoyancy from 17 to 23 May, and reinforcing the large-scale anticyclonic atmospheric conditions. These results show that the SAL acts as positive feedback on suppressing deep convection over the tropical Atlantic during this dust outflow and several days after its passage. Full article
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16 pages, 1540 KiB  
Article
An Experimental Framework of Particulate Matter Emission Factor Development for Traffic Modeling
by Sicong Zhu, Yongdi Qiao, Wenjie Peng, Qi Zhao, Zhen Li, Xiaoting Liu, Hao Wang, Guohua Song, Lei Yu, Lei Shi and Qing Lan
Atmosphere 2023, 14(4), 706; https://doi.org/10.3390/atmos14040706 - 12 Apr 2023
Cited by 1 | Viewed by 1662
Abstract
To estimate traffic facility-oriented particulate matter (PM) emissions, emission factors are both necessary and critical for traffic planners and the community of traffic professionals. This study used locally calibrated laser-scattering sensors to collect PM emission concentrations in a tunnel. Emission factors of both [...] Read more.
To estimate traffic facility-oriented particulate matter (PM) emissions, emission factors are both necessary and critical for traffic planners and the community of traffic professionals. This study used locally calibrated laser-scattering sensors to collect PM emission concentrations in a tunnel. Emission factors of both light-duty and heavy-duty vehicles were found to be higher in autumn compared to summer. Based on this study’s data analysis, PM emissions, in terms of mass, have a strong seasonal effect. The study also conducted a PM composition test on normal days and during haze events. Preliminary results suggested that the transformation of gaseous tailpipe emissions to PM is significant within the tunnel during a haze event. This study, therefore, recommends locally calibrated portable devices to monitor mobile-source traffic emissions. The study suggests that emission factor estimation of traffic modeling packages should consider the dynamic PM formation mechanism. The study also presents traffic policy implications regarding PM emission control. Full article
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14 pages, 3728 KiB  
Article
On the Radon-Related Mechanism of the Seismo- and Volcanogenic Geomagnetic Anomalies: Experiments in Tlamacas Mountain (Volcano Popocatepetl Area) and Electrode Effect Model
by Vsevolod Yutsis, Anatolyi Kotsarenko, Vladimir Grimalsky and Sergey Pulinets
Atmosphere 2023, 14(4), 705; https://doi.org/10.3390/atmos14040705 - 12 Apr 2023
Cited by 2 | Viewed by 2033
Abstract
The noise-like behavior of the geomagnetic anomalies observed in Tlamacas station (volcano Popocatepetl, Mexico), linked to the ionization produced by intensive radon release, are presented in the experimental part of this study. The magnetic field perturbations produced by charge spreading currents within the [...] Read more.
The noise-like behavior of the geomagnetic anomalies observed in Tlamacas station (volcano Popocatepetl, Mexico), linked to the ionization produced by intensive radon release, are presented in the experimental part of this study. The magnetic field perturbations produced by charge spreading currents within the fair-weather electric field are considered in the theoretical model based on the electrode. The electric charges are generated by the air ionization due to radon emanation. The simulations demonstrated that the ionization of the air leads to magnetic field perturbations of about 0.001–0.1 nT in the ULF (ultra low frequency) range 10−3–10−1 Hz. Magnetic field perturbations can be higher when the radon emanation occurs in a region with terrain irregularities. Full article
(This article belongs to the Special Issue Feature Papers in Upper Atmosphere)
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12 pages, 5751 KiB  
Communication
A Compact NO2 Gas Sensor with an Optimized Photoacoustic Cell and 450 nm-LD
by Wenyang Yuan, Jiaqi Yao, Ping Gong, Mingqi Jiao, Congbiao Lei, Yuxuan Jiang and Liang Xie
Atmosphere 2023, 14(4), 704; https://doi.org/10.3390/atmos14040704 - 12 Apr 2023
Cited by 4 | Viewed by 2084
Abstract
In this paper, a compact ambient gas sensor with an optimized photoacoustic cell is reported. The relationship between the geometric dimensions (usually radius and length) of the photoacoustic cell (PAC) and the acoustic signal was studied through theoretical and finite element analysis. Then [...] Read more.
In this paper, a compact ambient gas sensor with an optimized photoacoustic cell is reported. The relationship between the geometric dimensions (usually radius and length) of the photoacoustic cell (PAC) and the acoustic signal was studied through theoretical and finite element analysis. Then an optimized H-type PAC with a volume of 80 mm × 30 mm × 30 mm was machined out. The gas capacity is only 18.85 millilitres. The performance of the photoacoustic cell has been verified experimentally by the detection of nitrogen dioxide (NO2) standard gas. With an electret microphone and an economically self-designed 450 nm laser module, the detection of NO2 concentration was executed. The experimental results show good linearity with a fitting R-square of 0.9991. With an SNR (signal-to-noise ratio) of 41.247, the minimum detection limit (MDL) of the system can reach 4.85 ppb (1σ). With an analysis of allan variance, the MDL can achieve 0.11 ppb with a 228 s integration time. By replacing the light source, the system shows great potential for sensitive and compact detectors for other ambient gasses as well. Full article
(This article belongs to the Special Issue Advanced Photoacoustic Spectroscopy and Its Applications)
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16 pages, 3444 KiB  
Article
Apportionment of Chemical Components and Sources of PM2.5 in Shihezi City of Xinjiang, China
by Yuting Zhong, Youjiang He, Xia Li, Shuting Li, Maulen Ayitken and Xinchun Liu
Atmosphere 2023, 14(4), 703; https://doi.org/10.3390/atmos14040703 - 11 Apr 2023
Cited by 6 | Viewed by 2155
Abstract
In order to reveal the pollution characteristics and sources of PM2.5, in this study, we collected PM2.5 filter membrane samples in Shihezi continuously from December 2020 to January 2021, and analyzed 10 kinds of water-soluble inorganic ions (WSIIs) and 24 [...] Read more.
In order to reveal the pollution characteristics and sources of PM2.5, in this study, we collected PM2.5 filter membrane samples in Shihezi continuously from December 2020 to January 2021, and analyzed 10 kinds of water-soluble inorganic ions (WSIIs) and 24 inorganic elements (IEs), as well as organic carbon (OC) and elemental carbon (EC). The sources and transport paths of PM2.5 were also analyzed via PMF modeling and backward trajectory clustering analysis. The results show that, in winter, Shihezi can have a mean PM2.5 mass concentration as high as 164.69 ± 76.48 μg/m3, and the PM2.5 mass concentration on polluted days is 3.3 times that of clean days. Water-soluble inorganic ions (WSIIs), total carbon (TC), and inorganic elements (IEs) make up the percentage of PM2.5 mass concentration by 64.9%, 9.3%, and 2.6%, respectively. SO42−, NO3, and NH4+ (SIAs) are the major WSIIs, accounting for 91.0% of the WSII concentration. The heavier the pollution, the more SIAs contribute to PM2.5. The OC mean mass concentration is 14.04 ± 5.32 μg/m3. As the winter pollution becomes worse and worse, the value of OC/PM2.5 decreases constantly while that of SOC/OC follows an opposite trend. During the process of heavy pollution in Shihezi, the secondary transformation of total carbon cannot be ignored. The positive definite matrix factorization (PMF) model result suggests that the main pollution origins of PM2.5 in Shihezi City comprise secondary sources, coal-burning sources, motor vehicle sources, industrial sources, and flying dust sources. The backward trajectory clustering analysis denotes that the winter pollution in Shihezi mainly comes from the local pollutants in Manas and the short-distance transport of pollutants from the Urumqi-Changji Region. Full article
(This article belongs to the Section Air Quality)
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13 pages, 3265 KiB  
Article
Evaluating the Measurement Uncertainty of On-Road NOx Using a Portable Emission Measurement System (PEMS) Based on Real Testing Data in China
by Sheng Su, Pan Hou, Xin Wang, Liqun Lyu, Yang Ge, Tao Lyu, Yitu Lai, Wanyou Luo and Yachao Wang
Atmosphere 2023, 14(4), 702; https://doi.org/10.3390/atmos14040702 - 11 Apr 2023
Cited by 7 | Viewed by 2441
Abstract
An evaluation of the measurement uncertainty of on-road NOx emissions using portable emission measurement system (PEMS) based on real local testing data collected in China was carried out as per the type B method defined in the EN 17507 standard. The aim of [...] Read more.
An evaluation of the measurement uncertainty of on-road NOx emissions using portable emission measurement system (PEMS) based on real local testing data collected in China was carried out as per the type B method defined in the EN 17507 standard. The aim of this work was to quantify the “absolute” measurement uncertainty of PEMSs, which excluded “PEMS relative to laboratory constant volume sampler (CVS)” uncertainty from the calculation of on-road NOx measurement uncertainty using PEMSs. PEMS instruments from three mainstream manufacturers were employed. The zero drift of the NOx analyzers was evaluated periodically during the real driving emissions (RDE) test, and it was noticed that there was neither a linear nor step model of zero drift, with no correlation with the boundary conditions or measurement principle. Additionally, from the 256 valid RDE tests, the zero drift always ranged from 3.8 ppm to −3.8 ppm, and more than 95% of the span drifts were within a range of 1.5%. Based on the laboratory testing of ten vehicles using the worldwide harmonized light-duty vehicle test cycle (WLTC), the type B uncertainty of PEMS NOx measurements corresponding to China-6a and China-6b limits was assessed. An uncertainty of 26.5% for China-6a was found (NOx limit = 60 mg/km over the WLTC), which is very close to the 22.5% from the EU evaluation results (NOx limit = 80 mg/km over the WLTC); the uncertainty with respect to China-6b was found to be 42.8% because the type-I limit was tuned down to 35 mg/km. This result indicates that, with the ever-tightening regulatory limits of vehicle NOx emissions, big challenges will be posed in terms of the reliability of PEMS measurements, which requires PEMS manufacturers to improve the performance of the instruments and policymakers to refine the test procedures and/or result calculation method to minimize the impacts. Full article
(This article belongs to the Special Issue Traffic Related Emission)
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21 pages, 55320 KiB  
Article
Analysis of the Applicability of Multisource Meteorological Precipitation Data in the Yunnan-Kweichow-Plateau Region at Multiple Scales
by Hongbo Zhang, Ting Yang, Alhassane Bah, Zhumei Luo, Guohong Chen and Yanglin Xie
Atmosphere 2023, 14(4), 701; https://doi.org/10.3390/atmos14040701 - 10 Apr 2023
Cited by 2 | Viewed by 1889
Abstract
Multisource meteorological precipitation products are an important way to make up for a lack of observation sites or a lack of precipitation data in areas with a complex topography. They have important value for local industrial, agricultural, and ecological water use calculations, as [...] Read more.
Multisource meteorological precipitation products are an important way to make up for a lack of observation sites or a lack of precipitation data in areas with a complex topography. They have important value for local industrial, agricultural, and ecological water use calculations, as well as for water resource evaluation and management. The Yunnan-Kweichow Plateau is located in southwest China and has a relatively backward economy and few meteorological stations. At the same time, the terrain is dominated by mountain valleys, precipitation is greatly affected by the terrain, and meteorological data are lacking, making the calculation of local water resources difficult. In this study, the applicability of the 3-hourly merged high-quality/IR estimates (3B42) of the Tropical Rainfall Measuring Mission (TRMM), China Meteorological Forcing Dataset (CMFD), and China Meteorological Assimilation Driving Datasets (CMADS) in the Yunnan-Kweichow Plateau was analyzed using multiple evaluation indicators of different temporal scales and precipitation intensity levels as well as the spatial distribution of the indicators based on measured daily precipitation data from 59 national meteorological basic stations in the study area in 2008–2018. The results showed that (1) the three products had performed well and could be applied to the calculation of local water resources with CMFD performing the best; (2) the performance of precipitation products was slightly worse on the daily scale, and the overall performance of the yearly, quarterly, and monthly scales was better; (3) good results were achieved in most regions, but there were also some regions with prominent overestimation and underestimation; (4) the three precipitation products had the highest probabilities of detection and the lowest false alarm rates for no rain and light rain, and the probability of detection gradually decreased with an increase in the precipitation intensity; and (5) the mean absolute error of precipitation products in rainy months is large, so the accuracy of products in the calculation of heavy rain and flood will be limited. Full article
(This article belongs to the Section Meteorology)
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