Facilitated Transport Membranes for Gas Separations

A special issue of Membranes (ISSN 2077-0375). This special issue belongs to the section "Membrane Applications".

Deadline for manuscript submissions: closed (30 September 2021) | Viewed by 3877

Special Issue Editor


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Guest Editor
DICAM Department, Alma Mater Studiorum-Università di Bologna, via Terracini 28, 40131 Bologna, Italy
Interests: membranes for gas separation; membrane modeling; facilitated transport membranes; CO2 capture

Special Issue Information

Dear Colleagues,

Facilitated transport membranes have been considered extremely attractive for a long time for their ability to increase the permeability and selectivity of target molecules with respect to other compounds. The presence of selective carriers which are able to transport the compounds of interest across the membrane, mimicking the mechanisms of many biological membranes, have resulted in a very interesting approach to separation and stimulate research from both academia and industry.

Among the many possible applications, the present paper focuses on the use of facilitated transport membranes in the field of gas separation. Papers are sought focusing on the development and production of new materials and/or carriers for gas separation membranes as well as on the study of the transport phenomena in the membrane and membrane module. General reviews about the most common separation and studies related to novel or hybrid applications are also welcome.

Prof. Dr. Marco Giacinti Baschetti
Guest Editor

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Keywords

  • facilitated transport
  • gas and vapor separation
  • membrane modeling

Published Papers (1 paper)

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Research

14 pages, 3306 KiB  
Article
Effect of Mobile Carrier on the Performance of PVAm–Nanocellulose Facilitated Transport Membranes for CO2 Capture
by Riccardo Casadei, Elham Firouznia and Marco Giacinti Baschetti
Membranes 2021, 11(6), 442; https://doi.org/10.3390/membranes11060442 - 12 Jun 2021
Cited by 11 | Viewed by 3172
Abstract
Facilitated transport membranes obtained by coupling polyvinylamine with highly charged carboxymethylated nanocellulose fibers were studied considering both water sorption and gas permeation experiments. In particular, the effect of the L-arginine as a mobile carrier was investigated to understand possible improvements in CO2 [...] Read more.
Facilitated transport membranes obtained by coupling polyvinylamine with highly charged carboxymethylated nanocellulose fibers were studied considering both water sorption and gas permeation experiments. In particular, the effect of the L-arginine as a mobile carrier was investigated to understand possible improvements in CO2 transport across the membranes. The results show that L-arginine addition decreases the water uptake of the membrane, due to the lower polyvinylamine content, but was able to improve the CO2 transport. Tests carried on at 35 °C and high relative humidity indeed showed an increase of both CO2 permeability and selectivity with respect to nitrogen and methane. In particular, the CO2 permeability increased from 160 to about 340 Barrer when arginine loading was increased from 0 to 45 wt%. In the same conditions, selectivity with respect to nitrogen was more than doubled, increasing from 20 to 45. Minor improvements were instead obtained with respect to methane; CO2/CH4 selectivity, indeed, even in presence of the mobile carrier, was limited to about 20. Full article
(This article belongs to the Special Issue Facilitated Transport Membranes for Gas Separations)
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