Potential landslide identification and monitoring are essential to prevent geological disasters. However, in mountainous areas where the surface gradient changes significantly, the leveling effect is not completely removed, affecting the deformation results. In this paper, the SBAS-InSAR and PS-InSAR time-series processing methods were combined to interfere with the SAR image data of the ascending orbit in the southern mountainous area of Ningxia and its surrounding regions. Based on the obtained surface deformation monitoring results and optical images, landslide hazard identification was successfully carried out within the coverage area of 3130 km² in Xiji County. The results show that the whole study area presented a relatively stable state, most of the deformation rates were concentrated in the range of 0 mm/a to −10 mm/a, and the deformation in the southwest area was larger. A total of 11 large potential landslides (which were already registered potential danger points of geological disasters) were identified in the study area, including three historical collapses. The landslide identification results were highly consistent with the field survey results after verification. The timing analysis of the typical landslide point of the Jiaowan landslide was further carried out, which showed that the Jiaowan landslide produced new deformation during the monitoring time, but it was still in a basically stable state. It can do a good job in disaster prevention and reduction while strengthening monitoring. The results of this study have a guiding effect on landslide prevention and mitigation in the mountainous areas of southern Ningxia. Full article

Fingerlings (0.23 g) and juveniles (267.04 g) of African catfish (Clarias gariepinus) were reared for 32 days under experimental aquarium conditions and were exposed to either 0.75 mg/L or 3.0 mg/L diethylenetriaminepentaacetic acid-iron(II) (Fe-DTPA) and 3.0 mg/L or 12.0 mg/L Fe-DTPA in the water, respectively. These treatment groups were compared to a control group without additional Fe-DTPA. The growth, mortality, ethological indicators (activity, agonistic interactions, air-breathing), leukocyte distribution, histopathological changes in liver and gills, and genetic biomarkers were evaluated for each group. While the growth, mortality, and behavior were not significantly different between the groups, the lymphocyte count in the fish’s blood increased significantly in all groups during the course of the experiment, but independently from the treatments. A similar trend (p > 0.05) was observed in monocytes. The number of granulocytes decreased significantly, but independently from the treatments. These changes indicated the possibility of an ongoing immune response in the fish from all treatments that might be caused by the increasing aggressive behavior of the fish. However, the Fe-DTPA treatments did not cause a notable suppression or enhancement of the immune reactions. Fe³⁺ accumulations in liver tissues were detected at the tested concentrations, and further changes occurred in the cells of the gills. Gene-expression biochips were used to simultaneously quantify the transcript levels of 34 genes associated with iron metabolism and stress physiology in head kidney samples. The obtained gene-expression profiles did not reveal any significant differences across either the different treatments or the time points. The results indicate that Fe-DTPA supplementation in the tested concentrations can be considered relatively harmless for the health and welfare of African catfish. Full article

Groundwater belongs to the category of strategic minerals, along with hydrocarbon resources, so the supply of drinking water will become one of the urgent problems of modern society. The management of groundwater resources and their protection is a very complicated task, especially in border areas where neighboring states jointly exploit aquifers. The problem of transboundary water resources management, in particular groundwater, has been considered at the international level for more than 30 years. However, despite the adoption of a number of conventions, agreements and programs, both at the global and in the format of interstate relations, an understanding for the approach of a universal solution to the transboundary water issue has not yet been formed. An attempt to study the possibilities of applying the principles of unitization on the example of transboundary oil and gas fields in comparison with groundwater cross-border deposits is made in the paper for the first time. As a successful example, the unitization agreement between Norway and the UK for the development of the Frigg field was chosen. It is established that unitization agreements concluded by states in the joint development of transboundary mineral deposits, actively used in regulating the activities of transboundary oil and gas fields, can be used as one of the possible models of international agreements on the extraction of groundwater in transboundary territories. Full article

Dam surveillance activities are based on observing the structural behaviour and interpreting the past behaviour supported by the knowledge of the main loads. For day-to-day activities, data-driven models are usually adopted. Most applications consider regression models for the analysis of horizontal displacements recorded in pendulums. Traditional regression models are not commonly applied to the analysis of relative movements between blocks due to the non-linearities related to the simultaneity of hydrostatic and thermal effects. A new application of a multilayer perceptron neural network model is proposed to interpret the relative movements between blocks measured hourly in a concrete dam under exploitation. A new methodology is proposed for threshold definition related to novelty identification, taking into account the evolution of the records over time and the simultaneity of the structural responses measured in the dam under study. The results obtained through the case study showed the ability of the methodology presented in this work to characterize the relative movement between blocks and for the identification of novelties in the dam behaviour. Full article

Chacao channel bridge is located in a tidal channel with highly-energetic hydrodynamics conditions and significant erodibility potential. Once finished, this 2.5 km long cable-stayed bridge will be the largest in South-America. Here we report an integrated procedure to estimate scour around two of its three towers, both located on a relatively complex but different soil matrices. A high-resolution hydrodynamic model based on the Reynolds-averaged Navier–Stokes equations (RANS), physical tests of in situ soil samples in a Rotating Erosion Testing Apparatus (RETA) and empirical formulas for scour estimation are combined to provide a reliable estimation of scour depth under a periodic tidal ebb-flow regime. The relatively homogeneous soil material at the North Tower shows a high susceptibility to hydrodynamic erosion, which is estimated with SRICOS methodology. The Central Tower, in contrast, needs a combined approach based on the current state of the rock, information collected from underwater explorations and theoretical progress made about rock scour in order to reduce the uncertainty of the soils’ substrate. This study reveals that scour estimation for engineering design purposes in complex soils can be achieved with a joined vision of different disciplines and modelling tools for minimizing the uncertainty. Full article

Climate change, worsening freshwater quality, and anthropogenic factors have caused water caltrop to lose approximately 80% of its habitat in Poland since the early 1980s. The presence of this plant species has substantially changed since the end of the 19th century. Our aim in this study was to examine the habitat and conservation status of Trapa natans in the Szumirad reservoir and Nowokuźnicki pond reserve in Poland and to indicate sources of potential hazards for the analyzed population. To achieve this aim, we spatially analyzed the changes in the total reservoir area, dynamics of species population, physico-chemical parameters of water, and climatic data. For the Szumirad reservoir, we observed substantial changes in water caltrop quantity and condition. For the Nowokuźnicki pond reserve, we found a serious threat to the Trapa habitat posed by the developing Nupharo–Nymphaeetum albae association, which is a strong competitor of nymphaeids. The obtained results indicated that surface waters localized in protected areas might play an important role in maintaining the population of water caltrop. On the basis of our analyses of selected populations, we emphasize that present protection procedures should be supplemented with the active protection of the species. Full article

Using low permeability soils in landfill liners is a guaranteed leachate control and prevents leakage which causes environmental pollution. In this matter, the application of new technologies such as nano provides more capable filters that are used for reducing leachate pollutants and modifying the geotechnical properties of liners. The presented study attempted to conduct experimental research on nanoclay–nanofiber composite usage to control landfill liner permeability and observe its impact on the geotechnical characteristics of liners which provide a strong barrel for leachate leakage prevention and increase the liner durability for crack generations. In this regard, a total of 120 different geotechnical experiments were performed on mixed improved fine-grained soil samples which were categorized into four groups including nanoclay additives, nanofiber additives, nanocomposite additives, and control samples (without additives). According to the experimental results, permeability decreased, and geotechnical properties (e.g., Atterberg limits, unconfined compressive strength, cohesion, and friction) were increased with increasing nanocomposite content in the soil. Full article

This paper reports a high efficiency uptake of captopril (CPT), employing magnetic graphene oxide (MGO) as the adsorbent. The graphene oxide (GO) was produced through an oxidation and exfoliation method, and the magnetization technique by the co-precipitation method. The nanomaterials were characterized by FTIR, XRD, SEM, Raman, and VSM analysis. The optimal condition was reached by employing GO·Fe₃O₄ at pH 3.0 (50 mg of adsorbent and 50 mg L⁻¹ of CPT), presenting values of removal percentage and maximum adsorption capacity of 99.43% and 100.41 mg g⁻¹, respectively. The CPT adsorption was dependent on adsorbent dosage, initial concentration of adsorbate, pH, and ionic strength. Sips and Elovich models showed the best adjustment for experimental data, suggesting that adsorption occurs in a heterogeneous surface. Thermodynamic parameters reveal a favorable, exothermic, involving a chemisorption process. The magnetic carbon nanomaterial exhibited a high efficiency after five adsorption/desorption cycles. Finally, the GO·Fe₃O₄ showed an excellent performance in CPT removal, allowing future application in waste management. Full article

Particle aggregation modifies sediment dynamics, which is a determining factor for morphodynamic and ecological processes in deltaic plains. Here, we investigated the link between intra-annual hydrodynamics variability and flocculation in the Grijalva-Usumacinta system. Monthly (2016–2017) and seasonal (2021–2022) river data was processed using analytical methods and the simplified sonar equation. Flocs were reformed and characterized in the laboratory, validating the in situ settling velocities (0.5–3.8 mm/s) and the existence of large low-density macro-flocs (>300 μm). We verified that flocculation prevailed, exhibiting seasonal patterns; (1) the highest aggregation rates matched the increase in total suspended solids at rising-flow (>100 mg/L), (2) periods of high-flow showed stable aggregation rates, and (3) an influence of marine conditions occurred at low-flow. Particulate phosphorous and organic fraction showed seasonal patterns linked to flocculation. Due to damming, the shear rates varied slightly (7–11 L/s) in the Grijalva, leading to high flocculation intensities affecting the diffusivity ratio. In the Usumacinta, aggregation was limited by shear rates that normally exceed 15 1/s. We found seasonal Rouse parameters representative of sediment dynamics. Full article

The influence of anthropogenic and natural factors in the trends and mechanisms of development at various topological levels is determined based on relevant information on the structure and dynamics of fluvial systems in the south of Eastern Siberia in various geodynamic settings. This article considers the current spatial and temporal dynamics of the hydrological conditions of the vast territory of the Angara River and its influence on channel deformations and the manifestation of dangerous processes. An analysis of fluctuations in the maximum runoff using differential integral curves resulted in the identification of six periods of water content according to the maximum annual discharges for the period spanning from the beginning of observations to 2020 for the rivers under consideration. The dynamics and intensity of manifestation of hydrological and geological hazardous processes are demonstrated using a series of studies conducted under various geodynamic conditions. Catastrophic floods brought on by enhanced cyclonic activity are accompanied by the destruction of the bank. The highest rate of bank erosion in the plains is 1.5 to 2 m per year, and for rivers in mountains and piedmonts it is 2 to 6 m per year. An analysis of the dynamics of the development of floodplain–channel complexes in the Upper Angara region makes it possible to distinguish two zones of actively developing floodplain–channel complexes: piedmont and estuarine, separated by a relatively stable plain zone. Full article

This study evaluates the effects of carbon, nitrogen, and sulfur dopants on the photocatalytic activity of TiO₂ for degradation of oxytetracycline (OTC) and chemical oxygen demand (COD) removal from licorice extraction plant wastewater (LEPW). Three novel visible-light-responsive nanostructures, including L-Histidine-TiO₂, L-Methionine-TiO₂ and L-Asparagine-TiO₂, were successfully synthesized. The results showed that the modification of TiO₂ with these three amino acids made the catalyst active in the visible light region and reduced the recombination rate of e⁻/h⁺ pairs according to PL analysis. The photodegradation efficiency of L-Histidine (2 wt.%)-TiO₂ was 100% and 94% for OTC and COD, respectively. It showed the highest photocatalytic activity under illumination, compared to L-Methionine (1.5 wt.%)-TiO₂ and L-Asparagine (2 wt.%)-TiO₂. Synthesized composites were characterized with SEM, XRD, FTIR, DRS, and PL analyses. The biological oxygen demand to COD (BOD₅/COD) ratio for treated LEPW was determined to be 0.5–0.6, confirming the enhanced biodegradability of the treated effluent. The effect of the independent variables, namely, initial concentration of OTC and COD, catalyst dosage, irradiation time, pH of solution, and light intensity, on the photocatalytic process was evaluated by Response Surface Methodology (RSM), and the optimum value of each independent parameter for maximum degradation of OTC and COD by L-Histidine (2 wt.%)-TiO₂ was determined. The radical trapping experiment was performed with various scavengers in order to propose a photocatalytic mechanism, showing that hydroxyl radicals were the main active species. L-Histidine (2 wt.%)-TiO₂ showed a stable and reusable structure even after four cycles of COD removal under the following optimal conditions of [COD]: 300 mg/L, [catalyst]: 1 g/L, light intensity: 25 W/cm² at pH = 4 after 180 min irradiation. Full article

In order to evaluate and project the quality of groundwater utilized for irrigation in the Sahara aquifer in Algeria, this research employed irrigation water quality indices (IWQIs), artificial neural network (ANN) models, and Gradient Boosting Regression (GBR), alongside multivariate statistical analysis and a geographic information system (GIS), to assess and forecast the quality of groundwater used for irrigation in the Sahara aquifer in Algeria. Twenty-seven groundwater samples were examined using conventional analytical methods. The obtained physicochemical parameters for the collected groundwater samples showed that Ca²⁺ > Mg²⁺ > Na⁺ > K⁺, and Cl⁻ > SO₄²⁻ > HCO₃⁻ > NO₃⁻, owing to the predominance of limestone, sandstone, and clay minerals under the effects of human activity, ion dissolution, rock weathering, and exchange processes, which indicate a Ca-Cl water type. For evaluating the quality of irrigation water, the IWQIs values such as irrigation water quality index (IWQI), sodium adsorption ratio (SAR), Kelly index (KI), sodium percentage (Na%), permeability index (PI), and magnesium hazard (MH) showed mean values of 47.17, 1.88, 0.25, 19.96, 41.18, and 27.87, respectively. For instance, the IWQI values revealed that 33% of samples were severely restricted for irrigation, while 67% of samples varied from moderate to high restriction for irrigation, indicating that crops that are moderately to highly hypersensitive to salt should be watered in soft soils without any compressed layers. Two-machine learning models were applied, i.e., the ANN and GBR for IWQI, and the ANN model, which surpassed the GBR model. The findings showed that ANN-2F had the highest correlation between IWQI and exceptional features, making it the most accurate prediction model. For example, this model has two qualities that are critical for the IWQI prediction. The outputs’ R² values for the training and validation sets are 0.973 (RMSE = 2.492) and 0.958 (RMSE = 2.175), respectively. Finally, the application of physicochemical parameters and water quality indices supported by GIS methods, machine learning, and multivariate modeling is a useful and practical strategy for evaluating the quality and development of groundwater. Full article

A comprehensive framework for revealing the jeopardization between SDGs 2 and 6 is provided in this study. Along with a water footprint (WF) assessment, the 30-years pattern of agricultural WFs and its hydro-environmental, social, and ecopolitical (SEP) consequences were quantified for the major food producer regions of Iran, as it is a water-bankrupted country under socioeconomic drought. In addition, the enforced impacts of major water/food-related policies on environmental sustainability were analyzed through an institutional assessment. During 1986–2016, BWS and GWD raised with annual average rates of 5% and 44%, respectively. Consequently, SEP status prospered along with an 18% increase in irrigated area, 198% in added-value by crop production and 5% by staple-crop exports, and 51% in the number of agricultural workers. The Pearson correlation analysis revealed a significant tradeoff between self-supplied food availability and SEP. A 54% increase in food production occurred at the cost of 80% overexploitation in blue water resources and quality degradation. An annual average increase of 1.1% in P/ETo indicates the dominant role of anthropogenic interventions in such deteriorations. The institutional assessment demonstrated that environmental sustainability policies have never been applied as promoting policies to boost self-sufficiency in food production. According to the results, hydrological sustainability requires a transformative vision in national policies to exploit limited water and soil resources while preserving the environment. Full article

Automatic flushing valve (AFV) can improve the anti-clogging ability of the drip fertigation system. The minimum inlet pressure (H_amin) required for automatic closing and the maximum flushing duration (FD_max) are two important performance indexes of AFV. The existing AFV products have the problem of larger H_amin and smaller FD_max, which result higher investment and operating cost, and poor flushing efficiency. Based on the mechanical analysis of the AFV elastic diaphragm and the derivation of the FD, elastic diaphragm hardness (E), ascending channel offset distance (D), and drain hole width (W) were selected as the experimental factors, and nine AFVs were designed by L₉(3³) orthogonal test method to investigate the influence of elastic diaphragm hardness and structural parameters on the hydraulic performance of AFVs. The hydraulic performance test results showed that the H_amin of the nine AFVs ranged from 0.026 to 0.082 MPa and FD_max ranged from 36.3 to 95.7 s. H_amin was positively correlated with E and D and negatively correlated with W. FD_max was negatively correlated with E and W and tended to increase and then decrease with D. All elastic diaphragm hardness and structural parameters had a significant effect on H_amin, and E and W had a significant effect on FD_max. Based on the range analysis, two new combinations of AFV elastic diaphragm hardness and structural parameters with minimum H_amin (E = 40 HA, D = 0 mm, W = 2 mm) and maximum FD_max (E = 40 HA, D = 2 mm, W = 1.68 mm) were determined, and the corresponding H_amin was 0.022 MPa, 63.3% lower than that of the existing product, and FD_max was 116.4 s, 71.2% higher than that of the existing product. In this study, two ternary nonlinear mathematical regression models of H_amin and FD_max with elastic diaphragm hardness and structural parameters was constructed. The simulation accuracy of the models is good and can be used to quickly predict the optimal combination of AFV parameters to satisfy the actual engineering-required H_amin and FD_max. Full article

Optimizing pump operation in water networks can effectively reduce the cost of energy. To this end, the literature provides many methodologies, generally based on an optimization problem, that provide the optimal operation of the pumps. However, a persistent shortcoming in the literature is the lack of further analysis to assess if the obtained solutions are feasible from the technical point of view. This paper first showed that some of these available methodologies identify solutions that are technically unfeasible because they induce tank overflow or continuous pump switching, and consequently, proposed a novel approach to avoiding such unfeasible solutions. This consisted in comparing the number of time-steps performed by the hydraulic simulator with the predicted value, calculated as the ratio between the simulation duration and the hydraulic time-step. Finally, we developed a new model which couples Epanet 2.0 with Pikaia Genetic Algorithm using the energy cost as an objective function. The proposed method, being easily exportable into existing methodologies to overcome the limitations thereof, thus represents a substantial contribution to the field of pump scheduling for optimal operation of water distribution networks. The new method, tested on two case studies in the literature, proved its reliability in both cases, returning technically feasible solutions. Full article