Special Issue "s-Block Metal Complexes"
Deadline for manuscript submissions: closed (31 March 2017)
Prof. Dr. Matthias Westerhausen
Institute of Inorganic and Analytical Chemistry, Friedrich Schiller University Jena, Humboldtstrasse 8, D-07743 Jena, Germany
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Interests: s-block metal coordination chemistry; catalysis with s-block metals; Grignard reagents; transition metal carbonyl complexes; scorpionates; organocalcium compounds; cooperative effects in heterobimetallic complexes
The coordination chemistry of the s-block metals spans diverse fields, ranging from shielded coordination compounds over hydride to organometallic complexes for diverse applications. New developments pertain, not only to the lithium and magnesium chemistry with inspiring examples, such as heterobimetallic or heteroleptic complexes with special reactivity patterns, but the heavy s-block metals have progressively gained attention in various fields. Subvalent magnesium(I) derivatives are increasingly being used for reduction reactions, turbo-Grignard reagents show enhanced reactivity and tolerance toward functional groups, hydrides act as hydrogen storage materials, heavy Grignard reagents are available by straight forward procedures—just to name a few examples. Quantum chemical calculations deal with unique bonding situations and the relevance of d-orbital participation has been discussed to understand structure-reactivity relationships. Especially the complexes of the heavy alkaline earth metals are catalytically active in diverse reactions, promoting hydrofunctionalization reactions and Lewis acid catalysis. This Special Issue aims to highlight the structural and chemical diversity of s-block metal complexes, as well as the broad field of applications.
Prof. Dr. Matthias Westerhausen
Manuscript Submission Information
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- s-block metal coordination compounds
- Grignard-type reagents
- Lochmann-Schlosser bases
- s-block metal-mediated catalysis
- bonding in s-block complexes
- heterobimetallic complexes