The use of low frequency or DC (i.e., direct current) operation in the electroslag remelting process may lead to the electrolysis of some oxides in the slag pool, which will adversely affect the cleanliness of the electroslag ingot. In order to confirm this view, the effect of different power supply modes on the oxygen content and inclusions in electroslag ingot has been studied by adopting the self-designed electroslag remelting furnace as experimental equipment. The pulse heating inert gas fusion-infra-red absorption method is used for analyzing oxygen content. The analysis of non-metallic inclusion is conducted using an automatic SEM (i.e., scanning electron microscope) made by the American ASPEX Company, where the inclusion type and the inclusion size are determined. Results show that the oxygen content in the electroslag ingot increase significantly compared with that in the consumable metal electrode, whether under the frequency of 50 Hz, low-frequency, or DC. When DCSP (i.e., the consumable electrode is connected to the cathode of the DC power supply), DCRP (i.e., the consumable electrode is connected to the anode of the DC power supply), 2 Hz, 10 Hz, and 50 Hz power supply modes are adopted, the oxygen content in electroslag ingot is 155.3 ppm, 100.4 ppm, 75.8 ppm, 66.3 ppm, and 43.2 ppm respectively. With the increase in oxygen content, the number of inclusions in electroslag ingots increases significantly, and the increased inclusions are mainly Al₂O₃ inclusions. Regardless of the power supply mode, the largest diameter of inclusion is less than 20 μm. The electrolysis of Al₂O₃ is the direct reason for the increase in oxygen in the electroslag ingot when CaF₂-Al₂O₃ slag is used. With the decrease in frequency, the electrolysis trend increases, and the oxygen content and the number of inclusions also increase. However, most of the inclusions are regenerated with the decrease in metal pool temperature and solidification, so the size is fine. Full article

The conventional theoretical forming limit diagram (FLD) based on the plane stress state has defects due to the neglect of the stress in the thickness direction of the sheet. It is urgent to study the FLD which considers the stress in the thickness direction. Through the finite element simulation, it is further confirmed that the stress in the thickness direction will be induced in the deformation process. At the same time, the effect of the induced stress in the thickness direction on FLD is not the same as that always applied stress in the thickness direction during the deformation process. Based on the Modified Maximum Force Criterion (MMFC) instability theory, C-H instability theory, Mises and Hill48 yield criterion, the effects of the two stresses on FLD are compared. The induced stress in the thickness direction also affects the sensitivity of the coefficient of normal anisotropy $r$, but does not significantly change the effect of the stress-strain index $n$ on Forming Limit Curves (FLC). The theoretical calculations of the three materials TRIP780, AA5182, and 5754O are compared with the experimental data, which proves that the FLD which considers induced stress in the thickness direction is more accurate than the FLD of the plane stress. Full article

As a modification of the conventional blast furnace (BF), the top gas recycling-oxygen blast furnace (TGR-OBF) has been continuously studied in the context of the technological transformation of low-carbon metallurgy. As it has a set of new gas inlets in the stack and changes the blast operation system in the hearth, the pressure drop and the in-furnace gas flow are the primary problems to be solved in the TGR-OBF’s industrialization. In this paper, a two-dimensional model of a whole blast furnace, based on a softening-and-melting experiment and porous-medium theory, is established. The in-furnace pressure drop and the gas velocity with different oxygen concentrations and tuyere heights are studied. The results show that the suitable height of the stack tuyere is the same as that of the elevation as the cohesive zone inside the furnace. With the gradual increase in oxygen enrichment, the permeability of the cohesive ore layer (COL) increases, while the gas flow through the coke layer (CL) decreases gradually up to 10%. The simulation results provide a theoretical basis for the TGR-OBF to reduce the coke rate and keep the pressure drop from increasing, or even to enable it to decrease. Full article

The development of advanced materials for extreme dynamic environments requires an understanding of the links between the microstructure and the response of the material (i.e., Materials-by-Design). Spall failure significantly limits material performance at high strain rates, but our understanding of the influence of microstructure on spall strength is limited. While models suggest that increasing the static yield strength by adding precipitates or refining grain size can improve the spall strength, it is possible that the associated increase in nucleation sites may have deleterious effects on spall performance. Herein, we examine spall failure of a Magnesium-Aluminum system with precipitation and grain size strengthening through novel high-throughput laser-driven micro-flyer (LDMF) impact experiments. Six microstructures are investigated, four with grain sizes around 2–3 μm and precipitates around 0.5–1 μm, and two that are precipitate-free with grain sizes around 500 μm at six and nine percent Aluminum contents. The LDMF method allows us to detect differences in spall strength with relatively small changes in microstructure. The spall strength is observed to be strongly affected by varying levels of precipitates and consistently shows a notable reduction in average spall strength around 8–19% with the addition of precipitates, with values ranging from 1.22–1.50 GPa. The spall strength is also seen to decrease with the refinement of grain size independent of composition. However, this decrease is small compared to the hundred-fold grain size reduction. While ductile void growth is observed across all samples, greater variability and a further decrease in strength are seen with an increasing numbers of non-uniformly dispersed precipitates. Full article

In this paper, the effect of rare earth Ce content on the morphology, composition, type and size distribution of inclusions in W350 non-oriented silicon steel was investigated by means of ICP-MS (inductively coupled plasma mass spectrometry), SEM/EDS (scanning electron microscope-energy Dispersive Spectrometer), and ASPEX (automated SEM/EDS inclusion analysis). The results showed that with the increase of Ce content in the steel, the modification sequence of inclusions was CeAlO₃→Ce₂O₂S→Ce_xS_y. The type and size distribution of inclusions in the steel obviously changed with the difference in added Ce content. When the added Ce content in the steel was 10 ppm, 14 ppm, 20 ppm and 30 ppm respectively, the rare earth inclusions were mainly CeAlO₃-Ce₂O₂S. Furthermore, when the added Ce content increased to 60 ppm, the rare earth inclusions were mainly Ce₂O₂S with a small amount of CeAlO₃ contained in part inclusions. When the added Ce content increased continually to 95 ppm, the rare earth inclusions were mainly Ce_xS_y-Ce₂O₂S. The critical Ce content for the conversion between CeAlO₃ and Ce₂O₂S was 41 ppm. To ensure that inclusions transform from CeAlO₃ to Ce₂O₂S, the Ce content in the steel should be greater than 41 ppm. Under the current experimental conditions, it was found that when the Ce content was 20 ppm, the number density and proportion of inclusions in the steel were lower, and their average size was larger. When the added Ce content increased to 95 ppm, the number density of inclusions in the steel significantly increased, which deteriorated the steel cleanliness. Full article

The Silicon on Dust Substrate (SDS) is a gas-to-wafer process that produces multicrystalline silicon ribbons directly from gaseous feedstock (silane), avoiding the standard industry steps of polysilicon deposition, crystal growth, and wafering. The SDS technique consists of three main steps: (i) micrometric-sized silicon powder production by grinding silicon chunks; (ii) chemical vapor deposition (CVD) of silicon over this silicon powder substrate; and (iii) zone-melting recrystallization (ZMR) of the nanocrystalline pre-ribbon obtained in the CVD step. Several samples were produced by this technique. During CVD, mechanically self-sustained nanocrystalline pre-ribbons were grown over silicon powder substrates, with growth rates in the order of 50 µm/min. The ZMR process performance is substantially impacted by the pre-ribbon physical characteristics. The best and largest recrystallizations were achieved on pre-ribbons grown over powder substrates with smaller particle sizes, which also have lower substrate powder incorporation ratios. Multicrystalline silicon ribbons with crystalline areas as large as 2 × 4 cm² were successfully produced. These areas have visible columnar crystal growth with crystal lengths up to 1 cm. The SDS ribbons’ measured resistivity confirmed the high powder content of the resulting material. The ability to produce solar cells on SDS multicrystalline silicon ribbons was demonstrated. Full article

The coefficient of linear thermal expansion and the specific heat capacity of laser-deposited Cu-Fe alloys fabricated from tin, aluminum, chromium bronze (89–99 wt.% Cu), and SS 316L were studied. The investigated alloys had a 1:1 and a 3:1 bronze–steel ratio. The Al–bronze-based alloy showed the lowest value of linear thermal expansion coefficient: (1.212 ± 0.095)∙10⁻⁵ K⁻¹. Contrarily, this value was the highest {[(1.878–1.959) ± 0.095]∙10⁻⁵ K⁻¹} in the case of functionally graded parts created from alternating layers of bronze and steel. Differential scanning calorimetry provided experimental results about the specific heat capacity of the materials. In the case of Al–bronze-based specimens, it demonstrated a decrease in the specific heat capacity until ~260 °C and its further increase during a heating cycle. Exothermic peaks related to polymorphic transformations were observed in the Al–bronze-based specimens. Cooling cycles showed monotonous behavior for specific heat capacities. It had exothermic peaks in the case of Cr–bronze-based alloys. A Lennard-Jones potential equation was used for testing the relation between heat capacity and thermal expansion. A three-way interaction regression model validated the results and provided the relative thermal expansion of commercially pure DED-fabricated SS 316L. Its specific heat capacity was also studied experimentally and was 15–20% higher in comparison to the traditional method of production. Full article

Refractory high-entropy alloys (RHEAs) have recently attracted widespread attention due to their outstanding mechanical properties at elevated temperatures, making them appealing for concentrating solar power and nuclear energy applications. Here, the corrosion behavior of equimolar HfTaTiVZr and TaTiVWZr RHEAs was investigated in molten FLiNaK eutectic salt (LiF-NaF-KF: 46.5−11.5−42 mol.%) at 650 °C. Potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and immersion test measurements were carried out for these two RHEAs and compared with Inconel 718 (IN718) superalloy and SS316 stainless steel under identical test conditions. Both TaTiVWZr and HfTaTiVZr refractory high-entropy alloys exhibited an order of magnitude lower corrosion rate than SS316. IN718 and TaTiVWZr showed similar corrosion rates. Corrosion products enriched with noble alloying elements formed in the case of TaTiVWZr and IN718 were stable and protective on the substrate. SS316 showed the lowest corrosion resistance and void formation along the exposed surface due to the active dissolution of Cr and Fe, which provided diffusion paths for the corroded species. The surface analysis results showed that IN718 underwent pitting corrosion, while TaTiVWZr experienced selective dissolution in the inter-dendritic area. In contrast, HfTaTiVZr and SS316 experienced corrosion at the grain boundaries. Full article

This work focused on the synergistic effect of hydrostatic pressure (HP) within the range of 0.1~50 MPa and a dissolved oxygen (DO) concentration within the range of 0.18~11.8 ppm on the stress corrosion cracking (SCC) behavior of hydrogenated Ti6Al4V alloy in a simulated deep-sea environment by electrochemical measurements and slow strain rate tensile (SSRT) tests. The potentiodynamic polarization and electrochemical impedance spectra results confirmed the corrosion resistance degradation with the HP increasing to 50 MPa. The fracture morphologies showed a mixed characteristic of brittle fracture on the surface layer and ductile fracture in the inner part. Higher HPs increased SCC susceptibility while a larger DO concentration decrease that of Ti6Al4V alloy. Full article

2219 aluminum–copper alloy is a major material in launch vehicles transition rings. The study of dynamic recrystallization during its rolling and forming process is beneficial to improving the performance enhancement of 2219 aluminum alloy ring parts. In this paper, a multi-scale simulation of grain refinement and distribution of dynamic recrystallization (DRX) grains during the rolling of 2219 aluminum alloy rings is carried out using the finite element method and cellular automata method. On the basis of the JMK DRX model, an ABAQUS subroutine was written to simulate the ring-rolling of 2219 aluminum alloy, and the distribution of DRX percentage and average grain size was analysed from a macroscopic point of view, with a maximum DRX level of 12% and an average grain size distribution from 247 μm to 235 μm from the inside of the aluminum alloy ring towards the surface. A cellular automaton model of DRX during rolling of large aluminum alloys was developed to effectively simulate DRX nucleation, growth, and grain compression deformation during rolling. The DRX nucleation occurs at the grain boundaries and then grows, resulting in a homogeneous organisation and a refinement of grain size, with both the original and DRX grains being compressively deformed as the rolling process progresses and the grains being gradually elongated tangentially. Finally, a comparison of the experimental results with the simulations to obtain grain size and morphology demonstrates consistent results, indicating that the combination of FE and CA methods is an effective approach for a more comprehensive understanding of the microstructural evolution during rolling. Full article

Shape memory alloys (SMAs) are types of materials that can restore their original shape upon severe or quasi-plastic deformation, being exposed to specific external stimuli, including heating, electric current, magnetic field, etc. They are a category of functional materials that provides superelasticity as a significant material property. The roots of this unintentional discovery were in the 20th century, and later it attracted the attention of various industries, including aerospace, medical, mechanical, manufacturing industries, etc. Later developments mainly focused on improving the properties of these materials. One of the ways in which this is achieved is the application of intensive plastic strains on SMAs through severe plastic deformation (SPD) methods, leading to extreme grain refinement. Superelasticity is a key characteristic of SMAs and is known as the capacity of a polycrystalline material to display extremely high elongations before failure, in a typically isotropic way, with an approximate strain rate of 0.5. Utilization of SPD techniques can also affect and lead to superior superelasticity responses in SMAs. Several SPD methodologies have been introduced over the decades, to produce ultrafine-grained and even nanostructured materials, including constrained groove pressing, equal-channel angular pressing, high-speed high-pressure torsion, accumulative roll bonding, etc. This paper aims to present a clear view of the mechanical properties and microstructure evolution of shape memory alloys after processing by some SPD methods, and to show that SPD methods can be a great option for developing SMAs and expanding their industrial and technological applications. Full article

Generally, excellent mechanical properties of Mg alloys are desired, but their rapid degradation properties are seldom utilized. Petroleum fracturing techniques are required to take full advantage of this rapid degradation. Therefore, we have prepared an as-extruded Mg–6.0Gd–1.2Cu–1.2Zr (wt.%) alloy and treated it with peak aging to analyze its potential as a degradable fracture ball. The results show that the as-extruded alloy mainly consists of an α-Mg matrix, second phase, and large elongated α-Mg grains (LEGs). After aging, the LEGs undergo static recrystallization, which improves the mechanical properties of the alloy, and a lamellar long period stacking ordered (LPSO) phase is observed. Under simulated underground temperature conditions (93 °C), the ultimate tensile strength and elongation of both as-extruded and as-aged alloys are over Ȧ MPa and 11.1%, respectively, and the ultimate compressive strength and elongation of both alloys are over 336 MPa and 16.9%, respectively. The corrosion rate of the as-extruded alloy in 3 wt.% KCl solution at 93 °C reaches 1660.8 mm/y by mass loss test, and that of the as-aged alloy increases to 1955.1 mm/y. The atomic force microscope analysis result confirms that the second phase shows the highest corrosion potential, followed by the lamellar LPSO phase and α-Mg matrix. The as-extruded and as-aged Mg–6.0Gd–1.2Cu–1.2Zr alloy with good mechanical properties and a high corrosion rate in this work shows promising potential for degradable fracturing ball applications. Full article

In this study, MgO/Mg composites were prepared using direct melt oxidation to verify the effects of elastic deformation and microplastic deformation on the damping properties. It was found that the composites have high damping properties at a certain strain amplitude, which indicated that the damping properties of the magnesium matrix were effectively enhanced by the in situ-synthesized oxide particle. In addition, other damping mechanisms different from the G–L dislocation damping mechanism exist in MgO/Mg composites, i.e., the damping mechanism of the microplastic deformation, leading to a model of microplastic deformation damping established and its mechanistic analysis. Full article

Complex multi-phase phenomena, including turbulent flow, solidification, and magnetohydrodynamics (MHD) forces, occur during the continuous casting (CC) under the applied electromagnetic brake (EMBr). The results of the small-scale experiment of the liquid metal model for continuous casting (mini-LIMMCAST) at the Helmholtz-Zentrum Dresden-Rossendorf (HZDR), investigating MHD flow with a deep immersion depth of 100 mm, are supplemented by newly presented numerical studies with the shallow position of the submerged entry nozzle (SEN) at 50 mm below the meniscus. Herein, the focus is on the MHD effects at the meniscus level considering (i) a fully insulating domain boundary, (ii) a perfectly conductive mold, or (iii) the presence of the solid shell. The volume-of-fluid (VOF) approach is utilized to model a Galinstan flow, including free surface behavior. A multiphase solver is developed using conservative MHD formulations in the framework of the open-source computational fluid dynamics (CFD) package OpenFOAM^®. The wall-adapting local eddy-viscosity (WALE) subgrid-scale (SGS) model is employed to model the turbulent effects on the free surface flow. We found that, for the deep immersion depth, the meniscus remains calm under the EMBr for the conductive and semi-conductive domain. For the insulated mold disregarding the SEN position, the self-inducing MHD vortices, aligned with the magnetic field, cause strong waving of the meniscus and air bubble entrapment for shallow immersion depth. Secondary MHD structures can form close to the meniscus under specific conditions. The influence of the EMBr and immersion depth on the flow energy characteristics is analyzed using power spectral density (PSD). Full article

Austenitic stainless steels that exhibit good corrosion resistance have recently found increasing applications in industry and transportation. This article addresses the influence of cold rolling and deformation on the pitting corrosion resistance of AISI 301LN and 316L stainless steels. The results indicate that the content of martensite increases as the cold rolling reduction also increases. The current work combined different techniques such as optical microscopy and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDS) analyses. Corrosion tests were carried out, in accordance with the ASTM standards. The results confirm that the 316L steel performed better than the 301LN, regarding pitting corrosion, even when deformed. This is due to the high molybdenum (Mo) content, which guarantees greater corrosion resistance. The conducted corrosion tests showed that the increase of cold deformation reduces the resistance to pitting and overall corrosion in both steels. It was found that the 301LN stainless steel has higher susceptibility to deformation-induced martensite and, despite the addition of nitrogen, it still has a lower performance relative to the 316L steel. The current work focused on evaluating the formation of pits and the dynamics of the microstructures of the AISI 301LN and 316L steels with their mechanical properties and corrosion resistance in a saline environment including chlorides. Full article

In crystals, lattice defects, such as dislocations, control mechanical deformation. Similarly, it is widely believed that even in glasses and liquids some kinds of defects, strongly disordered regions, play a major role in deformation. To identify defects researchers focused on the nature of the short-range order (SRO) in the nearest neighbor cage of atoms. However, recent results by experiment, simulation and theory raise serious questions about this assumption. They suggest that the atomic medium-range order (MRO) provides resistance against flow at the atomic level. Because the MRO is a bulk property, it implies that defects play only a limited role. This new insight is supported by the density wave theory which shows that the MRO is driven by a top-down global force, rather than being a consequence of the SRO in the bottom-up manner, and the MRO provides stiffness to resist deformation. We briefly summarize the density wave theory, show that the MRO is related to ductility of metallic glasses, and discuss the implications on the role of the MRO in the atomic-level mechanism of deformation. Full article

Increasing the use of steel scrap and enhancing its recycling utilization are important strategies for fostering the low-carbon and environmental-friendly growth of the iron and steel industry in China. However, the current steelmaking processes cannot efficiently remove the residual elements in the scrap, such as Cu, Sn, As, and Sb. As a result, the above elements are recycled and accumulate in the scrap, which will eventually have a negative impact on the properties of steel. Currently, there are few studies on Sb removal from molten steel. To remove the residual element Sb in molten steel, the CaO-SiO₂-Al₂O₃ refining slag system containing CaC₂ was used, and the effect of the CaC₂ content in the molten slag, slag quantity, smelting temperature, and initial Sb and C contents in molten steel on the Sb removal ratio in the steel was investigated, and the mechanism of Sb removal by the aforementioned refining slag system was discussed in order to provide some experimental and theoretical basis for industrialization practice. When the smelting time is 5~10 min, the removal ratio of Sb from molten steel is at its peak and can reach 45.8%. The ”Sb-reversion” phenomenon will appear in the molten steel when the smelting period is progressively extended. In molten steel, CaC₂ will preferentially react with O and S, and as the smelting temperature decreases, the distribution ratio of Sb, L_Sb, improves. An increased initial Sb content in molten steel and slag quantity are beneficial to improving the removal ratio of Sb, but an increased initial C content in molten steel is detrimental to the progress of the Sb removal reaction. The removal reaction of Sb from molten steel by CaC₂ is a reversible reaction, and the diffusion of the products from the interface is the limiting factor of the overall reaction. Full article