Binder-Based Sintering Technologies for Titanium and Titanium Alloys

A special issue of Applied Sciences (ISSN 2076-3417). This special issue belongs to the section "Materials Science and Engineering".

Deadline for manuscript submissions: closed (28 February 2019) | Viewed by 3572

Special Issue Editor


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Guest Editor
Institute of Metallic Biomaterials, Helmholtz-Zentrum Hereon, 21502 Geesthacht, Germany
Interests: binder-based sintering technologies; MIM; FFF; titanium; magnesium; microstructure; impurities; fatigue

Special Issue Information

Dear Colleagues,

Sintering in combination with feedstock consisting of metal powder and polymeric binder has been gaining more and more interest within industry and research as an alternative to near-net-shape production by SLM (selective laser melting) and EBM (electron beam melting). Rather established technologies, like MIM (Metal Injection Moulding), as well as tool-less techniques, like FFF (Fused Filament Fabrication) and binder jetting, offer a variety of different possibilities to shape complex geometries. The choice of the specific method depends on boundary conditions, such as the complexity and number of parts to be produced. Independent of the shaping process, all techniques share the same post-processing procedure, namely debinding and sintering. FFF with metal powder-filled filaments, for example, supplements MIM in an ideal manner with respect to prototype manufacturing prior to the production of an expensive mold for MIM. A filament printer is of low cost and debinding and sintering facilities already exist.

However, in addition to MIM, the techniques are being applied slowly and, for all methods, titanium still has a niche presence, in spite of the fact that raw material and conventional processing is relatively expensive. In many cases, MIM or other sintering-based techniques could drastically decrease costs if their special possibilities were exploited.

All powder techniques are actually profiting from the current Additive Manufacturing boost; here, this refers to mainly SLM and EBM, as well as Direct Laser Deposition and related technology. The availability of powders has improved, and the price is decreasing. There are many studies on lowering the costs of a titanium component further through the usage of low-cost powders and simpler processing. MIM is still the better choice for high numbers of identical parts, and sintering is quite easy to control. FFF and binder jetting enable the easy production of individual parts. However, no titanium filament can currently be purchased commercially and the optimal binder is under development. The binder has to be adapted to the specific shaping technology and much research has to be done to ensure the mechanical properties of feedstock and green part, the removal of the binder, and acceptable contamination of the metal during sintering.

Furthermore, cost efficiency is a crucial topic, as is the application of binder-based sintering technologies for demanding fields, like aerospace and the medical science. Here, fatigue properties play an important role, and there is still too little fundamental knowledge. Thus, basic scientific studies and technological investigations have to go hand in hand to enable sintering to become a competitive technology for the conventional processing of titanium and titanium alloys.

This Special Issue gives an overview of the current status in both science and technology. Several key topics are discussed in the papers:

  • The usage of low-cost powders;
  • The reduction of processing costs;
  • Binder development;
  • Fatigue behavior;
  • Basic properties of novel technologies;
  • Microstructure and properties;
  • Influence of impurities;
  • The processing of special alloys;
  • Medical applications;
  • Applications in automotive and aerospace.

Dr. Thomas Ebel
Guest Editor

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Keywords

  • metal injection molding;
  • fused filament printing;
  • binder jetting;
  • solvent jetting;
  • screen printing;
  • tape casting;
  • titanium alloys;
  • low-cost powders;
  • binders;
  • fatigue;
  • impurities;
  • sintering;
  • aerospace;
  • automotive;
  • medical application

Published Papers (1 paper)

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Research

10 pages, 5349 KiB  
Article
The Technological Design of Geometrically Complex Ti-6Al-4V Parts by Metal Injection Molding
by Shulong Ye, Wei Mo, Yonghu Lv, Zhanhua Wang, Chi Tat Kwok and Peng Yu
Appl. Sci. 2019, 9(7), 1339; https://doi.org/10.3390/app9071339 - 29 Mar 2019
Cited by 10 | Viewed by 3149
Abstract
In this study, the metal injection molding (MIM) process is applied to produce Ti-6Al-4V parts using blended and prealloyed powders, respectively. The feedstocks are prepared from a polyformaldehyde-based binder system with a powder loading of 60 vol%, exhibiting a low viscosity. The decomposition [...] Read more.
In this study, the metal injection molding (MIM) process is applied to produce Ti-6Al-4V parts using blended and prealloyed powders, respectively. The feedstocks are prepared from a polyformaldehyde-based binder system with a powder loading of 60 vol%, exhibiting a low viscosity. The decomposition behavior of the binders is investigated and the thermal debinding procedure is designed accordingly. The debound parts are subsequently sintered at 1200 and 1300 °C. The results show the mechanical properties of the sintered samples prepared from blended powder are comparable to those prepared from prealloyed powder, with yield strength of 810 MPa, ultimate tensile strength (UTS) of 927 MPa, and elongation of 4.6%. The density of the as-sintered samples can reach 4.26 g/cm3 while oxygen content is ~0.3%. Based on the results, watch cases with complex shapes are successfully produced from Ti-6Al-4V blended powder. The case gives a good example of applying metal injection molding to mass production of precise Ti-6Al-4V parts with complex shapes in a cost-effective way. Full article
(This article belongs to the Special Issue Binder-Based Sintering Technologies for Titanium and Titanium Alloys)
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