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Molecules 2010, 15(8), 5756-5767; doi:10.3390/molecules15085756
Article

Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst

1, 1,* , 1, 2 and 2
Received: 28 June 2010; in revised form: 10 August 2010 / Accepted: 18 August 2010 / Published: 23 August 2010
(This article belongs to the Special Issue Ring-Closing Metathesis)
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Abstract: The synthesis of a monosilylated Grubbs-Hoveyda ruthenium alkylidene complex is described, as well as the preparation and characterization of the corresponding material by sol-gel cogelification with tetraethoxysilane (TEOS) and the assay of this recyclable supported catalyst in ring-closing diene and enyne metathesis reactions under thermal and microwave conditions.
Keywords: catalyst immobilization; ring-closing metathesis; organic-inorganic hybrid material; ruthenium alkylidene; sol-gel process catalyst immobilization; ring-closing metathesis; organic-inorganic hybrid material; ruthenium alkylidene; sol-gel process
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Borja, G.; Pleixats, R.; Alibés, R.; Cattoën, X.; Man, M.W.C. Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst. Molecules 2010, 15, 5756-5767.

AMA Style

Borja G, Pleixats R, Alibés R, Cattoën X, Man MWC. Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst. Molecules. 2010; 15(8):5756-5767.

Chicago/Turabian Style

Borja, Guadalupe; Pleixats, Roser; Alibés, Ramón; Cattoën, Xavier; Man, Michel Wong Chi. 2010. "Organic-Inorganic Hybrid Silica Material Derived from a Monosilylated Grubbs-Hoveyda Ruthenium Carbene as a Recyclable Metathesis Catalyst." Molecules 15, no. 8: 5756-5767.



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