Inclusion removal and modification of C96V saw wire steel using Na₂O- and Rb₂O- containing novel low-basicity LF (ladle furnace) Refining Slags have been researched. The results indicated that the addition of Na₂O deteriorates inclusion removal; by contrast, the addition of Rb₂O seems to significantly enhance inclusion removal. In detail, Rb₂O can improve the cleanliness in the as-quenched C96V saw wire steel melts compared to preexisting synthetic LF refining slag compositions: (i) The average inclusion diameter experienced a remarkable decrease after reaction between the liquid steel and the synthetic LF refining slag; (ii) In addition, the number of inclusions also suffered from a dramatic decrease, with the reaction time increasing from 900 to 2700 s (15 to 45 min); (iii) Furthermore, both of the MnO-SiO₂-Al₂O₃ and CaO-SiO₂-Al₂O₃ inclusion system mainly concentrated in the low melting zone when the composition of Rb₂O in synthetic refining slag was ≥5.0 wt%. This is mainly because Na₂O significantly reduces the viscosity of refining slag, while Rb₂O increases it. Then, there are two remarkable influences causing the increase of viscosity of refining slag with the addition of Rb₂O: the inclusions can be sufficiently entrained within the slag once absorbed due to the significant increase in the viscosity; and the slag entrapment during refining process weakened dramatically. Full article

We characterize the time evolution (≤120 s) of atmospheric-pressure plasma jet (APPJ)-synthesized Pt-SnO_x catalysts. A mixture precursor solution consisting of chloroplatinic acid and tin(II) chloride is spin-coated on fluorine-doped tin oxide (FTO) glass substrates, following which APPJ is used for converting the spin-coated precursors. X-ray photoelectron spectroscopy (XPS) indicates the conversion of a large portion of metallic Pt and a small portion of metallic Sn (most Sn is in oxidation states) from the precursors with 120 s APPJ processing. The dye-sensitized solar cell (DSSC) efficiency with APPJ-synthesized Pt-SnO_x CEs is improved greatly with only 5 s of APPJ processing. Electrochemical impedance spectroscopy (EIS) and Tafel experiments confirm the catalytic activities of Pt-SnO_x catalysts. The DSSC performance can be improved with a short APPJ processing time, suggesting that a DC-pulse nitrogen APPJ can be an efficient tool for rapidly synthesizing catalytic Pt-SnO_x counter electrodes (CEs) for DSSCs. Full article

Metallic glasses (MGs), a new class of advanced structural materials with extraordinary mechanical properties, such as high strength approaching the theoretical value and an elastic limit several times larger than the conventional metals, are being used to develop cellular structures with excellent mechanical-energy-dissipation performance. In this paper, the research progress on the development of MG structures for energy-dissipation applications is reviewed, including MG foams, MG honeycombs, cellular MGs with macroscopic cellular structures, microscopic MG lattice structures and kirigami MG structures. MG structures not only have high plastic energy absorption capacity superior to conventional cellular metals, but also demonstrate great potential for storing the elastic energy during cyclic loading. The deformation behavior as well as the mechanisms for the excellent energy-dissipation performance of varying kinds MG structures is compared and discussed. Suggestions on the future development/optimization of MG structures for enhanced energy-dissipation performance are proposed, which can be helpful for exploring the widespread structural-application of MGs. Full article

The machining of cavities for blow molding is a long and costly process, with the objective of obtaining an excellent surface finish with the minimal possible electrical energy consumption (EEC). This work has studied which combination of cutting parameters and cutting strategies to use to achieve an optimum surface finish on the mold using the minimal associated EEC: in roughing operation, tool path strategy and axial depth of cut were studied; in finishing operation, tool path strategy, spindle-speed, feed-rate, and step-over were evaluated. Thirty-two molds were machined in blocks of aluminium alloy EN-AW 7075 T6 in a machining center of a three-axis, following an orthogonal design of experiments. The analysis of results demonstrates that: a roughing strategy has influence on the surface roughness on the bottom of the mold; a finishing strategy is an influential factor on the surface roughness on the walls of the mold; certain parameters have no relevance on the surface roughness but have an influence on the EEC; an adequate selection of cutting strategies and cutting parameters permit an improvement of surface roughness of up to 70%, and a reduction of 40% in EEC, compared to the less favorable tests. Full article

Super-hydrophobic film with hierarchical micro/nano structures was prepared by galvanic replacement reaction process on the surface of galvanized steel. The effects of the etching time and copper nitrate concentration on the wetting property of the as-prepared surfaces were studied. Scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and electrochemical technique were employed to characterize the surface morphology, chemical composition, and corrosion resistance. The stability and self-cleaning property of the as-fabricated super-hydrophobic film were also evaluated. The super-hydrophobic film can be obtained within 3 min and possesses a water contact angle of 164.3° ± 2°. Potentiodynamic polarization measurements indicated that the super-hydrophobic film greatly improved the corrosion resistance of the galvanized steel in 3.5 wt % NaCl aqueous solution. The highest inhibition efficiency was estimated to be 96.6%. The obtained super-hydrophobic film showed good stability and self-cleaning property. Full article

The EU28 total lime demand in 2017 was estimated at about 20 million tons, out of which about 40% are consumed in the iron and steel industry. Steel remains the major consumer after environment and construction. The lime industry is quite mature and consolidated in developed countries, with enough reserves and production to serve regional markets while being fragmented in developing nations where steel producers rely on local sourcing. There is relatively very little trade for lime worldwide. Lime has a critical role at different steps of the steelmaking process, and especially to make a good slag facilitating the removal of sulphur and phosphorus, and for providing a safer platform to withstand high intensity arc plasma in the electric arc furnace (EAF), and violent reactions in the basic oxygen furnace (BOF). Lime quality and quantity has a direct effect on slag quality, which affects metallurgical results, refractory life, liquid metal yield, and productivity, and therefore the total cost of the steel production. In this paper, we present the importance of careful selection in the limestone and calcination process, which influences critical lime quality characteristics. We shall further elaborate on the impact of lime characteristics in the optimization of the steelmaking process, metallurgical benefits, overall cost impact, potential savings, and environmental benefits. Full article

In situ scanning electron microscopy three-point bending test was employed in this study to investigate the crack initiation and propagation in 5A05 aluminum alloy. The microscale strain fields around the crack tip were measured by using the geometric phase analysis method. Results show that prior to the crack initiation, the normal strain ε_yy (y direction is perpendicular to the load direction) was tensile around the notch, whereas the normal strain ε_xx (x direction is parallel to the load direction) was compressive around the notch. The shear strain ε_xy was nearly zero. With the increase in load, the normal strains ε_yy and ε_xx gradually increased, but the change in shear strain ε_xy was not evident. When the stresses at several sharp points at the notch root reached the breaking strengths, a few microcracks initiated at these points. At this moment, the normal strains ε_yy and ε_xx were much greater than the shear ε_xy, and dominated the strain fields around the crack tip. In the crack propagation process, the normal strains ε_yy and ε_xx, and the shear strain ε_xy dominated the strain fields around the crack tip, thereby leading to a Z-form of crack propagation path in the specimen. Full article

The present work provides validation of the ultimate tensile strength computational models, based on full-scale lamellar graphite iron casting process simulation, against previously obtained experimental data. Microstructure models have been combined with modified Griffith and Hall–Petch equations, and incorporated into casting simulation software, to enable the strength prediction for four pearlitic lamellar cast iron alloys with various carbon contents. The results show that the developed models can be successfully applied within the strength prediction methodology along with the simulation tools, for a wide range of carbon contents and for different solidification rates typical for both thin- and thick-walled complex-shaped iron castings. Full article

The structural integrity of steel bolted joints may be compromised due to excessive loading. Therefore, condition assessment and the detection of potential defects before they cause a failure have become a major issue. The paper is focused on the condition monitoring of a bolted lap joint subjected to progressive degradation in a tensile test. The inspection used Lamb waves propagated through the overlap area. Wave propagation signals were registered automatically by means of piezoelectric transducers. Two damage indices were defined based on linear and nonlinear features of Lamb waves. The use of a network of piezoelectric transducers and the analysis of multiple signals instead of single ones was proved to effectively monitor the state of the bolted joint. The obtained results showed that the method enabled to detect selected stages of the degradation process and to characterize the reduction of the contact area between the plates in the overlap area. Full article

Rare earth elements (REE) are present at low concentrations (hundreds of ppm) in phosphoric acid solutions produced by the leaching of phosphate ores by sulfuric acid. The strongly acidic and complexing nature of this medium, as well as the presence of metallic impurities (including iron and uranium), require the development of a particularly cost effective process for the selective recovery of REE. Compared to the classical but costly solvent extraction, liquid-solid extraction using commercial chelating ion exchange resins could be an interesting alternative. Among the different resins tested in this paper (Tulsion CH-93, Purolite S940, Amberlite IRC-747, Lewatit TP-260, Lewatit VP OC 1026, Monophos, Diphonix,) the aminophosphonic IRC-747, and aminomethylphosphonic TP-260 are the most promising. Both of them present similar performances in terms of maximum sorption capacity estimated to be 1.8 meq/g dry resin and in adsorption kinetics, which appears to be best explained by a moving boundary model controlled by particle diffusion. Full article

Fatigue life prediction for the notched components is an essential step within the design process of machines. Fatigue strength and life prediction of 40Cr notched steel before and after shot peening were studied. Fatigue fracture of specimens treated by three shot peening intensity parameters was discussed. The life prediction considering residual stress, work hardening and surface roughness caused by shot peening was analyzed. The results indicated that fatigue strength was obviously improved after shot peening and the improvement effect was gradually enhanced with the increase of shot peening intensity. The predicted values based on R_z coefficient showed a good correspondence with the experimental data. Full article

For constructing marine liquefied natural gas (LNG) fuel/storage tanks, high manganese steel is being recognized as an alternative to stainless steel, nickel alloy, and aluminum alloy. In this study, the nonlinear tensile behavior of high manganese steel was investigated and numerically simulated at cryogenic temperatures at which natural gas exists as a liquid. Physical experimental tensile tests were carried out for a flat test specimen at 293 K and 110 K. In particular, the tensile behavior of a flat hole-notched high manganese steel specimen was experimentally obtained. A specimen with a hole was readily fractured compared to one without a hole. Tensile behavior of high manganese steel at the two cryogenic temperatures was compared to that of stainless steel, nickel, and aluminum alloy. In addition, numerical tests were performed for flat tensile specimens under identical experimental conditions. The elastoplastic damage model was derived and implemented using an Abaqus user-defined subroutine to appropriately simulate material behavior and degradation. The influence of some parameters on tensile behavior was investigated. The simulation results satisfactorily replicated the nonlinear tensile behavior of high manganese steel. The proposed numerical method, which is based on the damage-coupled material constitutive model, can be applied to structural analysis on the finite element analysis platform considering mechanical nonlinearities induced by severe conditions such as cryogenic temperature. Full article

The focus of the present work is to develop a deep understanding of deformation of stacked metal sheets with a series of different sequences by using shock wave loading. Here, experimental and numerical investigations of deformation of a single metal sheet of 1.5-mm and the stack of three metal sheets of 0.5-mm thickness of aluminum (Al), copper (Cu) and brass (Br) material were carried out. In the shock wave experiments, helium was used as the driving gas to produce a strong shock wave. Finite elements method (FEM) simulations on 3D-computational models were performed with explicit dynamic analysis, and Johnson-Cook material model was used. The obtained results from experiments of the outer diameter, thickness distribution, and dome height were analyzed and compared with the numerical simulations, and both the results are in excellent agreement. Moreover, for the same pressure load, due to lower inter-metallic friction in the stacked sheets compared to a cohesive property of the single sheet, an excellent deformation of stacked metallic sheets was observed. The results of this work indicated that the shock wave-forming process is a feasible technique for mass production of stacked metallic sheets as well as fabricating a hierarchical composite structure, which provides higher formability and smooth thickness distribution compared to a single material. Full article

The precipitation of (Cr,Fe)₂₃C₆ carbide could significantly degrade the mechanical properties of Nb-bearing cast austenitic heat-resistant steels, designed for exhaust components of automotive gasoline engines at 1000 °C. In the current research, the precipitation behavior of (Cr,Fe)₂₃C₆ carbide in these alloys, with great variations in N/C (Nitrogen/Carbon) ratio, was investigated through the liquid metal cooling directional solidification method, combined with thermodynamic calculations. Microstructural characterization suggested that the (Cr,Fe)₂₃C₆ carbide formed in the steady-state zone and the competitive zone, upon cooling to room temperature, after the solidification ended. It grew in the colony of the δ-ferrite, through the eutectoid reaction and showed different concentrations of C and Si from the δ-ferrite. Its precipitation temperature decreased significantly with increasing the N/C ratio, thereby retarding its precipitation. Therefore, the quantity of (Cr,Fe)₂₃C₆ carbide could be limited though increasing the N/C ratio of this type of alloys. Full article

The two-stage controlled rolling and cooling of a low carbon Mo-V-Ti-N steel at different cooling paths was simulated through a Gleeble 3500 system. The microstructure and tensile properties of each sample were examined by estimating their dependence on the cooling paths. It was indicated that a mixed microstructure of polygonal ferrite (PF), acicular ferrite (AF), granular bainitic ferrite (GBF), and a martensite-austenite (M-A) constituent was developed in each sample. Results showed that application of the reduced cooling rate and elevated finishing cooling temperature led to the increases in the effective ferrite grain size and the precipitate amount despite a decrease in dislocation density, which eventually resulted in the overall yield strength. It also led to an increasing amount of M-A constituent, which lowered the yield ratio and, thereby, enhanced the capacity for strain hardening. In addition, the underlying mechanism for the correlations among the cooling path, the microstructure, and the yield strength was considered. Full article