Irrigation is an important factor affecting the change of terrestrial water storage (TWS), especially in grain-producing areas. The Northeast China Plain (NECP), the Huang-Huai-Hai Plain (HHH) and the middle and lower reaches of the Yangtze River Basin Plain (YRB) are major grain-producing regions of China, with particular climate conditions, crops and irrigation schemes. However, there are few papers focusing on the different variation pattern of water storage between NECP, HHH and YRB. In this paper, the characteristics of terrestrial water storage anomaly (TWSA) and groundwater storage in the three regions mentioned above from 2003 to 2014 were analyzed, and the main reasons for water storage variations in the three regions were also discussed. The result shows that although effective irrigated areas increased in all three regions, TWSA only decreased in HHH and TWSA in the other two regions have shown an increasing trend. Spatially, the water storage deficit was more serious in middle and south NECP and HHH. In the three regions, water storage variations were impacted by meteorological condition and anthropogenic stress (e.g., irrigation). However, irrigation water consumption has a greater impact on water storage deficit in HHH than the other two regions, and water storage variation in YRB was mainly impacted by meteorological conditions. In this case, we suggest that the structure of agricultural planting in HHH should be adjusted to reduce the water consumption for irrigation. Full article

Water is one of the natural resources most affected by anthropogenic activities, like industry, agriculture, and traffic [...] Full article

Polyaniline modified zinc oxide (PANI-ZnO) photocatalyst composites were synthesized by focusing on dissolution disadvantage of ZnO. In-Situ chemical oxidation polymerization method was performed under neutral conditions (PANI-ES) whereas in hybridization method physical blending was applied using emeraldine base of polyaniline (PANI-EB). PANI-ZnO composites were prepared in various ratios of aniline (ANI) to ZnO as 1%, 3%, 6% and 9%. The alterations on the structural and morphological properties of PANI-ZnO composites were compared by Fourier Transform Infrared (FT-IR), Raman Spectroscopy, X-ray Diffraction (XRD) and Scanning Electron Microscopy-Energy Dispersive X-ray Analysis Unit (SEM-EDAX) techniques. FT-IR and Raman spectroscopy confirmed the presence of PANI in all composites. SEM images revealed the morphological differences of PANI-ZnO composites based on PANI presence and preparation methods. Photocatalytic performances of PANI-ZnO specimens were investigated by following the degradation of methylene blue (MB) in aqueous medium under UVA irradiation. The effects of catalyst dose and initial dye concentration were also studied. MB degradation was followed by both decolorization extents and removal of aromatic fractions. PANI-ZnO composites expressed enhanced photocatalytic performance (~95% for both methods) as compared to sole ZnO (~87%). The hybridization method was found to be more efficient than the In-Situ chemical oxidation polymerization method emphasizing the significance of the neutral medium. Full article

In this paper, we present an agent-based model for exploring the interplay of basic structural and socio-cognitive factors and conventional water saving measures in the evolution of domestic water use in metropolitan areas. Using data of Barcelona, we discuss three scenarios that involve plausible demographic and cultural trends. Results show that, in the three scenarios, aggregate outcomes are consistent with available conventional modelling (while total water use grows, per capita water use declines); however, the agent-based simulation also reveals, for each scenario, the different dynamics of simple policy measures with population growth, cultural trends and social influence; thus providing unexpected insights for policy design. Full article

This paper focuses on the legal and institutional framework of urban water services in Spain, emphasizing water sanitation by using proposals that would positively contribute to wastewater management in Brazil. The recent Brazilian Federal Law No. 14,026/20 aims to encourage investment in water sanitation, promoting public-private collaboration formulas so that service management is viable even in economically less-favored regions. In Spain, sanitation policies are aimed at fulfilling the set of obligations and objectives imposed by European Union Directives within the environmental policies of the Union. From an economic point of view, supply and sanitation water services are classified at European legal framework as “services of general economic interest” (SGEI), not subject to harmonized regulation and open to a natural monopoly provision regime, which they admit various types of management formulas, public and private, based on the ownership and public intervention of the service, both at national and European level. We believe that the Spanish experience in this field, beyond its singularities, can serve as a useful reference for Brazilian’s urban wastewater new regulation for several reasons: (1) Because of the decentralized political scheme that both countries share and the need to articulate an adequate system of competencies in consequence; (2) Because of the international experience that Spanish companies have at the sector’s technological forefront, they are very competitive; (3) Due to the adequate functioning of the Spanish legal and organizational framework since, despite its shortcomings, as we later will comment, it has managed to develop successful financing formulas and management models that, in general terms, have allowed to ensure with reasonable efficiency, continuity, stability and sustainability in the provision of urban water services. Full article

Stream temperature is a critical parameter for understanding hydrological and biological processes in stream ecosystems. Although a large body of research has addressed the effects of forest harvesting on stream temperature, less is known about the responses of stream temperature to the practice of strip-thinning, which produces more coherent patches of shade and sunlight areas. In this study, we examined stream temperature response to 50% strip-thinning in a 17 ha headwater catchment. The thinning lines extended through the riparian zone. Paired-catchment analysis was applied to estimate changes in daily maximum, mean, and minimum stream temperatures for the first year following treatment. Significant effects on daily maximum stream temperature were found for April to August, ranging from 0.6 °C to 3.9 °C, similar to the magnitude of effect found in previous studies involving 50% random thinning. We conducted further analysis to identify the thermal response variability in relation to hydrometeorological drivers. Multiple regression analysis revealed that treatment effects for maximum daily stream temperature were positively related to solar radiation and negatively related to discharge. Frequent precipitation during the summer monsoon season produced moderate increases in discharge (from 1 to 5 mm day⁻¹), mitigating stream temperature increases associated with solar radiation. Catchment hydrologic response to rain events can play an important role in controlling stream thermal response to forest management practices. Full article

Environmental Hydraulics (EH) is the scientific study of environmental water flows and their related transport and transformation processes in natural water systems. This review provides some remarks about the historical development of EH throughout three different paradigms or ages, namely, the Public Health Age, the Water Quality Age, and finally the Integrated Environmental Hydraulics Age. We further evaluate how EH research has changed in the last 20 years through a bibliometric analysis of the proceedings of the International Symposium on Environmental Hydraulics (ISEH) and Environmental Fluid Mechanics (EFMC) journal articles conducted using Citespace and Leximancer. Authors and affiliations are analyzed to identify patterns of collaboration, followed by an analysis of the temporal evolution of the EFMC impact index as well as its highly-cited articles. Finally, the major EH topics are identified with a comparison between the topics extracted from the two different sources. As the EH field is becoming rapidly global, some topics were confirmed to have attracted more interest in EH such as Flow Condition, Numerical Modelling, Experimental Measurements. It is hoped that our findings could provide a reference for students, academics, and policy-makers related to EH. Full article

In rocky shore systems, sessile macrobenthic assemblages may act as “ecosystem engineers” for many smaller benthic organisms. Thus, the influence of macrobenthic coverage on the diversity and assemblage structure of the harpacticoid copepod fauna was investigated in the rocky shores of a Marine Protect Area (MPA) in the Ligurian Sea (NW, Mediterranean Sea). Two sampling sites were investigated in two seasons at three different depths on both sub-vertical and inclined reefs. A total of 61 species of copepods mainly represented by Miraciidae, Laophontidae, Longipediidae and Thalestridae were found. The complex micro-topography of these substrata provided a wide variety of niches for many species with different lifestyles that suggests the important role of rocky shores to ensure the functioning of coastal ecosystems. The harpacticoid assemblage structure seemed mainly influenced by season and depth. The temporal spread observed is likely one of the underlying mechanisms of niche segregation that allows many species to co-occur in this specific environment along with a subordinate spatial segregation corresponding to the depth gradient. The results seem to support the hypothesis that the different species composition of the “ecosystem engineer” (and consequently its structure changes) are relevant in structuring the copepod assemblages. The comparison with previous data on general meiofauna underlines that higher surrogacy of the taxonomic identification could be used to study rocky shore communities, but the rich diversity that these systems host can only be understood at the lower taxonomic levels. The same holds for future evaluations of impact of environmental changes (including MPA regulations) on meiofaunal assemblages. Full article

The quality of aquaculture waters is directly related to water management and aquaculture efficiency, which puts forward higher requirements for water quality evaluation. Based on the consideration of the influence of temporal and spatial changes on the water quality, this paper proposed an improved fuzzy comprehensive evaluation method for aquaculture water quality evaluation. Specifically, constructing a new membership function in the first place, and then selecting dissolved oxygen, pH, temperature and ammonia nitrogen content as water quality indexes for aquaculture, after that, collecting 60 sets of water quality index for different seasons in the past three years, finally, evaluating the water quality of Yangjiabo Aquaculture Base. Meanwhile, comparing it with the evaluation results of the single factor evaluation method and the traditional fuzzy evaluation method. The results show that the water quality of the Yangjiabo Aquaculture Base is at the worst level in winter, and the water quality has improved significantly in spring, summer and autumn. Compared with the other two method, the improved method can comprehensively reflect the changes in water quality with time and space, which is more practical, and so it can be considered to provide a scientific basis for efficient aquaculture and water quality classification. Full article

Fish passes facilitate fish movement in fragmented river systems, yet they can also provide important habitat functions. This study investigated the fish community composition of different constructed habitat types (fluvial habitats, floodplain ponds) within fish passes in relation to habitat characteristics in order to deduce recommendations for fish-friendly designs of such structures. Fish community structures within passes differed significantly from those in the main river, comprising a high number of rheophilic species in fluvial habitats (Thymallus thymallus, Hucho hucho, Salmo trutta, Cottus gobio, Chondrostoma nasus, and Barbus barbus), and of stagnophilic species in floodplain ponds (Rhodeus amarus, Scardinius erythrophthalmus, Misgurnus bipartitus, and Tinca tinca). During summer, floodplain ponds also provided important juvenile habitats for the target species C. nasus and B. barbus. Differences between the two habitat types in fish abundance were mostly explained by differences in macrophyte coverage, gravel, boulders, temperature, and current speed. The findings of this study stress the important habitat functions of fish passes. They also suggest that integration of diverse habitat structures, especially of currently hardly considered constructed floodplain ponds into fish passes, can greatly enhance their fish communities and contribute to the restoration of several declining target species of conservation. Full article

Ecuador has historically had a unique experience with water law, management, and policy as a result of its constitutional declaration of water access as a human right. In this paper, the legal, environmental, economic, and social aspects related to water management in Ecuador are analyzed. In doing so, the incorporation of local governance structures such as water users’ associations (WUAs) are characterized within a national model of authorization under SENAGUA, Ecuador’s former water agency, highlighting the importance of integrated management for meeting the country’s geographically and environmentally diverse needs. Additionally, the role of anthropogenic activities such as crude oil production, artisanal and small-scale gold (ASGM) mining, agriculture, sewage discharge, and domestic practices are evaluated in the context of policy implementation and environmental quality concerns. Finally, individual and community-level responses are explored, highlighting the importance of geographically specific perceptions of water rights and quality in the adoption of coping strategies. In these ways, a multi-faceted analysis of Ecuadorian water policy shaped by community-level engagement, geographic diversity, and influential economic sectors is developed. This study highlights the need for increased financial and legislative support around extractive and polluting industries such as agriculture, ASGM, and sewage treatment for long-term safety and sustainability of water access in Ecuador. Additionally, increased efforts to educate industry-specific workers, local management boards, and individuals about potential solutions to water-related challenges will help improve the efficiency of current legislation. Finally, this study underscores a need for additional research related to water quality and sustainability in Ecuador, as well as for the social, economic, and environmentally specific factors that influence water security outcomes in the country. Full article

In Brazil, the correct measurement of the individual firm energy of a plant is important, since it influences directly the determination of its assured energy which is used to establish contracts between power plants and distribution companies, free consumers, and traders. With increasing technological development and greater reliability in the use of automated techniques for monitoring, the use of the Acoustic Doppler Current Profiler (ADCP), has become a reality in Brazil. The ADCP has many advantages over the traditional techniques used for monitoring flows in gage stations of the national hydrometeorological network. In this context, the purpose of this work is to evaluate the impact of the streamflow rating curve measurement on the evaluation of the firm energy of a hydropower plant. A linear optimization model based on dynamic programming was used to calculate the firm energy and it was considered possible measurement errors in the plant’s inflow values and in the parameters of its polynomials that defines the upward and downward elevation. The results pointed that the two considerations had an impact on the calculated firm energy: the inflow measurements and the streamflow rating curve. Therefore, it is shown the importance of an accurate measurement of inflows for the evaluation of the plant’s firm energy. Full article

Sulphide build-up in pressure sewers has been identified as the main cause for the occurrence of odour and corrosion in sewer systems. Despite the efforts to optimize commonly used control technologies such as nitrate and iron salts to reduce sulphide emission, continuous addition of these chemicals is still required. A biocidal agent such as free nitrous acid can be added intermittently, less frequently, and in smaller quantities whilst achieving total sulphide control. So far, laboratory and field studies in Australia and the USA have successfully proven and applied the use of this control technology, exhibiting its strong biocidal effects during intermittent addition. In this study, nine trials were made to assess the application of the free nitrous acid (FNA) as an alternative sulphide control technology in Germany. The sewer pilot plant of the Berlin Water Utility Company was used to perform the trials at a technical scale using a supply of raw sewage. FNA exposure times ranging from 5 to 24 h in varying concentrations were investigated. The effectiveness of the FNA treatment was monitored using the online hydrogen sulphide (H₂S) gas and dissolved-sulphide sensors installed in the sewer pilot plant. Effective sulphide control was only possible during dosing periods, with rapid resumption of sulphide production for the trials with exposure times of <12 h and concentrations ranging from 0.08 to 0.56 mg HNO₂-N L⁻¹ suggesting a slight inhibitory effect. A more pronounced biocidal effect was observed for the trials exposed to FNA treatment for 24 h at concentrations >0.29 mg HNO₂-N L⁻¹. Overall, the trials of this study demonstrated that the biofilms were FNA resistant and that the concentrations and exposure times used were inadequate to develop an effective intermittent dosing strategy. Full article

The frequent occurrence of cyanobacterial blooms, caused by the eutrophication of water bodies, has triggered several ecological issues. Metal-controlled cyanobacteria are resulting in a series of secondary environmental problems and thus limiting environmental sustainability. Whether there is a more environmentally friendly way to replace metals in the removal of cyanobacteria is still unclear. To explore whether common heavy metals inhibit algal growth and whether Eucalyptus leaves (EL) can replace heavy metal ions in controlling algae outbreaks, here, we add Fe³⁺, Al³⁺, 3 mol/L of zinc (Zn₃), 10 mol/L zinc (Zn₁₀), and EL to a medium containing Cyanobacteria. We determine the medium’s color (456 nm), UV (254 nm), chlorophyll a, turbidity, temperature, pH, total dissolved solids, conductivity, and blue-green algae (BGA) at days 1, 4, 7, 11, 14, 19, and 21. We find that Fe³⁺, Al³⁺, Zn₃, Zn₁₀, and EL can inhibit chlorophyll synthesis, thereby impeding algae biomass growth due to metal ions’ disruption of the chlorophyll structure. The toxicity of Zn²⁺ may be higher than that of Fe³⁺ and Al³⁺ since it can completely destroy the structure of chlorophyll a. The damage of Zn (10) to chlorophyll a is stronger than that of Zn (3), indicating that high concentrations of metals have a stronger inhibitory effect on algae. The toxicity of EL to algae is lower than that of other metals, but it can significantly inhibit the growth of algae. We suggest the use of Eucalyptus leaves to inhibit algal growth in eutrophic water bodies. Our results provide a scientific basis for an environmentally friendly approach to controlling cyanobacteria outbreaks. Full article

Shifts in winter temperature and precipitation patterns can profoundly affect snow accumulation and melt regimes. These shifts have varying impacts on local to large-scale hydro-ecological systems and freshwater distribution, especially in cold regions with high hydroclimatic heterogeneity. We evaluate winter climate changes in the six ecozones (Mountains, Foothills, Prairie, Parkland, Boreal, and Taiga) in Alberta, Canada, and identify regions of elevated susceptibility to change. Evaluation of historic trends and future changes in winter climate use high-resolution (~10 km) gridded data for 1950–2017 and projections for the 2050s (2041–2070) and 2080s (2071–2100) under medium (RCP 4.5) and high (RCP 8.5) emissions scenarios. Results indicate continued declines in winter duration and earlier onset of spring above-freezing temperatures from historic through future periods, with greater changes in Prairie and Mountain ecozones, and extremely short or nonexistent winter durations in future climatologies. Decreases in November–April precipitation and a shift from snow to rain dominate the historic period. Future scenarios suggest winter precipitation increases are expected to predominantly fall as rain. Additionally, shifts in precipitation distributions are likely to lead to historically-rare, high-precipitation extreme events becoming more common. This study increases our understanding of historic trends and projected future change effects on winter snowpack-related climate and can be used inform adaptive water resource management strategies. Full article