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The Heck Reaction in Ionic Liquids: Progress and Challenges
Molecules 2010, 15(4), 2667-2685; doi:10.3390/molecules15042667
Review

The Heck Reaction Applied to 1,3- and 1,2-Unsaturated Derivatives, a Way towards Molecular Complexity

* , ,  and
Received: 1 February 2010; in revised form: 26 March 2010 / Accepted: 1 April 2010 / Published: 13 April 2010
(This article belongs to the Special Issue Heck Coupling)
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Abstract: This review is an overview of the last ten years’ use of the Mizoroki–Heck coupling applied to 1,2- and 1,3-dienes. Since both these systems form π-allyl palladium intermediates in Pd(0) coupling, they show particular chemical behavior. Many examples of 1,2-dienes Heck reactions are presented. 1,2-Dienes are important substrates because of their high reactivity that makes them useful building blocks for the synthesis of biologically relevant structures.
Keywords: Mizoroki–Heck reaction; palladium; 1,2-dienes; 1,3-dienes Mizoroki–Heck reaction; palladium; 1,2-dienes; 1,3-dienes
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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MDPI and ACS Style

Deagostino, A.; Prandi, C.; Tabasso, S.; Venturello, P. The Heck Reaction Applied to 1,3- and 1,2-Unsaturated Derivatives, a Way towards Molecular Complexity. Molecules 2010, 15, 2667-2685.

AMA Style

Deagostino A, Prandi C, Tabasso S, Venturello P. The Heck Reaction Applied to 1,3- and 1,2-Unsaturated Derivatives, a Way towards Molecular Complexity. Molecules. 2010; 15(4):2667-2685.

Chicago/Turabian Style

Deagostino, Annamaria; Prandi, Cristina; Tabasso, Silvia; Venturello, Paolo. 2010. "The Heck Reaction Applied to 1,3- and 1,2-Unsaturated Derivatives, a Way towards Molecular Complexity." Molecules 15, no. 4: 2667-2685.


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