Insights into Molecular Beryllium–Silicon Bonds
AbstractWe present the synthesis of two silyl beryllium halides HypSiBeX∙(thf) (HypSi = Si(SiMe3)3, X = Cl 2a, I 4a) and the molecular structure of 2a as determined by single crystal X-ray diffraction. Compounds 2a and 4a were characterized via multi-nuclear NMR spectroscopy (1H, 9Be, 13C, 29Si), and the bonding situation was further investigated using quantum chemical calculations (with the addition of further halides X = F 1b, Cl 2b, Br 3b, I 4b). The nature of the beryllium silicon bond in the context of these compounds is highlighted and discussed. View Full-Text
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Naglav, D.; Tobey, B.; Dzialkowski, K.; Jansen, G.; Wölper, C.; Schulz, S. Insights into Molecular Beryllium–Silicon Bonds. Inorganics 2017, 5, 22.
Naglav D, Tobey B, Dzialkowski K, Jansen G, Wölper C, Schulz S. Insights into Molecular Beryllium–Silicon Bonds. Inorganics. 2017; 5(2):22.Chicago/Turabian Style
Naglav, Dominik; Tobey, Briac; Dzialkowski, Kevin; Jansen, Georg; Wölper, Christoph; Schulz, Stephan. 2017. "Insights into Molecular Beryllium–Silicon Bonds." Inorganics 5, no. 2: 22.
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